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Beilstein J. Org. Chem. 2025, 21, 1489–1495, doi:10.3762/bjoc.21.111
Graphical Abstract
Figure 1: Selected fusicoccane diterpenoids and overview of this study. (a) Representative members of the fus...
Figure 2: Heterologous production of brassicicene I in an engineered A. oryzae strain. (a) Biosynthesis of fu...
Figure 3: Synthesis of cotylenol (3). (a) Synthesis of Nakada’s intermediate 10 from 5. (b) Orf7 catalyzes th...
Scheme 1: Synthesis of alterbrassicicene E (6) and brassicicenes A (7) and R (8) from brassicicene I (5).
Beilstein J. Org. Chem. 2013, 9, 983–990, doi:10.3762/bjoc.9.113
Scheme 1: Biogenetic origin of Vinca alkaloids.
Scheme 2: Synthetic strategy for velbanamine based on chemoselective dioxygenation.
Scheme 3: Intramolecular oxyamidation of alkene 11 with phenyliodine(III)-bis(trifluoroacetate) (PIFA) by Tel...
Scheme 4: Copper-catalyzed amination of aryliodide.
Scheme 5: Revised PIFA-promoted cyclization of amide 11.
Scheme 6: PIFA-promoted cyclization to synthesize lactone.
Figure 1: Hydrolysis of iminolactone 18 under basic conditions.
Scheme 7: “Stop-and-flow” strategy for the stepwise dioxygenation of alkenes.
Scheme 8: “Stop-and-flow” strategy for the construction of γ-lactone derivatives.