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1 article(s) from Zucchetta, Daniele

Approaches to stereoselective 1,1'-glycosylation

Daniele Zucchetta and
Alla Zamyatina

Beilstein J. Org. Chem. 2025, 21, 1700–1718, doi:10.3762/bjoc.21.133

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Scheme 1: Application of chloride-, bromide-, and trichloroacetimidate donors in 1,1'-coupling reactions towa...

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Scheme 2: Application of trichloroacetimidates as donors in 1,1'-β,α coupling reactions and the use of 1,2-or...

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Scheme 3: The β-anomeric configuration in the lactol acceptors can be trapped and fixed within the five-membe...

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Scheme 4: Diarylborinic acid-promoted β,α-1,1' glycosylation.

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Scheme 5: The anomeric configuration in the lactol acceptor can be trapped in the form of a TMS-glycoside.

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Scheme 6: The anomeric configuration in the lactol acceptor can be trapped in form of a 1-O-TMS-glycoside tha...

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Scheme 7: Influence of remote protecting groups on the stereoselectivity and efficiency of 1,1'-β,α bond form...

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Scheme 8: Synthesis of non-symmetrically fully orthogonally protected β,α-1,1' diglucosamines.

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Scheme 9: Synthesis of non-symmetric β,β-1,1'-linked disaccharides.

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Scheme 10: Synthesis of non-symmetric, fully orthogonally protected β,β-1,1'-diglucosamines.

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Scheme 11: Synthesis of α,α-1,1'-disaccharides.

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Scheme 12: Synthesis of α,α-1,1'-thiodisacchrides.

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Scheme 13: Synthesis of partially desymmetrized α,α-1,1'-linked disaccharides.

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Scheme 14: Synthesis of non-symmetric orthogonally protected α,α-1,1'-linked disaccharides involving an aminos...

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Published 27 Aug 2025

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