Photoinduced homolytic C–H activation in N-(4-homoadamantyl)phthalimide

• Nikola Cindro,
• Margareta Horvat,
• Kata Mlinarić-Majerski,
• Axel G. Griesbeck and
• Nikola Basarić

Beilstein J. Org. Chem. 2011, 7, 270–277, doi:10.3762/bjoc.7.36

• (Scheme 1) [51]. The mechanism of the photoinduced domino reaction was investigated and it was found that it probably takes place from a higher excited triplet state or the singlet state [52]. Herein, we report the synthesis and photochemistry of a phthalimide derivative of homoadamantane 5. The research

• unreacted 5 was recovered. This finding is in accordance with acetone acting as a triplet sensitizer and the anticipated triplet state reactivity of the phthalimide in the H-abstraction reactions. Furthermore, the addition of H2O as a protic solvent also increased the reactivity of the phthalimide, based on

• notation of atoms see the Experimental), which precluded unambiguous assignment of the stereochemistry to the isomers 7. According to the above product study, a mechanism for the photochemical transformation of 5 can be proposed. On excitation (direct or sensitized) the triplet state of 5 is populated and

Synthesis of bis(3-{[2-(allyloxy)ethoxy]methyl}-2,4,6-trimethylbenzoyl)(phenyl)phosphine oxide – a tailor-made photoinitiator for dental adhesives

• Norbert Moszner,
• Iris Lamparth,
• Jörg Angermann,
• Urs Karl Fischer,
• Frank Zeuner,
• Thorsten Bock,
• Robert Liska and
• Volker Rheinberger

Beilstein J. Org. Chem. 2010, 6, No. 26, doi:10.3762/bjoc.6.26

• between ~360 and 400 nm can be generally assigned to symmetry forbidden n-π* transitions, which are responsible for α-cleavage and formation of free radicals [17]. After excitation with light in the near UV–vis, the excited triplet state undergoes cleavage of the carbon-phosphorus bond, thereby producing

Reversible intramolecular photocycloaddition of a bis(9-anthrylbutadienyl)paracyclophane – an inverse photochromic system. (Photoactive cyclophanes 5)

• Henning Hopf,
• Christian Beck,
• Jean-Pierre Desvergne,
• Henri Bouas-Laurent,
• Peter G. Jones and
• Ludger Ernst

Beilstein J. Org. Chem. 2009, 5, No. 20, doi:10.3762/bjoc.5.20

• observed to occur under geometrical constraints [11][12][24] through a triplet state process [25]. [4+2]-Cycloadditions can take place in a hot ground state [26]. This result is reminiscent of the [4+2]-photocycloaddition between two naphthalene substrates for the anti-[2.2](1,4)-naphthalenophane leading