Beilstein J. Org. Chem.2006,2, No. 24, doi:10.1186/1860-5397-2-24
.
Tetramic acid antibiotics from natural sources.
H-bonding in tetronolactonyl dienyl esters.
Synthesis of tetronolactonyl aldehydes from L-ascorbic acid
Synthesis of tetronolactonyl dienyl esters from etronolactonyl aldehydes
Synthesis of 5-hydroxy lactams from dienyl tetronic esters
Synthesis of dienyl
PDF
Graphical Abstract
Figure 1:
Tetramic acid antibiotics from natural sources.
Beilstein J. Org. Chem.2006,2, No. 9, doi:10.1186/1860-5397-2-9
. Highly selective epoxidations of cycloalkenyl amides have been described[23] and, consistent with a hypothesis that the mixture of 10 and 11 arise through competing H-bonding directing effects of the carbamate and hydroxyl groups, acetylation of the free hydroxyl group prior to oxidation enhanced the
PDF
Graphical Abstract
Scheme 1:
The furan-nitroacylate approach to poly hydroxylated ACHC derivatives