Beilstein J. Org. Chem.2020,16, 989–1000, doi:10.3762/bjoc.16.88
”, 202 Stryska Str. 79031, Lviv, Ukraine 10.3762/bjoc.16.88 Abstract Four aryl-substituted acridan derivatives were designed, synthesized and characterized as electroactive materials for organic light emitting diodes based on emitters exhibiting thermally activated delayed fluorescence. These compounds
demonstrated maximum external quantum efficiencies up to 3.2%.
Keywords: acridan; hole mobility; host; OLED; thermally activated delayed fluorescence; Introduction
Organic light emitting diodes (OLEDs) are perfect candidates for multicolor displays and for next generation energy saving large area-lighting
levels are overcome [22][23][24][25][26]. The only hole or electron-transporting property of hosts leads to charge recombination near the interface between the charge-transporting layer and the emissive layer, thus decreasing the device’s efficiency [27].
In this work, four acridan derivatives were
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Graphical Abstract
Scheme 1:
Synthesis of acridan-based compounds 3–6. Reagents and conditions: (a) bromoethane, KOH, tetrabutyl...
Beilstein J. Org. Chem.2018,14, 282–308, doi:10.3762/bjoc.14.18
% could be attained for the sky-blue B4-based devices. Still based on the combination of acridan and 10H-phenoxaborin units, a complete isolation of the two units could be realized in B6 by directly functionalizing the 10H-phenoxaborin core with a spiro-type acridan group [38]. Using this strategy, pure
aromatic ring, interrupting the π-conjugation and localizing the HOMO level on the acridan moiety and the LUMO level on the central accepting group. The calculations also predicted a more planar phenyl–pyrimidine/phenyl–pyridine conformation (i.e., a smaller dihedral angle) in CN-P5/CN-P4 and a more
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Graphical Abstract
Figure 1:
Radiative deactivation pathways existing in fluorescent, phosphorescent and TADF materials.