Beilstein J. Org. Chem.2023,19, 1216–1224, doi:10.3762/bjoc.19.89
) porphyrins were transformed to the corresponding free base and zinc(II) benzo[f]chromeno[2,3-h]quinoxalinoporphyrins under standard demetallation and zinc insertion conditions. The absorption and emission properties of the obtained porphyrins were investigated by using UV–visible and fluorescence
spectroscopy. The preliminary photophysical results revealed a significant red-shift in their absorption and emission spectra as compared to the meso-tetrakis(4-methylphenyl)porphyrins due to the extended π-conjugation.
Keywords: bathochromic shift; benzo[f]chromeno[2,3-h]quinoxalinoporphyrins; catalysis
contruction of periphery-modified porphyrinoids [30][31][32][33][34][35][36][37][38][39][40][41], we thought to assemble benzo[f]chromeno[2,3-h]quinoxalinoporphyrins by incorporating porphyrin, quinoxaline and xanthene scaffolds in a single molecular framework using a multicomponent synthetic strategy. The
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Graphical Abstract
Scheme 1:
Synthesis of benzo[f]chromeno[2,3-h]quinoxalinoporphyrins 3–16.