Beilstein J. Org. Chem.2019,15, 299–309, doi:10.3762/bjoc.15.27
cichorinotoxin for this toxin. In conjunction with the D or L configurations of each amino acid, which were determined by Marfey’s method, we propose the structure of cichorinotoxin to be as follows: 3-hydroxydecanoyl-(Z)-dhThr1-D-Pro2-D-Ala3-D-Ala4-D-Ala5-D-Val6-D-Ala7-(Z)-dhThr8-Ala9-Val10-D-Ile11-Ser12-Ala13
alkaline hydrolysates, compounds A and B, were prepared. We discuss here the structure–activity relationships between the derivatives and their necrotic activities toward lettuce.
Keywords: cichorinotoxin; lipodepsipeptide; necrotic lesion of lettuce; phytotoxin; Pseudomonas cichorii; Introduction
compound has not been reported previously; we propose the name cichorinotoxin for this compound. Very recently, Huang et al. reported new phytotoxins, named cichopeptin A and B, from P. cichorii SF1-54 [14], which cause midrib rot disease in lettuce much like cichorinotoxin. However, cichorinotoxin is
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Graphical Abstract
Figure 1:
FABMS spectrum (positive mode, NBA matrix) of cichorinotoxin over the mass range of m/z 150─1000.