Beilstein J. Org. Chem.2011,7, 1622–1635, doi:10.3762/bjoc.7.191
nonribosomal peptide synthetase (NRPS) and polyketide synthase (PKS) pathways and highlight the unique enzyme mechanisms that were elucidated or can be anticipated for the individual products. We further include ribosomal natural products and UV-absorbing pigments from cyanobacteria. Mechanisticinsights
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Graphical Abstract
Figure 1:
Cyanobacteria proliferate in diverse habitats. A) Bloom-forming freshwater cyanobacteria of the gen...
Beilstein J. Org. Chem.2011,7, 744–758, doi:10.3762/bjoc.7.85
these reactions have not been completely understood [29][33]. A more detailed analysis of steric and electronic effects might provide helpful mechanisticinsights to clarify this practically important issue.
Previously, we demonstrated that additions to alkenes, which proceed through cyclic 3-membered