Beilstein J. Org. Chem.2019,15, 1829–1837, doi:10.3762/bjoc.15.177
respect to the orthogonal plane of the axle, only one stereoisomer of the [6]rotaxane was obtained.
Keywords: cucurbit[6]uril; cyclodextrin; macrocycles; mechanostereoisomer; rotaxane; Introduction
Cyclodextrins (CDs) are macrocycles composed of glucoses linked via α-1,4-glycosidic bonds. CDs of six (α
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Graphical Abstract
Scheme 1:
Synthesis of the axle and stopper building blocks 1 and 2.