Beilstein J. Org. Chem.2017,13, 558–563, doi:10.3762/bjoc.13.54
solid liquid interfacial layer-by-layer (LbL) synthesis of CMP-nanomembranes via Cu catalyzed azide–alkyne cycloaddition (CuAAC). However, this process featured very long reaction times and limited scalability. Herein we present the synthesis of surface grown CMP thin films and nanomembranes via light
induced thiol–yne click reaction. Using this reaction, we could greatly enhance the CMP nanomembrane synthesis and further broaden the variability of the LbL approach.
Keywords: click chemistry; conjugated microporous polymers (CMPs); microporous materials; nanomembranes; thin films; thiol–yne coupling
catalyzed azide–alkyne cycloaddition (CuAAC) approach, respectively [16]. These procedures are still limited to conductive substrates or associated with long reaction times.
In this work, we present a novel strategy for the LbL synthesis of CMP thin films and nanomembranes, using the light-induced and
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Graphical Abstract
Figure 1:
LbL synthesis with TPM-SH and TPM-alkyne using light-induced TYC reaction in the presence of the ph...