Beilstein J. Org. Chem.2010,6, No. 57, doi:10.3762/bjoc.6.57
-diiodobenzene a better procedure is presented together with the finding that 1,4-dialkyl-2,3-diiodobenzene, a constitutional isomer of 1,4-dialkyl-2,5-diiodobenzene, is one of the byproducts.
Keywords: alkyne protecting group; carbometalation; C–C coupling; phenyleneethynylene; polar tagging; Introduction
Oligo(p-phenyleneethynylene)s (oligoPPEs) have been frequently used as structural units for nanoscopic molecules because of their geometry and their electronic and photophysical properties [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19]. For their preparation three widely used
very weakly influenced by the number of the non polar repeating unit, 2,5-dihexyl-1,4-phenyleneethynylene, but dominated by the polar functional groups. Therefore, if the two products differ in the number of polar groups, chromatographic separation can become easy. This idea was put to the test for the
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Graphical Abstract
Scheme 1:
Synthesis of oligoPPEs by a unidirectional (a) or bidirectional (b) repeating unit by repeating uni...