Beilstein J. Org. Chem.2019,15, 2408–2418, doi:10.3762/bjoc.15.233
the resulting macrocycle.
Keywords: DFT; molecular mechanics; photostability; photo-switch; ring-strain; stiff stilbene; Introduction
The stiff stilbene (SS) molecule has drawn a lot of interest due to its photodynamic properties [1]. Stiff stilbenes typically undergo light triggered isomerization
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Graphical Abstract
Scheme 1:
The stiff stilbene photoisomerization from Z to E and vice versa by irradiation at 300 nm and 360 n...