Beilstein J. Org. Chem.2015,11, 2677–2688, doi:10.3762/bjoc.11.288
University College London, Gower Street, London WC1E 6BT, UK Laboratoire de Physicochimie des Polymères et des Interfaces (EA 2528), Institut des Matériaux, Université de Cergy-Pontoise, F-95031 Cergy-Pontoise Cedex, France 10.3762/bjoc.11.288 Abstract Two alternating polyfluorene polyrotaxanes (3·TM-βCD
polyrotaxane compounds exhibit a granular morphology with lower dispersity and smaller roughness exponent of the film surfaces in comparison with those of the neat copolymer 3.
Keywords: energy band gaps; fluorescence lifetimes; permethylated cyclodextrins; polyfluorene; polyrotaxanes; Introduction
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Graphical Abstract
Scheme 1:
Synthetic route of 3·TM-βCD and 3·TM-γCD polyrotaxanes, and the non-rotaxane counterpart 3.