Beilstein J. Org. Chem.2012,8, 1185–1190, doi:10.3762/bjoc.8.131
good yields and high stereoselectivities. Follow-up transformations of the primary products provided (E)-1-alkenyl-(pentafluorosulfanyl)benzenes and 2-(2-arylethyl)-(pentafluorosulfanyl)anilines.
Keywords: Horner–Wadsworth–Emmons reaction; pentafluorosulfanyl group; phosphonates; sulfurpentafluoride
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Graphical Abstract
Scheme 1:
Proposed synthesis of alkenyl-(pentafluorosulfanyl)benzenes.