Beilstein J. Org. Chem.2010,6, No. 26, doi:10.3762/bjoc.6.26
-butyl]acrylate [3] or 1,3-bis(methacrylamido)propane-2-yl dihydrogen phosphate (BMAMHP) [4], which show improved hydrolytic stability under acidic aqueous conditions. The visible-light (VL) photoinitiators (PIs) in current SEAs are based on mixtures of camphorquinone (CQ) and tertiaryamines (A) [5
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Graphical Abstract
Scheme 1:
Bisacylphosphine oxide with improved solubility in polar solvents.
Beilstein J. Org. Chem.2007,3, No. 43, doi:10.1186/1860-5397-3-43
progress to understand the exact mechanism of the reaction.
Conclusion
In conclusion, we have demonstrated that N-phenyl-3-substituted pyrazolones can be used for the intramolecular alpha-cyclisation of tertiaryamines [33] for the synthesis of pyrazolinoquinolizine and 1,4-oxazinopyrazoline derivatives in