A biphasic oxidation of alcohols to aldehydes and ketones using a simplified packed- bed microreactor

• Andrew Bogdan and
• D. Tyler McQuade

Beilstein J. Org. Chem. 2009, 5, No. 17, doi:10.3762/bjoc.5.17

• potential as continuous flow processes. Realizing this, we developed a catalytic packed-bed microreactor that could be used for the continuous flow oxidation of alcohols to aldehydes or ketones. Oxidations that do not require transition metal catalysts are particularly appealing since there is neither

An exceptional P-H phosphonite: Biphenyl- 2,2'-bisfenchylchlorophosphite and derived ligands (BIFOPs) in enantioselective copper- catalyzed 1,4-additions

• T. Kop-Weiershausen,
• J. Lex,
• J.-M. Neudörfl and
• B. Goldfuss

Beilstein J. Org. Chem. 2005, 1, No. 6, doi:10.1186/1860-5397-1-6

• ; Introduction Chiral monodentate phosphorus ligands with C2-symmetric diol backbones, e.g. with the prominent BINOLs or TADDOLs, are fundamental for the construction of efficient enantioselective transition metal catalysts, especially for copper-catalyzed 1,4-additions. [1][2][3][4][5][6][7][8][9][10][11][12