Beilstein J. Org. Chem.2017,13, 2800–2818, doi:10.3762/bjoc.13.273
; trifluoromethylation; trifluoromethylsulfenylation; trifluoromethylsufinylation; trifluoromethylsulfonylation; Introduction
In the preceding paper, we described the various uses of sodium trifluoromethanesulfinate in direct trifluoromethylation, trifluoromethylsulfenylation, trifluoromethylsufinylation and
of the substrates, paved the way to a dramatic acceleration of discoveries in the field. In addition, the recent breakthrough methods for direct trifluoromethylsufenylation and trifluoromethylsufinylation offer alternative accesses to SCF3 and S(O)CF3 compounds, respectively, bypassing the use of
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Graphical Abstract
Scheme 1:
Trifluoromethylation of silyl enol ethers.