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1 article(s) from Busche, Martin

From lithium to sodium: cell chemistry of room temperature sodium–air and sodium–sulfur batteries

Philipp Adelhelm,
Pascal Hartmann,
Conrad L. Bender,
Martin Busche,
Christine Eufinger and
Juergen Janek

Beilstein J. Nanotechnol. 2015, 6, 1016–1055, doi:10.3762/bjnano.6.105

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Figure 1: Theoretical and (estimated) practical energy densities of different rechargeable batteries: Pb–acid...

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Figure 2: Operating principles of (a) a lithium-ion battery, (b) a metal–oxygen battery (non-aqueous electrol...

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Figure 3: (a) The Li–O phase diagram. (b) The Na–O phase diagram. Figure redrawn based on [18] and [19].

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Figure 4: Matrix for classifying voltage profiles of metal–oxygen batteries. Type 1A is the ideal case. Frequ...

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Figure 5: DEMS analysis of Li/O₂ cells with different electrolyte compositions, namely a mixture of propylene...

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Figure 6: Sketch by Thotiyl et al. illustrating their findings on the oxidation of the carbon electrode. At d...

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Figure 7: SEM image of toroidal Li₂O₂ nanoparticles on a carbon fiber (10 µm in diameter) that form as a disc...

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Figure 8: Illustration of TEMPO as a redox mediator (RM) in an Li/O₂ cell reversibly catalyzing the Li₂O₂ oxi...

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Figure 9: Literature timeline of research papers on aprotic sodium–oxygen batteries (ranked after date of acc...

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Figure 10: Sketch of the first room temperature sodium–oxygen cell and its discharge and charge potentials dur...

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Figure 11: Discharge/charge curves (Type 1B) of a sodium–oxygen battery with NaO₂ as discharge product. The ma...

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Figure 12: The thermodynamic landscape of (a) sodium– and (b) lithium–oxygen cells. All values are calculated ...

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Figure 13: Voltage hysteresis of different carbon materials for the cathode of a sodium oxygen cell (left), fi...

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Figure 14: Voltage profiles of Na/O₂ cells under static gas atmosphere and flowing gas atmosphere (Type 1B/3B)...

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Figure 15: Literature overview on different studies of Na/O₂ cells. The comparison shows the voltage profile o...

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Figure 16: (a) The Li–S phase diagram. (b) The Na–S phase diagram. Redrawn from references [129,130]. The Na–S phase di...

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Figure 17: Schematic illustration of the reduction processes at the negative electrode during discharge of a L...

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Figure 18: Schematic illustration of the polysulfide shuttle mechanism after Mikhaylik and Akridge [123]. Long poly...

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Figure 19: Typical voltage profile of a lithium/sulfur cell. A similar behavior can be expected for an analogo...

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Figure 20: Schematic diagram of the interconnected pore structure of mesoporous CMK-3 impregnated with sulfur ...

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Figure 21: Operando X-ray absorption near-edge spectroscopy (XANES) measurements (left) during first charge an...

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Figure 22: Literature timeline of research papers on room temperature Na/S₈ batteries (ranked after date of ac...

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Figure 23: (a) First discharge–charge curve of a Na/S₈ battery with liquid electrolyte at room temperature and...

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Figure 24: (a) Voltage profiles a of Na/S₈ cells with a TEGDME-based electrolyte and a nanostructured carbon/s...

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Figure 25: Room temperature sodium–sulfur battery based on shallow cycling between sulfur and soluble long cha...

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Figure 26: Literature overview on different studies of Na/S₈ cells with liquid electrolyte operating at room t...

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Review

Published 23 Apr 2015

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