4 article(s) from Fairbrother, D. Howard
- Full Research Paper
- Published 14 Feb 2018
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Figure 1: Structural arrangement of HFeCo3(CO)12 and H2FeRu3(CO)13 illustrating differences in symmetry and l...
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Figure 2: Isotope distribution of a) HFeCo3(CO)12 and b) H2FeRu3(CO)13. Isotope distribution for both compoun...
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Figure 3: Negative ion yield curves for the formation of a) [Fe(CO)n]− and b) [Ru(CO)n]− up on electron attac...
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Figure 4: Loss of Fe(CO)2 (panel a), Fe(CO)3 (panel b), Fe(CO)4 (panel c) and additional loss of up to 7 COs ...
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Figure 5: Negative ions formed through loss of Ru(CO)3 (panel a), Ru(CO)4 (panel b) and further loss of up to...
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Figure 6: Calculated spin density of the [H2FeRu3(CO)13]− anion; a) in the constrained geometry of neutral H2...
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Figure 7: Calculated MO diagrams of H2FeRu3(CO)13 and HFeCo3(CO)12. Red lines represent the unoccupied molecu...
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Figure 8: Electron impact ionization spectra of H2FeRu3(CO)13 recorded at electron energy of 70 eV, upper pan...
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Figure 9: Evolution of O 1s, Fe 2p and Ru 3d/C 1s XPS regions of a H2FeRu3(CO)13 film exposed to electron dos...
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Figure 10: Change in fractional coverage of oxygen atoms (red stars) and, Ru 3d5/2 peak position (blue open ci...
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Figure 11: Mass spectrum of neutral gas phase species desorbed from an H2FeRu3(CO)13 film during the course of...
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Figure 12: Changes in O 1s, Fe 2p and Ru 3d/C 1s XPS regions when an H2FeRu3(CO)13 film was exposed to electro...
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Figure 13: Initial decomposition/deposition of surface adsorbed H2FeRu3(CO)13 precursor, mediated by dissociat...
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Figure 14: Schematic showing the incorporation of partially decarbonylated intermediate of H2FeRu3(CO)13 into ...
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Figure 15: (a) AFM cross sections of deposits shown in the SEM micrograph (b) at the positions indicated by th...
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Figure 16: Transport measurements of as-grown Fe–Ru deposit and deposits grown under identical conditions afte...
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Supp. Info
- Full Research Paper
- Published 30 Nov 2017
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Figure 1: Negative halogen ion yield curves for dissociative electron attachment to 2′-chloro-1,1′-biphenyl (...
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Figure 2: XP spectra of the Cl 2p, Br 3p doublets and the I 3d5/2 peak regions of SAMs made of 2-Cl-BPT 2-Br-...
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Figure 3: (a) Raw XP spectra of the S 2p region of SAMs made from BPT, 2-Cl-BPT 2-Br-BPT and 2-I-BPT before a...
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Figure 4: Helium ion microscope (HIM) image of a transferred carbon nanomembrane (CNM) made using 3 min (1.8 ...
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- Full Research Paper
- Published 15 Nov 2017
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Figure 1: (a) Representative FEBID deposit created from cis-Pt(CO)2Cl2. Representative AES and EDS of “as-dep...
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Figure 2: (a) SEM image of a deposit created from cis-Pt(CO)2Cl2, and (b) corresponding EDS spectrum. (c) SEM...
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Figure 3: (a) PtCl2 deposit created from cis-Pt(CO)2Cl2; (b) corresponding EDS analysis. (c) SEM image of the...
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Figure 4: (a) SEM image of a PtCl2 deposit created from cis-Pt(CO)2Cl2, without any EDS analysis and prior to...
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Figure 5: SEM images of a deposit created from cis-Pt(CO)2Cl2: (a) prior to any treatment, and after (b) 48, ...
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Figure 6: AES for a deposit created from cis-Pt(CO)2Cl2 (top spectrum) and then subjected to alternating trea...
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Figure 7: AFM data for nanostructures created from MeCpPtMe3 using different total exposure times (TET) (per ...
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Figure 8: (a) Height of nanostructures created from MeCpPtMe3 as determined by AFM: as-deposited (black bar) ...
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Scheme 1: Hess cycle for electron purification of PtCl2. ∆H = −∆Hf PtCl2 + Cl2 bond dissociation enthalpy (BD...
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Scheme 2: Hess cycle for atomic hydrogen purification of PtCl2. ∆H = −∆Hf PtCl2 + H2 bond dissociation enthal...
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Supp. Info
- Review
- Published 16 Sep 2015
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Figure 1: Schematic representation of the FEBID process (reproduced with permission from [2], Copyright (2008) A...
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Figure 2: Schematic representation of elastic and inelastic scattering of high-energy primary electrons impin...
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Figure 3: Experimentally measured SE spectra from Ni(111) [6] irradiated by PEs with 400 eV impact energy (black...
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Figure 4: Simplified two-dimensional potential energy diagram for quasi-diatomic dissociation through electro...
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Figure 5: Simplified two-dimensional potential energy diagram for a quasi-diatomic dissociation through elect...
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Figure 6: Simplified two-dimensional potential energy diagram for a quasi-diatomic dissociation through elect...
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Figure 7: Energy-dependent relative cross sections (ion yields) of negative ion fragments produced by DEA to ...
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Figure 8: Positive ion mass spectrum of MeCpPtMe3 recorded with electron energy of 100 eV (reproduced with pe...
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Figure 9: Positive ion mass spectra of MeCpPtMe3 in the m/z range of 0–85 (reproduced with permission from Wn...
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Figure 10: Changes in the C/Pt ratio of a 3.16 nm thick film of MeCpPtMe3 adsorbed on a gold surface at 180 K ...
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Figure 11: a) A line of best fit to the cross section for methane desorption from MeCpPtMe3 adsorbed on a gold...
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Figure 12: Energy-dependent absolute cross sections for negative ion fragments produced by DEA to Pt(PF3)4 (re...
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Figure 13: Electron ionization FT-ICR mass spectrum of Pt(PF3)4 recorded at 20 eV incident electron energy (re...
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Figure 14: (a) Electron energy loss spectra of Pt(PF3)4 recorded at 0° angle with varying residual energies. T...
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Figure 15: Time-resolved mass spectra of gas phase PF3 (positive [PF2]+ ions produced by 70 eV electron impact...
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Figure 16: Electron dose dependence of the fractional coverage of Phosphorous (P/PD=0), Fluorine (F/FD=0) and ...
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Figure 17: Energy-dependent absolute DEA cross sections for Co(CO)3NO (reproduced with permission from [10], Copyr...
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Figure 18: Energy dependence of the partial cross sections for positive ion fragments formed from Co(CO)3NO (r...
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Figure 19: The partial cross sections for single CO loss through DEA (red solid line), for single CO loss thro...
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Figure 20: Predicted relative effective damage yield for single CO loss through DEA (red solid line), for sing...
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Figure 21: Positive ion (DI) mass spectra of (a) gas phase Co(CO)3NO, (b) volatile species desorbing from a 2....
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Figure 22: Electron dose dependence of the fractional coverage of carbon, oxygen and nitrogen from Co(CO)3NO a...
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