Nanostructured materials characterized by scanning photoelectron spectromicroscopy

• Matteo Amati,
• Alexey S. Shkvarin,
• Alexander I. Merentsov,
• Alexander N. Titov,
• María Taeño,
• David Maestre,
• Sarah R. McKibbin,
• Zygmunt Milosz,
• Ana Cremades,
• Rainer Timm and
• Luca Gregoratti

Beilstein J. Nanotechnol. 2025, 16, 700–710, doi:10.3762/bjnano.16.54

• few nanometers along the entire nanowire. For operando SPEM measurements, nanowires were transferred onto a prepatterned device template with flat, individually contacted Au/Ti electrodes deposited onto a SiO2/Si substrate, separated by a 1.5 µm wide insulating gap. Optical microscopy images of the

• nanowire surface. The measured binding energy shift amounts to 0.48 eV in the In 4d spectra and 0.47 eV in the P 2p spectra. Even though this is a significant and well-resolved shift, its value is surprisingly low compared with the InP band gap of 1.34 eV at room temperature. Similarly grown InP p–n

High-temperature epitaxial growth of tantalum nitride thin films on MgO: structural evolution and potential for SQUID applications

• Michelle Cedillo Rosillo,
• Oscar Contreras López,
• Jesús Antonio Díaz,
• Agustín Conde Gallardo and
• Harvi A. Castillo Cuero

Beilstein J. Nanotechnol. 2025, 16, 690–699, doi:10.3762/bjnano.16.53

• significant progress, a major challenge remains in discovering materials that exhibit superconductivity at higher, more practical temperatures. The efficient fabrication of materials with a low superconducting energy gap and an intermediate Tc is crucial for the development and enhancement of superconducting

• has a superconductive energy gap lower than that of NbN [7], the most commonly used material for single-photon detectors in the gigahertz range; hence, this material can be a better candidate for superconductive electronic devices. Depending on the amount of incorporated nitrogen, x, the tantalum

Nanoscale capacitance spectroscopy based on multifrequency electrostatic force microscopy

• Pascal N. Rohrbeck,
• Lukas D. Cavar,
• Franjo Weber,
• Peter G. Reichel,
• Mara Niebling and
• Stefan A. L. Weber

Beilstein J. Nanotechnol. 2025, 16, 637–651, doi:10.3762/bjnano.16.49

• study materials such as perovskite solar cells [18][19][20] and Li-ion batteries [21][22][23]. AFM enables simultaneous acquisition of topographic and electronic data by applying AC or DC voltages across the tip–sample gap, allowing for the detection of capacitive forces [24][25] or contact potential

• the gradient of the energy, WC, stored in the tip–sample capacitor C with respect to the tip–sample separation z, as given by where Vtip−sample specifies the electrical voltage across the tip–sample gap. In conventional EFM with single-frequency excitation, Vtip−sample is given by Equation 2 [18

• excitation signal that has to be considered in Equation 12. By using appropriate means of coupling the electrical excitation into the tip–sample gap, experiments at microwave or even at optical frequencies are possible. In our setup, the two excitation frequencies can be varied in frequency from ≈600 kHz up

A formulation containing Cymbopogon flexuosus essential oil: improvement of biochemical parameters and oxidative stress in diabetic rats

• Ailton Santos Sena-Júnior,
• Cleverton Nascimento Santana Andrade,
• Pedro Henrique Macedo Moura,
• Jocsã Hémany Cândido dos Santos,
• Cauãn Torres Trancoso,
• Eloia Emanuelly Dias Silva,
• Deise Maria Rego Rodrigues Silva,
• Ênio Pereira Telles,
• Luiz André Santos Silva,
• Isabella Lima Dantas Teles,
• Sara Fernanda Mota de Almeida,
• Daniel Alves de Souza,
• Jileno Ferreira Santos,
• Felipe José Aidar Martins,
• Ana Mara de Oliveira e Silva,
• Sandra Lauton-Santos,
• Guilherme Rodolfo Souza de Araujo,
• Cristiane Bani Correa,
• Rogéria De Souza Nunes,
• Lysandro Pinto Borges and
• Ana Amélia Moreira Lira

Beilstein J. Nanotechnol. 2025, 16, 617–636, doi:10.3762/bjnano.16.48

• behavior of the formulations was assessed by flow tests using the Modular Compact Rheometer (Anton Paar, MRC 302). A cone-plate geometry was used (diameter 49.9 mm, angle 1°, and gap 96 μm). The shear stress (γ) was evaluated as a function of the shear rate ranging from 0.1 to 200 s−1. The experiment was

Polyurethane/silk fibroin-based electrospun membranes for wound healing and skin substitute applications

• Iqra Zainab,
• Zohra Naseem,
• Syeda Rubab Batool,
• Muhammad Waqas,
• Ahsan Nazir and
• Muhammad Anwaar Nazeer

Beilstein J. Nanotechnol. 2025, 16, 591–612, doi:10.3762/bjnano.16.46

N₂⁺-implantation-induced tailoring of structural, morphological, optical, and electrical characteristics of sputtered molybdenum thin films

• Usha Rani,
• Kafi Devi,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 495–509, doi:10.3762/bjnano.16.38

• films. Despite these advances, a noticeable gap exists in the systematic exploration of nitrogen implantation with variations in the thickness of Mo films. To address this gap, this study employs an extensive approach, implementing low-energy nitrogen ion implantation with a systematic variation in film

Effect of additives on the synthesis efficiency of nanoparticles by laser-induced reduction

• Rikuto Kuroda,
• Takahiro Nakamura,
• Hideki Ina and
• Shuhei Shibata

Beilstein J. Nanotechnol. 2025, 16, 464–472, doi:10.3762/bjnano.16.35

• Au–Pt alloy (atomic ratio, Au/Pt = 1:1) that has an immiscible gap in the binary phase diagram and is difficult to form a solid–solution alloy in a bulk form. Figure 6 shows a a) TEM image and b) STEM-EDS mappings of the particles produced after laser irradiation. The TEM results (Figure 6a

Synthetic-polymer-assisted antisense oligonucleotide delivery: targeted approaches for precision disease treatment

• Ana Cubillo Alvarez,
• Dylan Maguire and
• Ruairí P. Brannigan

Beilstein J. Nanotechnol. 2025, 16, 435–463, doi:10.3762/bjnano.16.34

• activity and nucleic acid catalysis, effectively bridging the gap between short oligomers and functional RNAs under various environmental conditions. In addition to a delivery enhancer, PLL can be efficiently employed as an antisense oligonucleotide condenser. In their exploration of advanced drug delivery

Quantification of lead through rod-shaped silver-doped zinc oxide nanoparticles using an electrochemical approach

• Ravinder Lamba,
• Gaurav Bhanjana,
• Neeraj Dilbaghi,
• Vivek Gupta and
• Sandeep Kumar

Beilstein J. Nanotechnol. 2025, 16, 422–434, doi:10.3762/bjnano.16.33

• . The 23 eV gap between two binding energies suggests that the Zn element is in a +2 oxidation state. The 1s orbital spectra of oxygen in Ag–ZnO samples are shown in Figure 7c, revealing a peak with a binding energy of 528 eV. The oxygen peak can be resolved into two distinct peaks, which indicates two

ReactorAFM/STM – dynamic reactions on surfaces at elevated temperature and atmospheric pressure

• Tycho Roorda,
• Hamed Achour,
• Matthijs A. van Spronsen,
• Marta E. Cañas-Ventura,
• Sander B. Roobol,
• Willem Onderwaater,
• Mirthe Bergman,
• Peter van der Tuijn,
• Gertjan van Baarle,
• Johan W. Bakker,
• Joost W. M. Frenken and
• Irene M. N. Groot

Beilstein J. Nanotechnol. 2025, 16, 397–406, doi:10.3762/bjnano.16.30

• whether a given catalyst becomes reactive, is referred to as the pressure gap. To provide an interpretive framework for catalysts under industrial conditions, new experimental and theoretical analysis tools are required. While recent years have witnessed a tremendous effort in this direction [3], many of

• these techniques are photon-based [4][5][6][7][8][9]. Even though they provide valuable insights, the development of surface-sensitive techniques that can image the catalyst at the atomic scale under high-pressure and high-temperature conditions remains crucial. In attempting to close the pressure gap

• ]. Alongside the pressure gap, the existence of the materials gap refers to the complexity and heterogeneity of real catalysts. Such catalysts are compounds that possess a special complex mixture consisting essentially of metals, oxides, and promoters, supported on refractory oxides. The requirement of a

Vortex lattices of layered HTSCs at different vortex–vortex interaction potentials

• Valerii P. Lenkov,
• Anastasia N. Maksimova,
• Anna N. Moroz and
• Vladimir A. Kashurnikov

Beilstein J. Nanotechnol. 2025, 16, 362–370, doi:10.3762/bjnano.16.27

• superconductors have a layered structure and can be modeled as a stack of superconducting planes separated by an insulating gap. The Abrikosov vortex in such a structure can be represented as a stack of flat layered vortices, the so-called pancakes, connected by an interplanar bond. In samples that do not have

Pulsed laser in liquid grafting of gold nanoparticle–carbon support composites

• Madeleine K. Wilsey,
• Teona Taseska,
• Qishen Lyu,
• Connor P. Cox and
• Astrid M. Müller

Beilstein J. Nanotechnol. 2025, 16, 349–361, doi:10.3762/bjnano.16.26

• , and the reference electrode was a reversible hydrogen electrode (Gaskatel HydroFlex®). Chronopotentiometry data were collected for 12 h at −10 mA·cm−2, provided by a Bio-Logic SP-150-EIS potentiostat, in a custom-made small-gap H-cell obtained from the Jaramillo group at Stanford University [82]. A

Tailoring of physical properties of RF-sputtered ZnTe films: role of substrate temperature

• Kafi Devi,
• Usha Rani,
• Arun Kumar,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 333–348, doi:10.3762/bjnano.16.25

• with energy lower than the excitation photon energy are emitted. The recombination can occur either from band to band or through impurities and defects present within an energy level inside the forbidden gap. Grain boundaries are responsible for non-radiative recombination processes. For the present

Preferential enrichment and extraction of laser-synthesized nanoparticles in organic phases

• Theo Fromme,
• Maximilian L. Spiekermann,
• Florian Lehmann,
• Stephan Barcikowski,
• Thomas Seidensticker and
• Sven Reichenberger

Beilstein J. Nanotechnol. 2025, 16, 254–263, doi:10.3762/bjnano.16.20

• unaddressed in literature. To tackle this knowledge gap, the present study investigates the phase preference of laser-generated noble metal (Au and Ag) and base metal (Cu, Fe, Al and Ti) nanoparticles within propylene carbonate/alcohol (PC/A) systems. Alcohols of increasing chain length (C6–C11) and hence

• , polarity of the solvent, or even physical attributes (e.g., boiling point), phase transfer methods are essential. To close this knowledge gap, we have performed ablation of six different metals (Au, Ag, Cu, Fe, Al, and Ti) ranging from high to low standard electrochemical reduction potentials in a

Nanocarriers and macrophage interaction: from a potential hurdle to an alternative therapeutic strategy

• Naths Grazia Sukubo,
• Paolo Bigini and
• Annalisa Morelli

Beilstein J. Nanotechnol. 2025, 16, 97–118, doi:10.3762/bjnano.16.10

Instance maps as an organising concept for complex experimental workflows as demonstrated for (nano)material safety research

• Benjamin Punz,
• Maja Brajnik,
• Joh Dokler,
• Jaleesia D. Amos,
• Litty Johnson,
• Katie Reilly,
• Anastasios G. Papadiamantis,
• Amaia Green Etxabe,
• Lee Walker,
• Diego S. T. Martinez,
• Steffi Friedrichs,
• Klaus M. Weltring,
• Nazende Günday-Türeli,
• Claus Svendsen,
• Christine Ogilvie Hendren,
• Mark R. Wiesner,
• Martin Himly,
• Iseult Lynch and
• Thomas E. Exner

Beilstein J. Nanotechnol. 2025, 16, 57–77, doi:10.3762/bjnano.16.7

• which controls), as part of good research output management, is necessary to maximise the reuse potential and value of the data. Instance maps have been developed and evolved to visualise experimental nanosafety workflows and to bridge the gap between the theoretical principles of FAIR (Findable

• coronas, where the documentation of the nanomaterials’ dispersion and corona formation steps was very complete, but the description of the protein isolation and informatics steps was much less complete. This gap in documentation was attributed to the fact that the omics analyses are often performed by

Theoretical study of the electronic and optical properties of a composite formed by the zeolite NaA and a magnetite cluster

• Joel Antúnez-García,
• Roberto Núñez-González,
• Vitalii Petranovskii,
• H’Linh Hmok,
• Armando Reyes-Serrato,
• Fabian N. Murrieta-Rico,
• Mufei Xiao and
• Jonathan Zamora

Beilstein J. Nanotechnol. 2025, 16, 44–53, doi:10.3762/bjnano.16.5

• characteristics for specific applications within the visible spectrum. Conclusion In this work, the influence of the inclusion of a magnetite cluster into NaA zeolite is studied through DFT calculations. The findings reveal that the cluster not only introduces states into the forbidden energy gap of the zeolite

Mechanistic insights into endosomal escape by sodium oleate-modified liposomes

• Ebrahim Sadaqa,
• Satrialdi,
• Fransiska Kurniawan and
• Diky Mudhakir

Beilstein J. Nanotechnol. 2024, 15, 1667–1685, doi:10.3762/bjnano.15.131

• simulations bridge the gap between experimental observations and mechanistic understanding. They also provide a robust framework for designing and optimizing innovative strategies for endosomal escape. Understanding these molecular interactions is akin to solving a complex puzzle, where each detail

• contributes to a comprehensive picture of overcoming endosomal entrapment. This study aims to bridge the knowledge gap by investigating the potential of SO in enhancing endosomal escape and elucidating the underlying mechanisms. We employ a multifaceted approach, combining in vitro experimentation, using 4T1

The round-robin approach applied to nanoinformatics: consensus prediction of nanomaterials zeta potential

• Dimitra-Danai Varsou,
• Arkaprava Banerjee,
• Joyita Roy,
• Kunal Roy,
• Giannis Savvas,
• Haralambos Sarimveis,
• Ewelina Wyrzykowska,
• Mateusz Balicki,
• Tomasz Puzyn,
• Georgia Melagraki,
• Iseult Lynch and
• Antreas Afantitis

Beilstein J. Nanotechnol. 2024, 15, 1536–1553, doi:10.3762/bjnano.15.121

• [48]. Both the QSPR and read-across approaches are extensively used for data gap filling (predicting activity/property/toxicity values of compounds devoid of experimentally derived endpoint values). Recently, Luechtefeld et al. [49] introduced the concept of classification-based read-across structure

Integrating high-performance computing, machine learning, data management workflows, and infrastructures for multiscale simulations and nanomaterials technologies

• Fabio Le Piane,
• Mario Vozza,
• Matteo Baldoni and
• Francesco Mercuri

Beilstein J. Nanotechnol. 2024, 15, 1498–1521, doi:10.3762/bjnano.15.119

• horizontal technologies to a vertical integration to the materials science domain see Figure 3. The successful implementation of digital strategies for materials/nanomaterials development relies on the crucial role of “translators” who bridge the gap between domain-specific researchers and digital technology

Polymer lipid hybrid nanoparticles for phytochemical delivery: challenges, progress, and future prospects

• Iqra Rahat,
• Pooja Yadav,
• Aditi Singhal,
• Mohammad Fareed,
• Jaganathan Raja Purushothaman,
• Mohammed Aslam,
• Raju Balaji,
• Sonali Patil-Shinde and
• Md. Rizwanullah

Beilstein J. Nanotechnol. 2024, 15, 1473–1497, doi:10.3762/bjnano.15.118

Effect of radiation-induced vacancy saturation on the first-order phase transformation in nanoparticles: insights from a model

• Aram Shirinyan and
• Yuriy Bilogorodskyy

Beilstein J. Nanotechnol. 2024, 15, 1453–1472, doi:10.3762/bjnano.15.117

• have identified only a few papers proposing a thermodynamic assessment [17][18][19][20]. Our aim in this work is to fill this gap. Shen’s proposed qualitative framework suggests that the grain size of a material influences its resistance to amorphization and the removal of radiation defects by altering

Strain-induced bandgap engineering in 2D ψ-graphene materials: a first-principles study

• Kamal Kumar,
• Nora H. de Leeuw,
• Jost Adam and
• Abhishek Kumar Mishra

Beilstein J. Nanotechnol. 2024, 15, 1440–1452, doi:10.3762/bjnano.15.116

• (EBSs)) of these materials becomes essential to expand their utility in energy-related and optoelectronic applications [18][19]. Engineering of the electronic gap not only broadens the possible use of 2D materials but also enables them to satisfy the demand for ultramodern technologies [20]. Bandgap

• , we performed EBS and density of states (DOS) calculations (Figure 1) alongside projected orbital calculations of the different atoms to understand their contributions to the electronic states. Our calculations reveal no gap between the energy bands in both ψ-graphene and ψ-graphone (Figure 1a,b

• the lattice plane, while a negative strain of −14% generates a gap of 0.2 eV between its energy bands. Structural and electronic properties of ψ-graphone with strain We tabulate the structural parameters, buckling heights, and electronic bandgap values of all strained structures in Table 3. Positive

Nanoarchitectonics with cetrimonium bromide on metal nanoparticles for linker-free detection of toxic metal ions and catalytic degradation of 4-nitrophenol

• Akash Kumar and
• Raja Gopal Rayavarapu

Beilstein J. Nanotechnol. 2024, 15, 1312–1332, doi:10.3762/bjnano.15.106

• highly depend on various factors, including size, shape, and reaction parameters [34]. However, there was a gap in the literature regarding which factor is most crucial to the efficient degradation of 4-nitrophenol using nanoparticles. Some studies suggest size is essential, while others suggest pH

• the case of CTAB-AuNS due to tightly bound CTAB. However, in the case of CTAB-AuNR1, CTAB is tightly bound to the flat side and show an intermicellar gap at the curvature. The curvature allows for metal interaction only after adding a specific amount of NaOH. The nanoparticles (as-prepared AuNR10.5

Introducing third-generation periodic table descriptors for nano-qRASTR modeling of zebrafish toxicity of metal oxide nanoparticles

• Supratik Kar and
• Siyun Yang

Beilstein J. Nanotechnol. 2024, 15, 1142–1152, doi:10.3762/bjnano.15.93

• -randomization procedure, the study calculated the mean values of R2 and Q2 for the 100 randomly generated models. External dataset for data gap filling and prediction reliability Our prepared external dataset consists of 35 MONPs that were used to predict toxicity for zebrafish. External prediction quality is

• 35 diverse MONPs as external dataset also helped to fill the toxicity data gap of zebrafish. The model’s capability to identify compounds with potentially high toxicity offers a pathway to preemptively address the environmental risk assessment and health impacts of nanomaterials. However, only a