Photocatalytic methane oxidation over a TiO₂/SiNWs p–n junction catalyst at room temperature

• Qui Thanh Hoai Ta,
• Luan Minh Nguyen,
• Ngoc Hoi Nguyen,
• Phan Khanh Thinh Nguyen and
• Dai Hai Nguyen

Beilstein J. Nanotechnol. 2024, 15, 1132–1141, doi:10.3762/bjnano.15.92

• ) [43][44]. As expected, the crystal orientation of the TiO2/SiNWs catalyst obviously led to the creation of a robust p–n junction photocatalyst. The SEM analysis further confirms the morphological evolution during etching and TiO2 ALD. As revealed in Supporting Information File 1, Figure S1, the

Direct electron beam writing of silver using a β-diketonate precursor: first insights

• Katja Höflich,
• Krzysztof Maćkosz,
• Chinmai S. Jureddy,
• Aleksei Tsarapkin and
• Ivo Utke

Beilstein J. Nanotechnol. 2024, 15, 1117–1124, doi:10.3762/bjnano.15.90

• , which lead to the pronounced deposition of halos. In addition, all require relatively high substrate temperatures (well above 100 °C) in order to avoid condensation. Hence, thermal effects are expected to play an important role in deposit shape evolution with the enhanced desorption rates contributing

• . Compared to the typically obtained granular structure of metallic nanoparticles in a carbonaceous matrix, the deposit composition and chemistry evolution are unexpected. The resulting deposit exhibits a carbon-rich body with a surface decorated with silver nanoparticles and an interfacial layer of

• deposition of an automated sequence of shapes overnight, carefully avoiding unintended electron beam impact while precursor molecules were present (cf. the section on deposit evolution in Supporting Information File 1 for more details). The high-resolution images presented in the main manuscript were taken

Unveiling the potential of alginate-based nanomaterials in sensing technology and smart delivery applications

• Shakhzodjon Uzokboev,
• Khojimukhammad Akhmadbekov,
• Ra’no Nuritdinova,
• Salah M. Tawfik and
• Yong-Ill Lee

Beilstein J. Nanotechnol. 2024, 15, 1077–1104, doi:10.3762/bjnano.15.88

• , especially biopolymer nanoparticles, are applied to drug delivery methods, the aforementioned drawbacks faced by traditional drug delivery today can be overcome. The evolution of nanoparticle-based drug delivery techniques Drug delivery via nanoparticles has transformed the world of medicine in recent

Effect of wavelength and liquid on formation of Ag, Au, Ag/Au nanoparticles via picosecond laser ablation and SERS-based detection of DMMP

• Sree Satya Bharati Moram,
• Chandu Byram and
• Venugopal Rao Soma

Beilstein J. Nanotechnol. 2024, 15, 1054–1069, doi:10.3762/bjnano.15.86

• SERS substrate over 60 days. We carried out systematic SERS measurements on different days, and their SERS intensities are compared concerning the days for the substrates, namely AgD3, AgAuD3, AuD3, AgN3, AgAuN3, and AuN3. The evolution of signal intensities over the 60 days is graphically depicted in

Ca_n neutral clusters: a two-step G₀W₀ and DFT benchmark

• Sunila Bakhsh,
• Sameen Aslam,
• Muhammad Khalid,
• Muhammad Sohail,
• Sundas Zafar,
• Sumayya Abdul Wadood,
• Kareem Morsy and
• Muhammad Aamir Iqbal

Beilstein J. Nanotechnol. 2024, 15, 1010–1016, doi:10.3762/bjnano.15.82

• is also called “the maximum hardness principle” [28]. From these three results we can see that the oscillatory pattern is moderated with the evolution of the cluster size. However, the majority of the values of IPs, EAs, and Egap are positive and following closely which suggests a clear correlation

Recent progress on field-effect transistor-based biosensors: device perspective

• Billel Smaani,
• Fares Nafa,
• Mohamed Salah Benlatrech,
• Ismahan Mahdi,
• Hamza Akroum,
• Mohamed walid Azizi,
• Khaled Harrar and
• Sayan Kanungo

Beilstein J. Nanotechnol. 2024, 15, 977–994, doi:10.3762/bjnano.15.80

• biosensors, and to study temperature effects on 2D and 3D FET-based biosensors. Conclusion This review introduces the significant evolution of FET-based biosensors. Various novel architectures of FET-based biosensors are summarized, providing valuable insights for enhancing sensitivity and designing

Effects of cutting tool geometry on material removal of a gradient nanograined CoCrNi medium entropy alloy

• Yu-Sheng Lu,
• Yu-Xuan Hung,
• Thi-Xuyen Bui and
• Te-Hua Fang

Beilstein J. Nanotechnol. 2024, 15, 925–940, doi:10.3762/bjnano.15.76

• and partial dislocation motions in crystalline materials were examined by common neighbor analysis (CNA) of the modules in OVITO. Cutting force, shear strain distribution, von Mises stress analysis, crystal structure evolution, temperature distribution, and calculation of material wear rate were

• radius was fixed at 1 nm to analyze the surface morphology, atomic-scale wear, shear strain distribution, temperature distribution, and crystal structure evolution during cutting. Figure 2a–f shows the atoms that pile-up on the surface of the CoCrNi MEA substrates. The number of wear atoms during cutting

• highest temperature at this position. Samples with small grain gradients, corresponding to a higher number of amorphous atoms, exhibit an increase in mixture disorder of the atoms, leading to higher kinetic energy, which generates more thermal energy [34]. Figure 7 displays the crystal structure evolution

Investigation on drag reduction on rotating blade surfaces with microtextures

• Qinsong Zhu,
• Chen Zhang,
• Fuhang Yu and
• Yan Xu

Beilstein J. Nanotechnol. 2024, 15, 833–853, doi:10.3762/bjnano.15.70

• ; Introduction In order to survive, organisms in nature have undergone billions of years of evolution; their body structures have been adapted to the current environment and exhibit special functions on biological surfaces [1]. For the purpose of drag reduction, valuable inspiration can be derived from rapidly

Exploring surface charge dynamics: implications for AFM height measurements in 2D materials

• Mario Navarro-Rodriguez,
• Andres M. Somoza and
• Elisa Palacios-Lidon

Beilstein J. Nanotechnol. 2024, 15, 767–780, doi:10.3762/bjnano.15.64

• data point, tp ≈ 10−3 s, yields two opposite situations. For GO, tp < τGO, the surface charge distribution does not reach the equilibrium configuration during the acquisition time, while for rGO, tp ≫ τrGO, measurements are carried out in equilibrium. It is important to note that the time evolution in

• Equation 8 is entirely a consequence of a non-negligible σs; if we set σs = 0, the time evolution cancels, and we recover the expected solution for a dielectric interface. When the tip oscillates or an AC voltage is applied, the oscillating electric field produces Joule dissipation at the surface as well

Green synthesis of biomass-derived carbon quantum dots for photocatalytic degradation of methylene blue

• Dalia Chávez-García,
• Mario Guzman,
• Viridiana Sanchez and
• Rubén D. Cadena-Nava

Beilstein J. Nanotechnol. 2024, 15, 755–766, doi:10.3762/bjnano.15.63

• optoelectronic characteristics of the synthesized CQDs, UV–vis absorption spectra were measured using a Thermo Scientific Evolution 220 spectrophotometer. The CQDs were dissolved in deionized water at a ratio of 1:10 (0.3 mg of CQDs per mL) and the measurements were taken in the range of 200–800 nm. A 1 cm path

• value of the reaction mixture was kept constant during the test (pH 7). To initiate the catalytic process, each CQD sample was individually applied to the degradation of the MB dye. The UV–vis absorption spectrum of the dye was monitored using a spectrophotometer (Thermo Scientific Evolution model 220

Level set simulation of focused ion beam sputtering of a multilayer substrate

• Alexander V. Rumyantsev,
• Nikolai I. Borgardt,
• Roman L. Volkov and
• Yuri A. Chaplygin

Beilstein J. Nanotechnol. 2024, 15, 733–742, doi:10.3762/bjnano.15.61

• Alexander V. Rumyantsev Nikolai I. Borgardt Roman L. Volkov Yuri A. Chaplygin National Research University of Electronic Technology - MIET, Bld. 1, Shokin Square, Zelenograd, Moscow, 124498, Russia 10.3762/bjnano.15.61 Abstract The evolution of a multilayer sample surface during focused ion beam

• only possible for shallow structures milled under constant sputtering yield conditions [18][19][20]. For more complex cases, one has to turn to various kinds of computer simulations that considerably facilitate structure fabrication using FIB. For example, surface evolution was studied using segment

• to take into account ion beam-induced redistribution and intermixing of atoms from different layers, were considered less frequently. Some of the examples include analytical estimations of the depth of bilayer substrates [26] and cell-based simulations of surface evolution and ion implantation using

Functional fibrillar interfaces: Biological hair as inspiration across scales

• Guillermo J. Amador,
• Brett Klaassen van Oorschot,
• Caiying Liao,
• Jianing Wu and
• Da Wei

Beilstein J. Nanotechnol. 2024, 15, 664–677, doi:10.3762/bjnano.15.55

• 200 million years of independent evolution, feathers and hair follicles share numerous structural similarities, including the presence of a dermal papilla and a dermal sheath [71]. However, unlike hair, feathers also have a dermal pulp, which is essential in growth and regeneration during feather

• classifications. Future research linking form and function in microbial hairs may lead to a better understanding of their evolution, as well as providing inspiration for the development of functional fibrillar structures at the micrometer and nanometer scales. Filter feeding Locomotion is key for searching for

Laser synthesis of nanoparticles in organic solvents – products, reactions, and perspectives

• Theo Fromme,
• Sven Reichenberger,
• Katharine M. Tibbetts and
• Stephan Barcikowski

Beilstein J. Nanotechnol. 2024, 15, 638–663, doi:10.3762/bjnano.15.54

• will be discussed first, followed by hydrocarbons and carbonaceous products. Permanent gas evolution during LSPC Compared to water, the laser irradiation of organic solvents (in the absence of nanoparticles) leads to decomposition reactions that form permanent gases. Baymler et al. irradiated water

• , ethanol, isopropyl alcohol, diethyl ether, and isobutanol with nanosecond laser pulses while quantifying the formed hydrogen pressure with amperometric sensors. The organic alcohols, while having a lower number of hydrogen atoms per molecule, showed a ten times higher hydrogen evolution rate than water

• [45]. Additionally, the molecular structure of the solvent affects the hydrogen evolution rate. Ethanol and isopropyl alcohol produced greater hydrogen yields than isobutyl alcohol and diethyl ether, which was attributed to the higher ratio of hydrogen to carbon and, thus, more C–H bonds relative to C

Stiffness calibration of qPlus sensors at low temperature through thermal noise measurements

• Laurent Nony,
• Sylvain Clair,
• Daniel Uehli,
• Aitziber Herrero,
• Jean-Marc Themlin,
• Andrea Campos,
• Franck Para,
• Alessandro Pioda and
• Christian Loppacher

Beilstein J. Nanotechnol. 2024, 15, 580–602, doi:10.3762/bjnano.15.50

Electron-induced deposition using Fe(CO)₄MA and Fe(CO)₅ – effect of MA ligand and process conditions

• Hannah Boeckers,
• Atul Chaudhary,
• Petra Martinović,
• Amy V. Walker,
• Lisa McElwee-White and
• Petra Swiderek

Beilstein J. Nanotechnol. 2024, 15, 500–516, doi:10.3762/bjnano.15.45

• ascribed to C–H bond cleavage within the MA ligand or in potential products formed from MA during electron irradiation. A second ESD experiment was performed under the same conditions to record the time evolution of specific m/z ratios during irradiation (Figure 3). Three irradiation steps of 2000 µC/cm2

Sidewall angle tuning in focused electron beam-induced processing

• Sangeetha Hari,
• Willem F. van Dorp,
• Johannes J. L. Mulders,
• Piet H. F. Trompenaars,
• Pieter Kruit and
• Cornelis W. Hagen

Beilstein J. Nanotechnol. 2024, 15, 447–456, doi:10.3762/bjnano.15.40

• etching the deposit from below, resulting in under-etched structures. The evolution of the sidewall angle during etching has also been experimentally observed in a scanning electron microscope by continuously monitoring the secondary electron detector signal. Keywords: electron lithography; FEBID; FEBIE

• incidence x [9]; thus, the etching is enhanced by the same factor. Directing the beam to a fixed position on the sloped sidewall, the Gaussian profile, multiplied by the local SE-yield enhancement factor, governs the etching of the deposit, given a fixed etching strength. Figure 2b illustrates the evolution

• , section S1 for more details on the simulation). Sidewall slope evolution under FEBIE To experimentally study the modification of the sidewalls of a FEBID structure, carbon structures were first deposited on a silicon substrate with a 20 nm gold–palladium layer and a 5 nm titanium adhesion layer. The

Heat-induced morphological changes in silver nanowires deposited on a patterned silicon substrate

• Elyad Damerchi,
• Sven Oras,
• Edgars Butanovs,
• Allar Liivlaid,
• Mikk Antsov,
• Boris Polyakov,
• Annamarija Trausa,
• Veronika Zadin,
• Andreas Kyritsakis,
• Loïc Vidal,
• Karine Mougin,
• Siim Pikker and
• Sergei Vlassov

Beilstein J. Nanotechnol. 2024, 15, 435–446, doi:10.3762/bjnano.15.39

• affect the outcome of the experiment since in any case defects caused by heating/cooling (hence, tensile compression) cycles will result in reduced thermal stability of the suspended part compared to the adhered part. Note that, as mentioned earlier, the morphology evolution in the adhered parts is

• of the NW with subsequent evolution into necking and finally splitting (Figure 9b, Figure 9c). It should be noted that the goal of the MD simulations was only to qualitatively evaluate the role of the thermomechanically induced defects in the fragmentation of five-fold twinned Ag NWs. Therefore, the

Unveiling the nature of atomic defects in graphene on a metal surface

• Karl Rothe,
• Nicolas Néel and
• Jörg Kröger

Beilstein J. Nanotechnol. 2024, 15, 416–425, doi:10.3762/bjnano.15.37

• presence of graphene [48]. The -shaped feature with minimum signal slightly below zero bias may be associated with the Dirac cone at the BZ -point. Figure 1d reveals the spatial evolution of the spectra, which shows a gradual quenching of the Ir(111) surface resonance signal accompanied by a small shift

• ). The lateral evolution of the dI/dV spectra hints at a markedly different character of defects 1 and 2, which will further be explored on the basis of the AFM results to be discussed below. They will clarify structural aspects of the defects and help understand the different spectroscopic properties

• an Ar+-induced Ir(111) surface defect [57]. In a next step, AFM imaging of the defects at different tip–surface distances was complemented by spatially resolved Δf(Δz) measurements (Figure 4). Figure 4a shows the evolution of the total vertical force recorded along the path across a type-1 defect

Classification and application of metal-based nanoantioxidants in medicine and healthcare

• Nguyen Nhat Nam,
• Nguyen Khoi Song Tran,
• Tan Tai Nguyen,
• Nguyen Ngoc Trai,
• Nguyen Phuong Thuy,
• Hoang Dang Khoa Do,
• Nhu Hoa Thi Tran and
• Kieu The Loan Trinh

Beilstein J. Nanotechnol. 2024, 15, 396–415, doi:10.3762/bjnano.15.36

• nanotechnology, especially for reducing oxidative stress. Review Metal-based nanomaterials exhibiting antioxidant activities Preventive metal-based nanoantioxidants Along the evolution, the human body has naturally developed a complex antioxidant defense system, which uses endogenous non-enzymatic and enzymatic

Investigating ripple pattern formation and damage profiles in Si and Ge induced by 100 keV Ar⁺ ion beam: a comparative study

• Indra Sulania,
• Harpreet Sondhi,
• Tanuj Kumar,
• Sunil Ojha,
• G R Umapathy,
• Ambuj Mishra,
• Ambuj Tripathi,
• Richa Krishna,
• Devesh Kumar Avasthi and
• Yogendra Kumar Mishra

Beilstein J. Nanotechnol. 2024, 15, 367–375, doi:10.3762/bjnano.15.33

• displays two steps corresponding to the backscattering from Si and Ar for channel numbers ≈1050 and ≈1275, respectively. Defect clustering may lead to a subsequent increase of the damage peak in irradiated samples as compared to that of pristine Si and Ge samples. To understand the evolution of the lattice

Nanomedicines against Chagas disease: a critical review

• Maria Jose Morilla,
• Kajal Ghosal and
• Eder Lilia Romero

Beilstein J. Nanotechnol. 2024, 15, 333–349, doi:10.3762/bjnano.15.30

• 2025 driven by the evolution of vaccines against COVID-19 based on nanomedicines and the projected huge global demand for these products [105]. However, the clinical translatability of nanomedicines is still complex. Consider, for instance, the liposomal formulation of the antifungal amphotericin B

Investigating structural and electronic properties of neutral zinc clusters: a G₀W₀ and G₀W₀Г₀⁽¹⁾ benchmark

• Sunila Bakhsh,
• Muhammad Khalid,
• Sameen Aslam,
• Muhammad Sohail,
• Muhammad Aamir Iqbal,
• Mujtaba Ikram and
• Kareem Morsy

Beilstein J. Nanotechnol. 2024, 15, 310–316, doi:10.3762/bjnano.15.28

• PBE functional. The binding energies show the two-knee behavior also seen in metal clusters of various species. Electronic properties, such as IP, EA, and the relative hardness of the clusters, have been obtained using the G0W0@PBE in FHI-aims. The IP benchmark shows the size evolution behavior of the

Determining by Raman spectroscopy the average thickness and N-layer-specific surface coverages of MoS₂ thin films with domains much smaller than the laser spot size

• Felipe Wasem Klein,
• Jean-Roch Huntzinger,
• Vincent Astié,
• Damien Voiry,
• Romain Parret,
• Houssine Makhlouf,
• Sandrine Juillaguet,
• Jean-Manuel Decams,
• Sylvie Contreras,
• Périne Landois,
• Ahmed-Azmi Zahab,
• Jean-Louis Sauvajol and
• Matthieu Paillet

Beilstein J. Nanotechnol. 2024, 15, 279–296, doi:10.3762/bjnano.15.26

• Supporting Information File 1, the frequency and the linewidth of the Si mode as functions of the laser power are displayed (Figure S2). These two parameters are found to be insensitive to Pλ below 0.5 mW. More intriguing is the evolution of the frequency (Figure 2a) and width (Figure 2b) of the phonon modes

• expected by considering a simple thermal effect. Consequently, the results reported in Figure 2c clearly evidence photo-doping of 1L-MoS2 concomitant with a thermal effect, as already observed for MoS2 on SiO2/Si [45] as well as for graphene [42]. Furthermore, the evolution of the A′1 and E′ widths with Pλ

Ultrasensitive and ultrastretchable metal crack strain sensor based on helical polydimethylsiloxane

• Shangbi Chen,
• Dewen Liu,
• Weiwei Chen,
• Huajiang Chen,
• Jiawei Li and
• Jinfang Wang

Beilstein J. Nanotechnol. 2024, 15, 270–278, doi:10.3762/bjnano.15.25

• Figure 1c. Concurrently, the microcracks propagate into channel cracks that traverse the entire width of the sample, as illustrated in Figure 1d. The crack structure evolution of the helix metal film under tensile strain ranging from 0 to 300% was observed using an optical microscope, as depicted in

Ion beam processing of DNA origami nanostructures

• Leo Sala,
• Agnes Zerolová,
• Violaine Vizcaino,
• Alain Mery,
• Alicja Domaracka,
• Hermann Rothard,
• Philippe Boduch,
• Dominik Pinkas and
• Jaroslav Kocišek

Beilstein J. Nanotechnol. 2024, 15, 207–214, doi:10.3762/bjnano.15.20

• , respectively. In vacuum, material from the structures may sublime. In air, it is plausible that the stochastic irradiation transforms into uniform changes on the structure, which can be controlled by DNA origami design. Supporting Information Height evolution upon thermal processing of DNA origami deposited