Beilstein J. Nanotechnol.2011,2, 333–338, doi:10.3762/bjnano.2.39
. Apparently, a V/III ratio of 1/1 is optimal for high quantumdot density. Compared to the highest QD density previously reported, our results reveal a two times higher density.
Figure 2 shows the PL spectra of two QD samples grown at a V/III ratio of 1/1 (so-called smaller dots) and 1.5/1 (larger dots
compared to our work.
According to Figure 2 an increase in the dot volume should lead to a redshift of the PL peak. However, the blueshift induced by the decreased Sb concentration in the QDs overcompensates for the volume dependent redshift, leading to the net blueshift observed in Figure 4.
Quantumdot
× 1010 cm−2 was achieved in the SK epitaxial growth mode, with a V/III flux ratio of 1/1 at a growth temperature of T = 527 °C and nominal coverage of 3 ML. With increasing V/III ratio the dot size also increased. Only one PL peak was detected, attributable to the quantumdot nature; no further peak
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Figure 1:
Top: AFM images of samples grown at a temperature of T = 527 °C and a nominal coverage of 3 ML, but...
Beilstein J. Nanotechnol.2010,1, 94–100, doi:10.3762/bjnano.1.11
, aggregation of nanoparticles, loss of transparency and luminescence quenching due to exciton energy transfer [2][7]. Several methods have been described to overcome these problems for quantumdot polymer composites. For example, Bawendi and coworkers incorporated trioctylphosphine oxide covered CdSe/ZnS QDs