Novel roles for well-known players: from tobacco mosaic virus pests to enzymatically active assemblies

• Claudia Koch,
• Fabian J. Eber,
• Carlos Azucena,
• Alexander Förste,
• Stefan Walheim,
• Thomas Schimmel,
• Alexander M. Bittner,
• Holger Jeske,
• Hartmut Gliemann,
• Sabine Eiben,
• Fania C. Geiger and
• Christina Wege

Beilstein J. Nanotechnol. 2016, 7, 613–629, doi:10.3762/bjnano.7.54

• cells is relatively low [55]. Hence ectopically produced TMV templates are not yet accessible. Finally, an attachment of functional molecules to virus surfaces equipped too densely with anchoring tags may also be inefficient. For these reasons, previous work on elongated viral enzyme carriers succeeded

Invariance of molecular charge transport upon changes of extended molecule size and several related issues

• Ioan Bâldea

Beilstein J. Nanotechnol. 2016, 7, 418–431, doi:10.3762/bjnano.7.37

• particularly true in (chemisorption) cases where the anchoring groups form covalent bonds to the electrodes. Within current approaches to molecular charge transport, mostly based on nonequilibrium Keldysh Green’s functions (NEGF) combined with density functional theory (DFT), the molecular device is

• , which quantify the hopping between the left and right molecular ends (“anchoring groups”, denoted by labels 1 and N, respectively) and the adjacent electrode ends (labels l = 1 and r = 1 for left and right electrodes in Equation 9). In Equation 9, the small molecule, which needs not to be one

Rigid multipodal platforms for metal surfaces

• Michal Valášek,
• Marcin Lindner and
• Marcel Mayor

Beilstein J. Nanotechnol. 2016, 7, 374–405, doi:10.3762/bjnano.7.34

• anchoring units in order to control the spatial arrangement of the protruding molecular subunit. Another interesting feature is the lateral orientation of these foot structures which, depending on the particular application, is equally important as the spatial arrangement of the molecules. The numerous

• approaches towards assembling and organizing functional molecules into specific architectures on metal substrates are reviewed here. Particular attention is paid to variations of both, the core structures and the anchoring groups. Furthermore, the analytical methods enabling the investigation of individual

• molecules as well as monomolecular layers of ordered platform structures are summarized. The presented multipodal platforms bearing several anchoring groups form considerably more stable molecule–metal contacts than corresponding monopodal analogues and exhibit an enlarged separation of the functional

Hemolysin coregulated protein 1 as a molecular gluing unit for the assembly of nanoparticle hybrid structures

• Tuan Anh Pham,
• Andreas Schreiber,
• Elena V. Sturm (née Rosseeva),
• Stefan Schiller and
• Helmut Cölfen

Beilstein J. Nanotechnol. 2016, 7, 351–363, doi:10.3762/bjnano.7.32

• inorganic material. Here, we use hemolysin coregulated protein 1 (Hcp1) from Pseudomonas aeruginosa as a building and gluing unit for the formation of biohybrid structures by implementing cysteine anchoring points at defined positions on the protein rim (Hcp1_cys3). We successfully apply the Hcp1_cys3

Case studies on the formation of chalcogenide self-assembled monolayers on surfaces and dissociative processes

• Yongfeng Tong,
• Tingming Jiang,
• Azzedine Bendounan,
• Makri Nimbegondi Kotresh Harish,
• Angelo Giglia,
• Stefan Kubsky,
• Fausto Sirotti,
• Luca Pasquali,
• Srinivasan Sampath and
• Vladimir A. Esaulov

Beilstein J. Nanotechnol. 2016, 7, 263–277, doi:10.3762/bjnano.7.24

• various applications such as catalysis, sensor development, hydrogen storage, thin films, and molecular electronics has focused on the study of self-assembled monolayers (SAMs) with different combinations of molecular architecture, and in particular, different molecule anchoring head groups. The latter

Controlled graphene oxide assembly on silver nanocube monolayers for SERS detection: dependence on nanocube packing procedure

• Martina Banchelli,
• Bruno Tiribilli,
• Roberto Pini,
• Luigi Dei,
• Paolo Matteini and
• Gabriella Caminati

Beilstein J. Nanotechnol. 2016, 7, 9–21, doi:10.3762/bjnano.7.2

• with procedure B. The larger amount of GO obtained with procedure B (see Table 2) is therefore strictly related to the smaller fraction of bare silicon oxide surface exposed. In both cases GO adsorbs through interactions with the silver surface anchoring exclusively to the outer face of the nanocube

• nm for both procedures. Such high thickness values are in accordance with the formation of folded geometries of single GO sheets after anchoring to the nanoparticle surface. Nevertheless, AFM measurements reveal a smaller thickness compared to QCM for the same samples. This was expected since QCM

High electronic couplings of single mesitylene molecular junctions

• Yuki Komoto,
• Shintaro Fujii,
• Tomoaki Nishino and
• Manabu Kiguchi

Beilstein J. Nanotechnol. 2015, 6, 2431–2437, doi:10.3762/bjnano.6.251

• electronics. To bind a single molecule to metal electrodes, anchoring groups such as –SH [14] and –NH2 or (R)3–N [15][16] have been used. Such anchoring groups form strong chemical bonds with metal electrodes and the anchoring regions act as resistive space, leading to low electronic conductances of the

• single molecular junctions. Recently several groups [17][18][19][20] including ours [17][21][22] developed a direct π-binding technique, where a π-conjugated molecule is directly bound to metal electrodes without anchoring groups. The direct π-binding technique has been applied for various systems such

• experimentally obtained I–V characteristics to the Breit-Wigner model, the metal–molecule coupling Γ, and energy difference between Fermi level and conduction orbital ε0 are obtained. This I–V analysis has been applied for molecular junctions with a variety of anchoring groups. For example Γ = 60 meV and ε0

Nanostructured surfaces by supramolecular self-assembly of linear oligosilsesquioxanes with biocompatible side groups

• Maria Nowacka,
• Anna Kowalewska and
• Tomasz Makowski

Beilstein J. Nanotechnol. 2015, 6, 2377–2387, doi:10.3762/bjnano.6.244

• LPSQ-COOH/X allow for a very efficient polymer anchoring on the surface due to both multipoint ionic substrate–adsorbate interactions and adsorbate–adsorbate hydrogen bonding [37]. The formation of ordered SAMs and PSAMs at the liquid–solid interface can occur only if it is energetically allowed by

Orthogonal chemical functionalization of patterned gold on silica surfaces

• Francisco Palazon,
• Didier Léonard,
• Thierry Le Mogne,
• Francesca Zuttion,
• Céline Chevalier,
• Magali Phaner-Goutorbe,
• Éliane Souteyrand,
• Yann Chevolot and
• Jean-Pierre Cloarec

Beilstein J. Nanotechnol. 2015, 6, 2272–2277, doi:10.3762/bjnano.6.233

• immobilize proteins onto gold nanostructures on a silica substrate, as demonstrated by atomic force microscopy (AFM). These results are especially promising in the development of future biosensors where the selective anchoring of target molecules onto nanostructured transducers (e.g., nanoplasmonic

• hot spot areas. Orthogonal surface chemical functionalization appears to enable such directed anchoring of target biomolecules (Figure 1) [6][8][9]. Despite the aforementioned publications, there is still much to be investigated regarding the orthogonal functionalization of patterned metal on

Controlled switching of single-molecule junctions by mechanical motion of a phenyl ring

• Yuya Kitaguchi,
• Satoru Habuka,
• Hiroshi Okuyama,
• Shinichiro Hatta,
• Tetsuya Aruga,
• Thomas Frederiksen,
• Magnus Paulsson and
• Hiromu Ueba

Beilstein J. Nanotechnol. 2015, 6, 2088–2095, doi:10.3762/bjnano.6.213

• cleavage of the junction by tip retraction (Figure 1b) provides a well-defined measure of the direct current through the molecule. To investigate the influence of the anchoring group on the conductance, we also prepared PhS on the surface. This molecule is imaged as a protrusion with a tail which is

• retraction were recorded. The height of the plateau, corresponding to the conductance for each molecule, is robust between repeated measurements and is larger by a factor of ≈2 for PhS. This demonstrates that the conductance is modified by chemical substitution of the anchoring atom from oxygen to sulfur. To

• . The role of the anchoring group (O vs S) on the junction geometry was also computed. Figure 5 compares the total energy differences and molecular tilt angles for PhO [12] and PhS junctions in flat and tilted configurations. While the energy difference is rather similar, the tilt angle is generally

Electrospray deposition of organic molecules on bulk insulator surfaces

• Antoine Hinaut,
• Rémy Pawlak,
• Ernst Meyer and
• Thilo Glatzel

Beilstein J. Nanotechnol. 2015, 6, 1927–1934, doi:10.3762/bjnano.6.195

• molecules which are more suitable for future devices and could incorporate additional functions and anchoring groups. In this work we present the adaptation of a UHV-ESI system to deposit triply fused porphyrin molecules on a bulk insulator KBr(001) sample and the analysis of theses deposits by high

• characterized theses islands showing molecular assemblies stabilized by π–π stacking organization and anchoring through the cyano group of the molecules and K+ ions of the surface. To achieve single molecule deposition, we added a pumping chamber in the setup that lowered the number of molecules reaching the

Conductance through single biphenyl molecules: symmetric and asymmetric coupling to electrodes

• Karthiga Kanthasamy and
• Herbert Pfnür

Beilstein J. Nanotechnol. 2015, 6, 1690–1697, doi:10.3762/bjnano.6.171

• groups like amine, nitro, nitrile, carboxy, iso cyanate, pyridine. The electron donating group leads to higher conductance while electron withdrawing groups have a smaller conductance. The Au–S thiol is a well known anchoring group due strong covalent bond coupling [15]. The iso cyano group has been

Electrical properties and mechanical stability of anchoring groups for single-molecule electronics

• Riccardo Frisenda,
• Simge Tarkuç,
• Elena Galán,
• Mickael L. Perrin,
• Rienk Eelkema,
• Ferdinand C. Grozema and
• Herre S. J. van der Zant

Beilstein J. Nanotechnol. 2015, 6, 1558–1567, doi:10.3762/bjnano.6.159

• mechanically controlled break junction (MCBJ) technique. The four molecules studied share the same core structure, namely oligo(phenylene ethynylene) (OPE3), while having different aurophilic anchoring groups: thiol (SAc), methyl sulfide (SMe), pyridyl (Py) and amine (NH2). The focus of this paper is on the

• combined characterization of the electrical and mechanical properties determined by the anchoring groups. From conductance histograms we find that thiol anchored molecules provide the highest conductance; a single-level model fit to current–voltage characteristics suggests that SAc groups exhibit a higher

• theory combined with non-equlibrium Green’s function calculations help in elucidating the experimental findings. Keywords: anchoring groups; coherent transport; current–voltage; molecular electronics; single molecule; Introduction Molecular-scale electronics is a field that in recent years experienced

Possibilities and limitations of advanced transmission electron microscopy for carbon-based nanomaterials

• Xiaoxing Ke,
• Carla Bittencourt and
• Gustaaf Van Tendeloo

Beilstein J. Nanotechnol. 2015, 6, 1541–1557, doi:10.3762/bjnano.6.158

• electrons, and therefore provide the anchoring points with a certain degree of flexibility allowing for the movement of the Ru4POM molecules. Additionally, a continuous deformation of the molecular structure is noticed throughout the imaging. A typical example is demonstrated in Figure 8c–i. The acquired

Enhanced fullerene–Au(111) coupling in (2√3 × 2√3)R30° superstructures with intermolecular interactions

• Michael Paßens,
• Rainer Waser and
• Silvia Karthäuser

Beilstein J. Nanotechnol. 2015, 6, 1421–1431, doi:10.3762/bjnano.6.147

• extensively studied self-assembled systems due to their rich structural and electronic properties [1]. A considerable interest in C60 films arises from their use in photovoltaic cells [2][3] and potential applications in molecular electronics [4]. Likewise, C60 molecules can be used as chemical anchoring

Heterometal nanoparticles from Ru-based molecular clusters covalently anchored onto functionalized carbon nanotubes and nanofibers

• Deborah Vidick,
• Xiaoxing Ke,
• Michel Devillers,
• Claude Poleunis,
• Arnaud Delcorte,
• Pietro Moggi,
• Gustaaf Van Tendeloo and
• Sophie Hermans

Beilstein J. Nanotechnol. 2015, 6, 1287–1297, doi:10.3762/bjnano.6.133

• Scienze 17/A, 43124 Parma, Italy 10.3762/bjnano.6.133 Abstract Heterometal clusters containing Ru and Au, Co and/or Pt are anchored onto carbon nanotubes and nanofibers functionalized with chelating phosphine groups. The cluster anchoring yield is related to the amount of phosphine groups available on

• nanocarbon surface. In the case of Ru–Pt species, anchoring occurs without reorganization through a ligand exchange mechanism. After thermal treatment, ultrasmall (1–3 nm) bimetal Ru–Pt nanoparticles are formed on the surface of the nanocarbons. Characterization by high resolution transmission electron

• the presence of additives, binders, etc. Results and Discussion Cluster anchoring Phosphine-functionalized carbon nanofibers and nanotubes were prepared in several steps, as previously reported [38] and shown in Figure 1. We have also successfully applied this methodology to ordered mesoporous carbon

Electrical characterization of single molecule and Langmuir–Blodgett monomolecular films of a pyridine-terminated oligo(phenylene-ethynylene) derivative

• Henrry M. Osorio,
• Santiago Martín,
• María Carmen López,
• Santiago Marqués-González,
• Simon J. Higgins,
• Richard J. Nichols,
• Paul J. Low and
• Pilar Cea

Beilstein J. Nanotechnol. 2015, 6, 1145–1157, doi:10.3762/bjnano.6.116

• molecules within the LB film do not strongly influence the molecule conductance. The results presented here complement earlier studies of single molecule conductance of 1 using STM-BJ methods, and support the growing evidence that the pyridyl group is an efficient and effective anchoring group in sandwiched

• molecular electronics have focused attention on this potential linker group as an alternative to solve these problems [87]. Previous studies of pyridyl-functionalized molecules in single molecule conductance studies [19][21][88][89][90][91] have revealed that this moiety can work as an anchoring group

• other LB films), the conductance value for compound 1 is 3–20 times greater than for LB films of other oligo(phenylene-ethynylene) (OPE) derivatives bearing anchoring groups such as thiol (–SH), amine (–NH2), carboxylate (–COO−), trimethylsilylethynyl (–C≡CSiMe3) or acetylide (–C≡C) [23][24][30][45

Self-assembled anchor layers/polysaccharide coatings on titanium surfaces: a study of functionalization and stability

• Ognen Pop-Georgievski,
• Dana Kubies,
• Josef Zemek,
• Neda Neykova,
• Roman Demianchuk,
• Eliška Mázl Chánová,
• Miroslav Šlouf,
• Milan Houska and
• František Rypáček

Beilstein J. Nanotechnol. 2015, 6, 617–631, doi:10.3762/bjnano.6.63

• anchoring layers of self-assembled bisphosphonate neridronate monolayers and polymer films of 3-aminopropyltriethoxysilane and biomimetic poly(dopamine). These were further used to bind a bio-functional alginate coating. The success of the titanium surface activation, anchoring layer formation and alginate

• contribution is to perform and precisely characterize the activation of commercially pure titanium substrates for the realization of reactive titanium surfaces without contaminants. Such activated surfaces can be further functionalized by the covalent immobilization of self-assembled anchoring layers of

• different organic compounds, providing functional groups for further modification. Covalent bonding, which provides a stable fixation of immobilized compounds, is an alternative approach to coatings based on adsorption processes. The most common strategies for the formation of anchoring layers are thiol

Palladium nanoparticles anchored to anatase TiO₂ for enhanced surface plasmon resonance-stimulated, visible-light-driven photocatalytic activity

• Kah Hon Leong,
• Hong Ye Chu,
• Shaliza Ibrahim and
• Pichiah Saravanan

Beilstein J. Nanotechnol. 2015, 6, 428–437, doi:10.3762/bjnano.6.43

• the TiO2 surface and promotes the application of a non-conventional energy resource. In the present study, a smart, easy and sustainable method for anchoring noble metal onto the surface of TiO2 is reported. Palladium was chosen as the noble metal for the study due to its high reactivity and

• anchoring of Pd NPs onto the surface of TiO2, and the large size of the Pd NPs contributed to the visible-light absorption. Localized surface plasmon resonance (LSPR) and the formation of a Schottky barrier at the TiO2 interface also occured. The prepared heterogeneous photocatalysts exhibited superior

Influence of spurious resonances on the interaction force in dynamic AFM

• Luca Costa and
• Mario S. Rodrigues

Beilstein J. Nanotechnol. 2015, 6, 420–427, doi:10.3762/bjnano.6.42

• added to the measured signal. Considering Equation 4 and recomputing both and , the position of the moving mass, given by its deflection plus the motion of the base, is , where Am is the amplitude of the measured signal and Ab the oscillation amplitude of the cantilever anchoring point. To simplify, as

Electrical response of liquid crystal cells doped with multi-walled carbon nanotubes

• Amanda García-García,
• Ricardo Vergaz,
• José F. Algorri,
• Xabier Quintana and
• José M. Otón

Beilstein J. Nanotechnol. 2015, 6, 396–403, doi:10.3762/bjnano.6.39

• minimize the energy derived from the electric field and the anchoring elastic forces [13]. These LC properties may be used to induce alignment and reorientation on dispersed CNTs. Using this effect, several photonic and electronic devices have been proposed [5] including electrically controlled switches

• isotropic transition [14]. The authors explain these results by assuming a strong anchoring between the LC molecules and the CNTs. This anchoring keeps the former arranged in pseudo-nematic oriented domains around the latter above the isotropic point. Confirmation of this phenomenon and other features of

Mammalian cell growth on gold nanoparticle-decorated substrates is influenced by the nanoparticle coating

• Christina Rosman,
• Sebastien Pierrat,
• Marco Tarantola,
• David Schneider,
• Eva Sunnick,
• Andreas Janshoff and
• Carsten Sönnichsen

Beilstein J. Nanotechnol. 2014, 5, 2479–2488, doi:10.3762/bjnano.5.257

• filamentous residue remains (Figure 1D). However, this residue emerges in control samples without nanoparticle patterning as well (Supporting Information File 1, Figure S1) and corresponds to retracting filopodia [25]. Therefore, no specific anchoring of the membrane to the nanoparticles seems to be necessary

• average, negatively charged. Electrostatic interaction with negatively charged COOH–PEG nanorods should therefore be repulsive, comparable to the bare glass substrates. In contrast, amines are known to interact with the negatively charged cell membrane. It is therefore likely that an anchoring of the

Synthesis and characterization of fluorescence-labelled silica core-shell and noble metal-decorated ceria nanoparticles

• Rudolf Herrmann,
• Markus Rennhak and
• Armin Reller

Beilstein J. Nanotechnol. 2014, 5, 2413–2423, doi:10.3762/bjnano.5.251

• error in this estimate is probably due to changes in the molar extinction coefficient upon anchoring at the surface (Figure 3 (left) shows two maxima with different absorbance where free MPD has the same). Since the surface coverage is low, we expected that the labelling would not interfere with

Influence of the supramolecular architecture on the magnetic properties of a Dy^III single-molecule magnet: an ab initio investigation

• Julie Jung,
• Olivier Cador,
• Kevin Bernot,
• Fabrice Pointillart,
• Javier Luzon and
• Boris Le Guennic

Beilstein J. Nanotechnol. 2014, 5, 2267–2274, doi:10.3762/bjnano.5.236

• “averaged” position of the H atom along the N–H…O bond has to be considered. Conclusion The understanding of the subtle mechanisms at the origin of the magnetic properties of molecular materials is a prerequisite before anchoring/grafting these molecular architectures onto surfaces, nanoparticles or

In situ metalation of free base phthalocyanine covalently bonded to silicon surfaces

• Fabio Lupo,
• Cristina Tudisco,
• Federico Bertani,
• Enrico Dalcanale and
• Guglielmo G. Condorelli

Beilstein J. Nanotechnol. 2014, 5, 2222–2229, doi:10.3762/bjnano.5.231

• 17/A, 43124 Parma, Italy 10.3762/bjnano.5.231 Abstract Free 4-undecenoxyphthalocyanine molecules were covalently bonded to Si(100) and porous silicon through thermic hydrosilylation of the terminal double bonds of the undecenyl chains. The success of the anchoring strategy on both surfaces was

• demonstrated by the combination of X-ray photoelectron spectroscopy with control experiments performed adopting the commercially available 2,3,9,10,16,17,23,24-octakis(octyloxy)-29H,31H-phthalocyanine, which is not suited for silicon anchoring. Moreover, the study of the shape of the XPS N 1s band gave

• synthesized to allow for a silicon grafting by functionalization with four undecenyl chains each having a terminal double bond. Phthalocyanine covalent anchoring was performed through thermic hydrosilylation on flat Si(100) and on porous silicon (Si-1-Pc and PSi-1-Pc, respectively). The success of the