Molecular materials – towards quantum properties

• Mario Ruben

Beilstein J. Nanotechnol. 2015, 6, 1485–1486, doi:10.3762/bjnano.6.153

• trade-off between decoupling of the quantum object for low decoherence and connecting it for the electrical read-out could be achieved [2]. Quantum computing, the manipulation of data encoded in qubits instead of bits of information such as spin states of electrons or of an atomic nucleus, has been a

Closed-loop conductance scanning tunneling spectroscopy: demonstrating the equivalence to the open-loop alternative

• Chris Hellenthal,
• Kai Sotthewes,
• Martin H. Siekman,
• E. Stefan Kooij and
• Harold J. W. Zandvliet

Beilstein J. Nanotechnol. 2015, 6, 1116–1124, doi:10.3762/bjnano.6.113

• decoupling the contributions of and ζ once again requires the use of a derivative numerical method. Taking into account that I does not vary as a function of V during closed-loop experiments, Equation 5 can be rewritten as: Substituting Equation 5 into this expression and dividing by I gives: Following the

Experimental determination of the light-trapping-induced absorption enhancement factor in DSSC photoanodes

• Serena Gagliardi and
• Mauro Falconieri

Beilstein J. Nanotechnol. 2015, 6, 886–892, doi:10.3762/bjnano.6.91

• produced by the concurrent phenomena of light absorption by dye molecules and light trapping in the mesoporous, titania photoanode structure. The decoupling of these two phenomena is important for device characterization and the design of novel photoelectrode geometries with increased optical performance

Magnetic properties of self-organized Co dimer nanolines on Si/Ag(110)

• Lisa Michez,
• Kai Chen,
• Fabien Cheynis,
• Frédéric Leroy,
• Alain Ranguis,
• Haik Jamgotchian,
• Margrit Hanbücken and
• Laurence Masson

Beilstein J. Nanotechnol. 2015, 6, 777–784, doi:10.3762/bjnano.6.80

• -plane anisotropy (for instance, along the nanolines) is not excluded, but its demonstration requires further measurements. We stress that due to the presence of a magnetic Co–Si dead layer on the Si template, an efficient decoupling of the Co nanostructures from the metallic silver substrate can be

A versatile strategy towards non-covalent functionalization of graphene by surface-confined supramolecular self-assembly of Janus tectons

• Ping Du,
• David Bléger,
• Fabrice Charra,
• Vincent Bouchiat,
• David Kreher,
• Fabrice Mathevet and
• André-Jean Attias

Beilstein J. Nanotechnol. 2015, 6, 632–639, doi:10.3762/bjnano.6.64

• . Face A was designed to act as a pedestal capable of steering a 2D self-assembly onto the substrate, while B is a functional entity (e.g., a chromophore). The spacer acts as a pillar ensuring the decoupling of the B face from the substrate. Moreover, if the Janus tecton is laying on the substrate via

Electrostatic interplay: The interaction triangle of polyamines, silicic acid, and phosphate studied through turbidity measurements, silicomolybdic acid test, and ²⁹Si NMR spectroscopy

• Anne Jantschke,
• Katrin Spinde and
• Eike Brunner

Beilstein J. Nanotechnol. 2014, 5, 2026–2035, doi:10.3762/bjnano.5.211

• , a commercial 10 mm HR probe (56° flip angle, number of scans 180, 60 s repetition time) was used. Typical T1 values for samples in solution were 8–13 s. Waltz16 1H decoupling was applied during signal acquisition. The chemical shift was referenced relative to tetramethylsilane (TMS). pH Titration

Probing the electronic transport on the reconstructed Au/Ge(001) surface

• Franciszek Krok,
• Mark R. Kaspers,
• Alexander M. Bernhart,
• Marek Nikiel,
• Benedykt R. Jany,
• Paulina Indyka,
• Mateusz Wojtaszek,
• Rolf Möller and
• Christian A. Bobisch

Beilstein J. Nanotechnol. 2014, 5, 1463–1471, doi:10.3762/bjnano.5.159

• structure, we conclude that the subsurface layer appears to be the major transport channel for this contact geometry. Rather sharp transitions of the potential at embedded Au islands suggest a decoupling of the Au islands from the surface layer. From in depth-profile analysis we can conclude that the Au

Interaction of iron phthalocyanine with the graphene/Ni(111) system

• Lorenzo Massimi,
• Simone Lisi,
• Daniela Pacilè,
• Carlo Mariani and
• Maria Grazia Betti

Beilstein J. Nanotechnol. 2014, 5, 308–312, doi:10.3762/bjnano.5.34

• (111). The results have been compared to the deposition of iron phthalocyanine on graphene/Ir(111), for which a higher decoupling of the organic molecule from the underlying metal is exerted by the graphene buffer layer. Keywords: angular-resolved photo-electron spectroscopy (ARPES); buffer layer

The role of surface corrugation and tip oscillation in single-molecule manipulation with a non-contact atomic force microscope

• Christian Wagner,
• Norman Fournier,
• F. Stefan Tautz and
• Ruslan Temirov

Beilstein J. Nanotechnol. 2014, 5, 202–209, doi:10.3762/bjnano.5.22

• surface (8 Å ≤ ztip ≤ 12 Å, cf. Figure 1b), while the second occurs during the final detachment of the molecule (17 Å ≤ ztip ≤ 20 Å). In both cases the effect of the soft tip manifests itself as a partial decoupling between the position z of the tip (i.e., the read-out in the experiment of the position of

Constant-distance mode SECM as a tool to visualize local electrocatalytic activity of oxygen reduction catalysts

• Michaela Nebel,
• Thomas Erichsen and
• Wolfgang Schuhmann

Beilstein J. Nanotechnol. 2014, 5, 141–151, doi:10.3762/bjnano.5.14

• intermitted contact mode (IC-SECM) [11], the shearforce-based constant-distance mode [12][13][14] has been widely used and demonstrated its feasibility for high-resolution SECM. Furthermore, decoupling of the working distance of the electrochemical detection from the typically very short working distances

Noise performance of frequency modulation Kelvin force microscopy

• Heinrich Diesinger,
• Dominique Deresmes and
• Thierry Mélin

Beilstein J. Nanotechnol. 2014, 5, 1–18, doi:10.3762/bjnano.5.1

• Kelvin force microscope (FM-KFM) is assessed. Noise propagation is modeled step by step throughout the setup using both exact closed loop noise gains and an approximation known as “noise gain” from operational amplifier (OpAmp) design that offers the advantage of decoupling the noise performance study

• modeling noise at different stages of the setup starting from the beam deflection signal, via the phase detector and the PLL outputs up to the Kelvin output voltage. The concept of noise gain allows for decoupling noise performance from the optimization of bandwidth and stability. It is commonly used in

Simultaneous current, force and dissipation measurements on the Si(111) 7×7 surface with an optimized qPlus AFM/STM technique

• Zsolt Majzik,
• Martin Setvín,
• Andreas Bettac,
• Albrecht Feltz,
• Vladimír Cháb and
• Pavel Jelínek

Beilstein J. Nanotechnol. 2012, 3, 249–259, doi:10.3762/bjnano.3.28

• measured at the tip, a cross-talk of the tunneling current with the force signal can easily occur. The origin and general features of the capacitive cross-talk will be discussed in detail in this contribution. Furthermore, we describe an experimental setup that improves the level of decoupling between the

Towards a scalable and accurate quantum approach for describing vibrations of molecule–metal interfaces

• David M. Benoit,
• Bruno Madebene,
• Inga Ulusoy,
• Luis Mancera,
• Yohann Scribano and
• Sergey Chulkov

Beilstein J. Nanotechnol. 2011, 2, 427–447, doi:10.3762/bjnano.2.48

• coordinates for periodic systems remains a complex issue. We are currently investigating optimum decoupling techniques for such systems in our laboratory. In the present study, however, we use a rectilinear 2-mode representation of the PES, despite its limitations, as this simplifies the calculation of the

Infrared receptors in pyrophilous (“fire loving”) insects as model for new un-cooled infrared sensors

• David Klocke,
• Anke Schmitz,
• Helmut Soltner,
• Herbert Bousack and
• Helmut Schmitz

Beilstein J. Nanotechnol. 2011, 2, 186–197, doi:10.3762/bjnano.2.22

• density and heat capacity may have a low IR absorption, which makes this fluid disadvantageous for the application. A decoupling of thermal and optical properties can be achieved with a matrix of a good absorber, e.g., a meshwork of plastic or tiny plastic beads, or a dye immersed in the fluid. The

• decoupling of the thermal and optical properties permits the determination of an optimal absorption coefficient approximately for each cavity depth to absorb the IR energy completely in the cavity without any unused fluid volume. Gas Using gas instead of water in the cavity as in the well known pneumatic

Oriented growth of porphyrin-based molecular wires on ionic crystals analysed by nc-AFM

• Thilo Glatzel,
• Lars Zimmerli,
• Shigeki Kawai,
• Ernst Meyer,
• Leslie-Anne Fendt and
• Francois Diederich

Beilstein J. Nanotechnol. 2011, 2, 34–39, doi:10.3762/bjnano.2.4

• molecular assemblies can be formed. The electronic decoupling of the molecules by one or two monolayers of KBr from the Cu(111) substrate is found to be insufficient to enable comparable growth conditions to bulk ionic materials. Keywords: directed growth; KBr; molecular wires; NaCl; nc-AFM; porphyrin

• NaCl thin films have already proved their importance as homogeneous ultrathin spacer layers to separate single molecules from the metal substrate [14][15][16]. Nevertheless, complete electrical decoupling of such devices from the substrate requires bulk insulators or thick insulating films. Several

• decoupling. Results and Discussion Cleaving KBr crystals in vacuum and annealing them at moderate temperatures results in the formation of wide terraces with step edges in [100] direction which can be as long as several hundred nanometers. Evaporating the cyano-porphyrins onto the bulk KBr(001) surface

Magnetic coupling mechanisms in particle/thin film composite systems

• Giovanni A. Badini Confalonieri,
• Philipp Szary,
• Durgamadhab Mishra,
• Maria J. Benitez,
• Mathias Feyen,
• An Hui Lu,
• Leonardo Agudo,
• Gunther Eggeler,
• Oleg Petracic and
• Hartmut Zabel

Beilstein J. Nanotechnol. 2010, 1, 101–107, doi:10.3762/bjnano.1.12

• without ion-milling. The nanoparticle array showed a collective super-spin behavior due to dipolar interparticle coupling. In the composite system, we observed a decoupling into two nanoparticle subsystems. In the ion-milled system, the nanoparticle layer served as a magnetic flux guide as observed by