Stereodiscrimination of guests in chiral organosilica aerogels studied by ESR spectroscopy

• Sebastian Polarz,
• Yasar Krysiak,
• Martin Wessig and
• Florian Kuhlmann

Beilstein J. Nanotechnol. 2025, 16, 2034–2054, doi:10.3762/bjnano.16.140

• first as this, according to [42][44], alters the difference in the interaction profiles. Isopropanol (ε = 18.3, μ = 1.66 D) has a lower dielectric constant ε and lower dipole moment μ than ethanol (ε = 24.2, μ = 1.69 D). Because of the carboxyl group in 3CP (see Figure 3), together with the dipole

Laser ablation in liquids for shape-tailored synthesis of nanomaterials: status and challenges

• Natalie Tarasenka

Beilstein J. Nanotechnol. 2025, 16, 1963–1997, doi:10.3762/bjnano.16.137

• process with the formation of dendritic structures. The authors discussed the evolution of NP shape based on the electrostatic attraction between species released from the plasma plume and liquid molecules, so that the resulting shape of the forming NPs would depend on the dielectric constant and dipole

Laser processing in liquids: insights into nanocolloid generation and thin film integration for energy, photonic, and sensing applications

• Akshana Parameswaran Sreekala,
• Pooja Raveendran Nair,
• Jithin Kundalam Kadavath,
• Bindu Krishnan,
• David Avellaneda Avellaneda,
• M. R. Anantharaman and
• Sadasivan Shaji

Beilstein J. Nanotechnol. 2025, 16, 1428–1498, doi:10.3762/bjnano.16.104

• illustrations of the pulsed laser heating mechanism are presented in Figure 7f,g. Factors such as laser fluence, irradiation time, and solvent properties, such as dielectric constant and thermal conductivity, must be carefully controlled to optimize nanoparticle formation [49][68][69][75]. Other factors like

Wavelength-dependent correlation of LIPSS periodicity and laser penetration depth in stainless steel

• Nitin Chaudhary,
• Chavan Akash Naik,
• Shilpa Mangalassery,
• Jai Prakash Gautam and
• Sri Ram Gopal Naraharisetty

Beilstein J. Nanotechnol. 2025, 16, 1302–1315, doi:10.3762/bjnano.16.95

• angle, the period of the resulting ripples can be determined using the equation [57][58][59]: where Λ is the ripple periodicity (LSFL spatial periodicity), λ is the incident wavelength, and εd and εm are the dielectric constants of the medium and metal, respectively. εd = 1 (dielectric constant of the

Piezoelectricity of hexagonal boron nitrides improves bone tissue generation as tested on osteoblasts

• Sevin Adiguzel,
• Nilay Cicek,
• Zehra Cobandede,
• Feray B. Misirlioglu,
• Hulya Yilmaz and
• Mustafa Culha

Beilstein J. Nanotechnol. 2025, 16, 1068–1081, doi:10.3762/bjnano.16.78

• , making them particularly attractive for biomedical applications. [21][22]. Barium titanate (BaTiO3) is one of the most well-known piezoelectric nanomaterials (NMs), characterized by a cubic structure with four polymorphs which change depending on the temperature and a high dielectric constant. All its

Morphology and properties of pyrite nanoparticles obtained by pulsed laser ablation in liquid and thin films for photodetection

• Akshana Parameswaran Sreekala,
• Bindu Krishnan,
• Rene Fabian Cienfuegos Pelaes,
• David Avellaneda Avellaneda,
• Josué Amílcar Aguilar-Martínez and
• Sadasivan Shaji

Beilstein J. Nanotechnol. 2025, 16, 785–805, doi:10.3762/bjnano.16.60

• experimental variables that cause the kinetics of the nanoparticles formation to change, resulting in nanoparticles with different sizes and morphologies [40]. Thermodynamic properties such as density, dielectric constant, viscosity, vapor pressure, and optical properties of the solvents are some of the

Nanoscale capacitance spectroscopy based on multifrequency electrostatic force microscopy

• Pascal N. Rohrbeck,
• Lukas D. Cavar,
• Franjo Weber,
• Peter G. Reichel,
• Mara Niebling and
• Stefan A. L. Weber

Beilstein J. Nanotechnol. 2025, 16, 637–651, doi:10.3762/bjnano.16.49

• nanoscale systems across materials science, biology, and nanotechnology, complementing established methods in the field. Keywords: atomic force microscopy; capacitance gradients; dielectric constant; dielectric spectroscopy; heterodyne frequency mixing; Kelvin probe force microscopy; multifrequency AFM

• to at least 50 MHz, limited by the bandwidth of the LIA. To reach a nanoscale-sensitive measurement of the dielectric constant in media besides air, a detection at higher excitation frequencies in the megahertz regime is strictly necessary [59]. The indirect detection of local capacitance variations

• yields: where ε0 is the dielectric constant of the vacuum. The dimensions of the lever are given by its width w, its length l, and the height of the tip cone h. The lever is tilted by the angle α = ϑlever. The tip cone can be approximated by a truncated cone (Figure 9). The electrostatic force as a

Water in nanoporous hexagonal boron nitride nanosheets: a first-principles study

• Juliana A. Gonçalves,
• Ronaldo J. C. Batista and
• Marcia C. Barbosa

Beilstein J. Nanotechnol. 2025, 16, 510–519, doi:10.3762/bjnano.16.39

• boron nitride (h-BN) [19]. Among these materials, h-BN stands out because of its properties, which are similar to those of graphene. It is composed of alternating boron and nitrogen atoms arranged in a honeycomb-like crystalline structure, characterized by high thermal stability, low dielectric constant

Tailoring of physical properties of RF-sputtered ZnTe films: role of substrate temperature

• Kafi Devi,
• Usha Rani,
• Arun Kumar,
• Divya Gupta and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 333–348, doi:10.3762/bjnano.16.25

• ]. The dielectric constant and the dielectric loss of the deposited ZnTe films exhibit a similar pattern and were also found to decrease with increasing substrate temperature (see below). Photoluminescence studies Photoluminescence (PL) studies were carried out to analyse the films’ electronic features

Fabrication of hafnium-based nanoparticles and nanostructures using picosecond laser ablation

• Abhishek Das,
• Mangababu Akkanaboina,
• Jagannath Rathod,
• R. Sai Prasad Goud,
• Kanaka Ravi Kumar,
• Raghu C. Reddy,
• Ratheesh Ravendran,
• Katia Vutova,
• S. V. S. Nageswara Rao and
• Venugopal Rao Soma

Beilstein J. Nanotechnol. 2024, 15, 1639–1653, doi:10.3762/bjnano.15.129

• [8] compared to bulk Hf. HfO2 is a wide-bandgap (5.68 eV) material with a high dielectric constant (≈25) [9][10]. HfC has a very high melting point (≈3900 °C) and ranks among the hardest materials, with a Vickers hardness value exceeding 20 GPa [4][11]. The properties vary substantially depending on

Lithium niobate on insulator: an emerging nanophotonic crystal for optimized light control

• Midhun Murali,
• Amit Banerjee and
• Tanmoy Basu

Beilstein J. Nanotechnol. 2024, 15, 1415–1426, doi:10.3762/bjnano.15.114

• high dielectric constant enables the fabrication of photonic crystals characterized by high-quality factors and minimal losses [17][18][19][20][21][22][23]. The combination of LiNbO3 and TiO2 in multi-stacked 1D PhC holds promise for optical applications [5]. The birefringence and electro-optic

Quantum-to-classical modeling of monolayer Ge₂Se₂ and its application in photovoltaic devices

• Anup Shrivastava,
• Shivani Saini,
• Dolly Kumari,
• Sanjai Singh and
• Jost Adam

Beilstein J. Nanotechnol. 2024, 15, 1153–1169, doi:10.3762/bjnano.15.94

• coefficient and a high dielectric constant inspired the design of a monolayer Ge2Se2-based solar cell, exhibiting a high open circuit voltage of Voc = 1.11 V, a fill factor of 87.66%, and more than 28% power conversion efficiency at room temperature. Our findings advocate monolayer Ge2Se2 for various

• ) eigenvalues relative to the bottom of the conduction band. Along with the DFT-derived parameters, some excited state eigenfunctions in terms of absorption coefficient and dielectric constant are also required to simulate solar cell-based devices. An optimum way of extracting these optical parameters from

• ground-state eigenvalues is described below. Extraction of optical properties To explore the optical properties, including dielectric constant, refractive index, absorption constant, extinction coefficient, and susceptibility for monolayer Ge2Se2, we employed the non-equilibrium Green’s function (NEGF

Unveiling the potential of alginate-based nanomaterials in sensing technology and smart delivery applications

• Shakhzodjon Uzokboev,
• Khojimukhammad Akhmadbekov,
• Ra’no Nuritdinova,
• Salah M. Tawfik and
• Yong-Ill Lee

Beilstein J. Nanotechnol. 2024, 15, 1077–1104, doi:10.3762/bjnano.15.88

• ]. The polymer film’s soil moisture sensing capabilities were proved by measuring the dielectric constant of the polymer with soil samples containing low and high moisture (Figure 7). According to the results, the polymer film has excellent moisture sensing characteristics at frequencies as low as a few

Recent progress on field-effect transistor-based biosensors: device perspective

• Billel Smaani,
• Fares Nafa,
• Mohamed Salah Benlatrech,
• Ismahan Mahdi,
• Hamza Akroum,
• Mohamed walid Azizi,
• Khaled Harrar and
• Sayan Kanungo

Beilstein J. Nanotechnol. 2024, 15, 977–994, doi:10.3762/bjnano.15.80

• dielectric constant inside the cavity resulting in a gating effect modulation and subsequent alteration in channel conductivity. This leads to a change in both threshold voltage and drain current, manifesting the presence of target biomolecules in the cavity, and the corresponding sensitivity is defined

• coupling [55]. The variation of capacitance depends on the intrinsic charge density and the dielectric constant of the target biomolecule [48]. The cavity specification and thereby the sensor device design is also related to the diameter of targeting species, which varied from micro- to nanoscale (Figure 4

• biosensor without a gate above the nanocavity for biomolecules with a dielectric constant equal to 12, compared to the structure of the TMD FET biosensor with a gate above the nanocavity for fully-filled cavities. 2.2.3 Split-gate junctionless FET-based biosensors. A dielectric-modulated split-gate

Electrospun nanofibers: building blocks for the repair of bone tissue

• Tuğrul Mert Serim,
• Gülin Amasya,
• Tuğba Eren-Böncü,
• Ceyda Tuba Şengel-Türk and
• Ayşe Nurten Özdemir

Beilstein J. Nanotechnol. 2024, 15, 941–953, doi:10.3762/bjnano.15.77

• , concentration and molecular weight of the polymer, solvent or solvent mixture, surface tension, conductivity, dielectric constant, and environmental parameters are parameters that must be optimized in the electrospinning process. Voltage Voltage is the parameter that most affects the shape of the droplet from

• fewer beads are formed [79]. Dielectric constant The dielectric constant refers to the ability of a substance to hold an electric charge in the region where an electric field is applied. The dielectric constant of a polymer liquid mainly depends on the solvent used. For the electrospinning process, the

• dielectric constant must be high enough [74][75]. With an increase in dielectric constant fewer beads and smaller fiber diameters are formed [80]. Environmental parameters Temperature Temperature affects the viscosity and spinnability of polymer liquids and the thickness of the collected fiber mats

Reduced subthreshold swing in a vertical tunnel FET using a low-work-function live metal strip and a low-k material at the drain

• Kalai Selvi Kanagarajan and
• Dhanalakshmi Krishnan Sadhasivan

Beilstein J. Nanotechnol. 2024, 15, 713–718, doi:10.3762/bjnano.15.59

• research paper, a vertical tunnel field-effect transistor (TFET) structure containing a live metal strip and a material with low dielectric constant is designed, and its performance metrics are analyzed in detail. Low-k SiO2 is incorporated in the channel–drain region. A live molybdenum metal strip with

• to reduce gate oxide leakage are high-k materials. The device’s ability to keep a charge is increased by using high-k materials, which also aids in downsizing. HfO2 is compatible with a silicon substrate and possesses a high dielectric constant (ε ≈ 25), a large bandgap (5.68 eV), band offsets with

• [12] is 2.96 × 10−13 A/μm. The threshold voltage is 0.28 V. The on-state current is 1.00 × 10−5 A/μm. The transfer characteristics of the three devices are presented in Figure 7. The leakage current is minimal in the proposed model. Miller capacitance and leakage The high dielectric constant of HfO2

Nanoarchitectonics of photothermal materials to enhance the sensitivity of lateral flow assays

• Elangovan Sarathkumar,
• Rajasekharan S. Anjana and
• Ramapurath S. Jayasree

Beilstein J. Nanotechnol. 2023, 14, 988–1003, doi:10.3762/bjnano.14.82

• LSPR effect highly depends on size, shape, composition, interparticle distance, dielectric constant, and surrounding medium of the particles [36][37]. While Pt, Ag, and Au particles all exhibit photothermal properties, Au nanoparticles are commonly used for photothermal applications. By changing the

Investigations on the optical forces from three mainstream optical resonances in all-dielectric nanostructure arrays

• Guangdong Wang and
• Zhanghua Han

Beilstein J. Nanotechnol. 2023, 14, 674–682, doi:10.3762/bjnano.14.53

• (T) in the Cartesian coordinate system using the multipole decomposition technique. The multipole expansion is achieved based on the electric displacement current using the following formula: where ε0 represents the vacuum dielectric constant, n is the refractive index of the uniform background above

ZnO-decorated SiC@C hybrids with strong electromagnetic absorption

• Liqun Duan,
• Zhiqian Yang,
• Yilu Xia,
• Xiaoqing Dai,
• Jian’an Wu and
• Minqian Sun

Beilstein J. Nanotechnol. 2023, 14, 565–573, doi:10.3762/bjnano.14.47

• ·6H2O at the same filler load (20–50 wt %). This may be because both the real and imaginary parts of the carbon permittivity are higher than those of ZnO. Comparing the dielectric constant of SCZ0.5 and SiC@C at the same filler load of 30 wt %, the ε′ and ε″ values of SCZ0.5 are lower than the

Carbon nanotube-cellulose ink for rapid solvent identification

• Tiago Amarante,
• Thiago H. R. Cunha,
• Claudio Laudares,
• Ana P. M. Barboza,
• Ana Carolina dos Santos,
• Cíntia L. Pereira,
• Vinicius Ornelas,
• Bernardo R. A. Neves,
• André S. Ferlauto and
• Rodrigo G. Lacerda

Beilstein J. Nanotechnol. 2023, 14, 535–543, doi:10.3762/bjnano.14.44

• two important properties of the liquids, namely dielectric constant and vapor pressure, on the transduction of the MFC-MWCNT sensors. These results were corroborated by independent heat flow measurements (thermogravimetric analysis). The proposed MFC-MWCNT sensor platform may help paving the way to

• mechanism of polymer composites with physicochemical characteristics such as dielectric constant, specific heat, and vapor pressure [25][56][57]. Our ink-based devices could extract those characteristics even from unknown samples and mixtures. Finally, test analysis using principal component analysis (PCA

• ) with physicochemical properties of the organic solvents (vapor pressure and dielectric constant) [63][64]. Guided by previous studies that show the electrical response is due to the swelling of CPCs [25][56][57], we found that the maximum value in the Gain curve (max) is proportional to the dielectric

Plasmonic nanotechnology for photothermal applications – an evaluation

• A. R. Indhu,
• L. Keerthana and
• Gnanaprakash Dharmalingam

Beilstein J. Nanotechnol. 2023, 14, 380–419, doi:10.3762/bjnano.14.33

• constant of the surrounding medium and hence the LSPR frequency can be arrived at as [39]: Thus, for any morphology of a plasmonic nanoparticle, the LSPR frequency is intimately tied to the free electron density and the dielectric constant of the surrounding matrix. These factors thus decide the shape

• different morphologies on plasmon excitation can be understood are hence crucial for assessing the PT properties of nanomaterials. 2.1.1 Tunability of the plasmon frequency – changes to the dielectric constant. In 1834, William Whewell coined the term dielectric [41]. In a dielectric material, positive

• shown in prior sections) [42]. The real (εr) and imaginary part (εi) of the dielectric constant relate to the refractive index (n) and extinction coefficient (k), respectively. Energy from a time-varying incident electric field is dissipated in part as heat, termed as dielectric loss. It can be

Concentration-dependent photothermal conversion efficiency of gold nanoparticles under near-infrared laser and broadband irradiation

• Vikas,
• Raj Kumar and
• Sanjeev Soni

Beilstein J. Nanotechnol. 2023, 14, 205–217, doi:10.3762/bjnano.14.20

• ]. Localized heat generation through GNPs under irradiation can be used for hyperthermia treatment of tumors, termed plasmonic photothermal therapy (PPTT) [7][8][9][10][11]. The net temperature rise of a GNP-containing medium highly depends on shape and size of the GNPs, the dielectric constant of the medium

High–low Kelvin probe force spectroscopy for measuring the interface state density

• Ryo Izumi,
• Masato Miyazaki,
• Yan Jun Li and
• Yasuhiro Sugawara

Beilstein J. Nanotechnol. 2023, 14, 175–189, doi:10.3762/bjnano.14.18

• on the semiconductor surface and ε0 is the dielectric constant of vacuum. A bias voltage Vdc + Vac·cos 2πft is applied between the tip and the semiconductor sample, where Vdc, Vac, and f are the DC bias voltage, amplitude of the AC bias voltage, and modulation frequency of the AC bias voltage

• dielectric constant. LD is the Debye length for majority carriers (electrons), which characterizes the change in the potential inside the semiconductor. kB, T and e are the Boltzmann constant, absolute temperature, and elementary charge (e > 0), respectively. Since the applied voltage V is divided between

Batch preparation of nanofibers containing nanoparticles by an electrospinning device with multiple air inlets

• Dong Wei,
• Chengwei Ye,
• Adnan Ahmed and
• Lan Xu

Beilstein J. Nanotechnol. 2023, 14, 141–150, doi:10.3762/bjnano.14.15

• density of spinning solution (kg/m3), g is the gravitational acceleration (m/s2), h is the fluctuation height of the polymer spinning solution (m), γ is the surface tension coefficient of the spinning solution (N/m), ε0 is vacuum dielectric constant, E0 is the edge electric field intensity (V/m), Ep is

• the electric field intensity of the thin liquid surface (V/m), εα is the dielectric constant of the polymer, and k is the amount of radial fluctuations on the spinning solution surface. In addition, the centripetal force F1 at point B is generated by the horizontal component of the viscous force (τ

Solvent-induced assembly of mono- and divalent silica nanoparticles

• Bin Liu,
• Etienne Duguet and
• Serge Ravaine

Beilstein J. Nanotechnol. 2023, 14, 52–60, doi:10.3762/bjnano.14.6

• Instruments). The dielectric constant of water was set to 80.4 and the Smoluchowsky constant f(ka) was 1.5. Synthetic route for the preparation of 1-PSN with a controlled patch-to-particle size ratio. TEM images of the silica/PS monopods after (a) 0, (b) 1, (c) 2, (d) 4, (e) 9, and (f) 14 iterative silica