Beilstein J. Nanotechnol.2025,16, 1677–1694, doi:10.3762/bjnano.16.118
is largely derived from ex situ surface analysis using XPS and scanning tunneling microscopy. However, the findings of UHV-XPS do not accurately represent the genuine passivefilm/electrolyte interface. APXPS is essential to observe the onset and progression of corrosion and to gain a fundamental
near the alloy’s surface, exacerbating metal dissolution. The passivefilm breakdown has been studied for different acidities of the electrolyte solution, as reported in Figure 14. A parallel study extended these findings to martensitic stainless steel, offering further insights into the chemical
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Figure 1:
Picture of the electrochemical APXPS setup at HIPPIE. The EEA on the left is facing the working ele...
Beilstein J. Nanotechnol.2022,13, 236–244, doi:10.3762/bjnano.13.18
); corrosion; friction; metallic glass; passivefilm; Introduction
Metallic glasses (MGs) exhibit excellent mechanical properties including extraordinary hardness and strength [1][2]. Thus, MGs have emerged as novel wear-resistant materials with high potential in tribological applications [3][4][5][6][7][8
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Figure 1:
(a) Potentiodynamic polarization curves of Zr63Ni22Ti15 metallic glass in 0.2 M NaCl solution and 0...