Beilstein J. Nanotechnol.2013,4, 345–351, doi:10.3762/bjnano.4.40
photocatalytic efficiency [8][9]. However, silver nanoparticles have prospective applications including biosensing, biodiagnostics, optical fibers, and antimicrobial and photocatalytic uses. Silverions are known to cause denaturation of proteins present in bacterial cell walls and slow down bacterial growth [5
]. The simplest photocatalytic mechanism of silverions is that it may take part in catalytic oxidation reactions between oxygen molecules in the cell and hydrogen atoms of thiol groups, i.e., two thiol groups become covalently bonded to one another through disulfide bonds (R–S–S–R), which leads to
not found with gold nanoparticles [12].
Previously, it was observed that doping of a TiO2 matrix with silverions moved the absorption to a longer wavelength, i.e., to the visible region in comparison with pure TiO2, due to the change in electronic and optical properties of TiO2 [13]. On the other
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Figure 1:
XRD pattern of (a) TiO2 and (b) 3% and (c) 7% Ag-doped TiO2 nanoparticles annealed at 450 °C.
Beilstein J. Nanotechnol.2012,3, 134–143, doi:10.3762/bjnano.3.14
larger metal grain [52] is, thus, not possible unless a critical number of silver atoms are simultaneously generated through the reduction of an equal number of closely located silverions. This can be accomplished at a target surface covered by a silver-binding monolayer such as OTSeo, in which the
pristine OTS surface is not possible because of the very low probability of nucleation and growth of metal grains on such a surface devoid of ion-binding functions [53]. Since the local concentration of hydrated silverions in solution in front of an OTS monolayer should be much lower than that of Ag+ ions
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Figure 1:
Scheme of parallel-contact electrochemical metallization of a OTSeo@OTS/Si template nanopattern (ta...