Beilstein J. Nanotechnol.2026,17, 737–743, doi:10.3762/bjnano.17.50
the efficiency of alkaline water electrolysis [1]. Developing robust and highly active OER electrocatalysts is therefore essential for practical hydrogen production and large-scale renewable energy conversion. Among numerous catalyst platforms, spineloxides (AB2O4) have attracted significant
, enhances metal–oxygen (M–O) covalency and optimizes the adsorption energies of key intermediates (*OH, *O, and *OOH), leading to improved reaction energetics [6][7][8].
Despite these advantages, synthesizing phase-pure spineloxides remains challenging when Cu is incorporated. Cu-based catalysts are
secondary phases (e.g., CuO or Cu2O) [11]. Thus, establishing an atmosphere-controlled synthesis route is critical for producing single-phase Cu-containing spineloxides with reliable and optimized electrocatalytic properties.
Herein, we demonstrate the synthesis of Cu–Rh bimetallic single-phase spinel
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Figure 1:
Schematic illustration of the synthesis procedure used in this study.
Beilstein J. Nanotechnol.2018,9, 1448–1470, doi:10.3762/bjnano.9.137
photocatalytic reduction of Cr(VI) along with their good recoverability and recyclability.
Keywords: charge transfer; Cr(VI) reduction; heterojunction; modified TiO2; photocatalysis; spineloxides; Review
Introduction
The increase in the global population demands rapid growth of industrialization and
because the hopping of electrons takes place between different valence states of metals in O-sites. This caused efficient transfer of charge carriers [180]. Hence, spineloxides are being recognized as the potential photocatalysts.
The modification of TiO2 with these metal oxides has shown promising
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Figure 1:
Speciation diagram of Cr(VI). Reprinted from [6], copyright 2016 Thermo Fisher Scientific Inc.