Colorimetric detection of Cu²⁺ based on the formation of peptide–copper complexes on silver nanoparticle surfaces

• Gajanan Sampatrao Ghodake,
• Surendra Krishna Shinde,
• Rijuta Ganesh Saratale,
• Avinash Ashok Kadam,
• Ganesh Dattatraya Saratale,
• Asad Syed,
• Fuad Ameen and
• Dae-Young Kim

Beilstein J. Nanotechnol. 2018, 9, 1414–1422, doi:10.3762/bjnano.9.134

• Cu2+-binding casein peptide ligands. The solution of aggregates was incubated for 20 min to allow for the coordination to occur. Results and Discussion Synthesis and characterization of casein peptide-capped AgNPs The surface plasmon resonance (SPR) of spherical AgNPs immediately caused an absorbance

Surface-plasmon-enhanced ultraviolet emission of Au-decorated ZnO structures for gas sensing and photocatalytic devices

• T. Anh Thu Do,
• Truong Giang Ho,
• Thu Hoai Bui,
• Quang Ngan Pham,
• Hong Thai Giang,
• Thi Thu Do,
• Duc Van Nguyen and
• Dai Lam Tran

Beilstein J. Nanotechnol. 2018, 9, 771–779, doi:10.3762/bjnano.9.70

• response/recovery times. The various origins of these properties are commonly assigned to the following two phenomena: (i) a surface plasmon resonance (SPR) effect of plasmonic gold nanoparticles (Au NPs) could certainly take place and contribute to the electrical transport behavior for Au-decorated ZnO

Colloidal solution of silver nanoparticles for label-free colorimetric sensing of ammonia in aqueous solutions

• Alessandro Buccolieri,
• Antonio Serra,
• Gabriele Giancane and
• Daniela Manno

Beilstein J. Nanotechnol. 2018, 9, 499–507, doi:10.3762/bjnano.9.48

• particular silver nanoparticles (AgNPs), are often considered for analytical application because of their peculiar optical and electrical properties [13]. The surface plasmon resonance (SPR) properties of metal nanoparticles are considered very useful for the use of colloidal solutions in the field of

Near-infrared-responsive, superparamagnetic Au@Co nanochains

• Varadee Vittur,
• Arati G. Kolhatkar,
• Shreya Shah,
• Irene Rusakova,
• Dmitri Litvinov and
• T. Randall Lee

Beilstein J. Nanotechnol. 2017, 8, 1680–1687, doi:10.3762/bjnano.8.168

• nanoparticles not only renders the nanoparticles biocompatible but also gives rise to distinct optical properties [18][19]. Noble metal nanoparticles, such as gold and silver, possess the unique property of surface plasmon resonance (SPR); the latter exhibit a strong extinction band in the visible region [19

Two-dimensional carbon-based nanocomposites for photocatalytic energy generation and environmental remediation applications

• Suneel Kumar,
• Ashish Kumar,
• Ashish Bahuguna,
• Vipul Sharma and
• Venkata Krishnan

Beilstein J. Nanotechnol. 2017, 8, 1571–1600, doi:10.3762/bjnano.8.159

Thin SnO_x films for surface plasmon resonance enhanced ellipsometric gas sensing (SPREE)

• Daniel Fischer,
• Andreas Hertwig,
• Uwe Beck,
• Volkmar Lohse,
• Detlef Negendank,
• Martin Kormunda and
• Norbert Esser

Beilstein J. Nanotechnol. 2017, 8, 522–529, doi:10.3762/bjnano.8.56

• the problems of cross sensitivity of the MOS concept. Results: Undoped tin oxide (SnOx) and iron doped tin oxide (Fe:SnOx) thin add-on films were prepared by magnetron sputtering on the top of the actual surface plasmon resonance (SPR) sensing gold layer. The films were tested for their sensitivity to

Influence of hydrofluoric acid treatment on electroless deposition of Au clusters

• Rachela G. Milazzo,
• Antonio M. Mio,
• Giuseppe D’Arrigo,
• Emanuele Smecca,
• Alessandra Alberti,
• Gabriele Fisichella,
• Filippo Giannazzo,
• Corrado Spinella and
• Emanuele Rimini

Beilstein J. Nanotechnol. 2017, 8, 183–189, doi:10.3762/bjnano.8.19

• shown quite interesting applications in the fields of Si nanowire (SiNW) catalysis [1][2][3], metal-assisted etching (MAE) [4] or even as electrical contacts in standard miniaturized devices [5]. Their ability to display enhanced surface plasmon resonance (SPR) at optical frequencies makes them

Streptavidin-coated gold nanoparticles: critical role of oligonucleotides on stability and fractal aggregation

• Roberta D'Agata,
• Pasquale Palladino and
• Giuseppe Spoto

Beilstein J. Nanotechnol. 2017, 8, 1–11, doi:10.3762/bjnano.8.1

• relevant ligands has led to dramatic progresses in both living cells as well as biomolecular diagnostic assays [3][4][5]. In particular, optical sensing exploiting the surface plasmon resonance (SPR) effect has been widely investigated and plays a significant role in biomolecular detection [6][7]. In this

Functionalized platinum nanoparticles with surface charge trigged by pH: synthesis, characterization and stability studies

• Giovanna Testa,
• Laura Fontana,
• Iole Venditti and
• Ilaria Fratoddi

Beilstein J. Nanotechnol. 2016, 7, 1822–1828, doi:10.3762/bjnano.7.175

• interest for many technological applications [1][2]. For example PtNPs are of interest due to their catalytic activity [3][4], electrochemical applications [5], chemical sensing [6][7][8][9] and optical features related to surface plasmon resonance (SPR) that occurs in the ultraviolet range of

Hydrophilic silver nanoparticles with tunable optical properties: application for the detection of heavy metals in water

• Paolo Prosposito,
• Federico Mochi,
• Erica Ciotta,
• Mauro Casalboni,
• Fabio De Matteis,
• Iole Venditti,
• Laura Fontana,
• Giovanna Testa and
• Ilaria Fratoddi

Beilstein J. Nanotechnol. 2016, 7, 1654–1661, doi:10.3762/bjnano.7.157

• nitrate as precursor molecules, hydrophilic thiol (3-mercapto-1-propanesulfonic acid sodium salt, 3MPS) and sodium borohydride as capping and reducing agents, respectively. The AgNPs were characterized using techniques such as surface plasmon resonance (SPR) spectroscopy, dynamic light scattering (DLS

• the field of sensors for specific analytes [7][8][9][10]. In particular, given their flexible and easy preparation, large specific surface area, and surface plasmon resonance (SPR) properties, metal nanoparticles are excellent candidates for a wide variety of applications ranging from catalysis [11

Highly compact refractive index sensor based on stripe waveguides for lab-on-a-chip sensing applications

• Chamanei Perera,
• Kristy Vernon,
• Elliot Cheng,
• Juna Sathian,
• Esa Jaatinen and
• Timothy Davis

Beilstein J. Nanotechnol. 2016, 7, 751–757, doi:10.3762/bjnano.7.66

• highly sensitive to the surrounding dielectric environment. This unique property is incredibly useful in sensing applications. Mach–Zehnder (MZ) interferometry [1][2][3][4][5], surface enhanced Raman spectroscopy (SERS) [6][7][8][9], ring resonators [10] and surface plasmon resonance (SPR) [11][12][13

Gold nanoparticles covalently assembled onto vesicle structures as possible biosensing platform

• M. Fátima Barroso,
• M. Alejandra Luna,
• Juan S. Flores Tabares,
• Cristina Delerue-Matos,
• N. Mariano Correa,
• Fernando Moyano and
• Patricia G. Molina

Beilstein J. Nanotechnol. 2016, 7, 655–663, doi:10.3762/bjnano.7.58

• ]. Note, that when the AuNPs are formed after 8 and 13 min of UV irradiation, bands corresponding to the surface plasmon resonance (SPR) around 520 or 550 nm appeared. This maximum wavelength (λmax) is in accordance with other reported studies [26][29][30], and the small differences founded in the λmax

Investigating organic multilayers by spectroscopic ellipsometry: specific and non-specific interactions of polyhistidine with NTA self-assembled monolayers

• Ilaria Solano,
• Pietro Parisse,
• Ornella Cavalleri,
• Federico Gramazio,
• Loredana Casalis and
• Maurizio Canepa

Beilstein J. Nanotechnol. 2016, 7, 544–553, doi:10.3762/bjnano.7.48

• . Optical methods based on optical reflectivity, such as surface plasmon resonance (SPR) and ellipsometry, allow for label-free, non-invasive, in situ monitoring of molecular adsorption/desorption at surfaces [34][35][36][37][38][39][40]. While SPR-based methods require supports with specific plasmonic

Characterisation of thin films of graphene–surfactant composites produced through a novel semi-automated method

• Nik J. Walch,
• Alexei Nabok,
• Frank Davis and
• Séamus P. J. Higson

Beilstein J. Nanotechnol. 2016, 7, 209–219, doi:10.3762/bjnano.7.19

• similar manner. TIRE study The surface plasmon resonance (SPR) phenomenon in graphene films deposited on thin films of gold was studied in more detail using the method of total internal reflection ellipsometry (TIRE), which was developed in the last decade [12][13][14]. TIRE experimental set-up (shown

Green and energy-efficient methods for the production of metallic nanoparticles

• Mitra Naghdi,
• Mehrdad Taheran,
• Satinder K. Brar,
• M. Verma,
• R. Y. Surampalli and
• J. R. Valero

Beilstein J. Nanotechnol. 2015, 6, 2354–2376, doi:10.3762/bjnano.6.243

• range of 40–200 nm [86]. Also, Wei et al. used CTS in aqueous solution of AgNO3 and HAuCl4 to act as reducing agent and scaffold for the formation of Au and Ag NPs. They used surface plasmon resonance (SPR) analysis to confirm the formation of NPs [29]. In related reports, they used TEM analysis and

Self-organization of gold nanoparticles on silanated surfaces

• Htet H. Kyaw,
• Salim H. Al-Harthi,
• Azzouz Sellai and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2015, 6, 2345–2353, doi:10.3762/bjnano.6.242

• structures [8]. AuNPs have been studied intensively for a wide range of applications such as catalysis [9], biosensing [10], colorimetric sensing [11], optical sensing (surface plasmon resonance (SPR) and surface-enhanced Raman scattering (SERS)) [12][13], photonics [13][14], photovoltaic devices [15] and

• driving force for migrating on the surface during annealing process leading to no specific reorganisation of AuNPs. Figure 8 shows ultraviolet–visible absorption spectra of AuNPs deposited on APTES-functionalized glass substrates (before and after annealing in air and vacuum). Surface plasmon resonance

• (SPR) signals show band broadening in as deposited sample and the sample annealed in vacuum. A shoulder observed at 672 nm (marked as a region) for the sample annealed in vacuum is due to the alignment of the AuNPs on the glass substrate (see Figure 7b). Moreover, some AuNPs combined in a specific

Conformational switching of ethano-bridged Cu,H₂-bis-porphyrin induced by aromatic amines

• Simona Bettini,
• Emanuela Maglie,
• Rosanna Pagano,
• Victor Borovkov,
• Yoshihisa Inoue,
• Ludovico Valli and
• Gabriele Giancane

Beilstein J. Nanotechnol. 2015, 6, 2154–2160, doi:10.3762/bjnano.6.221

• bis-porphyrin derivative. The Langmuir–Schaefer technique has been used to transfer the floating bis-porphyrin film (when using pure water as a subphase) to a surface plasmon resonance (SPR) substrate and the resulting device was able to detect the presence of aniline at concentrations as low as 1 nM

Protein corona – from molecular adsorption to physiological complexity

• Lennart Treuel,
• Dominic Docter,
• Michael Maskos and
• Roland H. Stauber

Beilstein J. Nanotechnol. 2015, 6, 857–873, doi:10.3762/bjnano.6.88

• adsorption such as isothermal titration calorimetry (ITC) [82][83], and surface plasmon resonance (SPR) [22][84]. Moreover, techniques based on the size of proteins and protein–NP complexes have been utilized such as size-exclusion chromatography (SEC) [85][86][87][88][89][90] or one- and two-dimensional

Synergic combination of the sol–gel method with dip coating for plasmonic devices

• Cristiana Figus,
• Maddalena Patrini,
• Francesco Floris,
• Lucia Fornasari,
• Paola Pellacani,
• Gerardo Marchesini,
• Andrea Valsesia,
• Flavia Artizzu,
• Daniela Marongiu,
• Michele Saba,
• Franco Marabelli,
• Andrea Mura,
• Giovanni Bongiovanni and
• Francesco Quochi

Beilstein J. Nanotechnol. 2015, 6, 500–507, doi:10.3762/bjnano.6.52

• an extended time and inducing a suitable reduction of the regeneration time of the chip. Keywords: biosensors; nanodevices; plasmonics; sol–gel; thin films; Introduction Plasmonic nanostructures have gained increasing attention for their surface plasmon resonance (SPR)-related properties, which can

Influence of size, shape and core–shell interface on surface plasmon resonance in Ag and Ag@MgO nanoparticle films deposited on Si/SiO_x

• Sergio D’Addato,
• Daniele Pinotti,
• Maria Chiara Spadaro,
• Guido Paolicelli,
• Vincenzo Grillo,
• Sergio Valeri,
• Luca Pasquali,
• Luca Bergamini and
• Stefano Corni

Beilstein J. Nanotechnol. 2015, 6, 404–413, doi:10.3762/bjnano.6.40

• atmosphere gave rise to formation of a MgO shell matrix surrounding the Ag NPs. The behaviour of the surface plasmon resonance (SPR) excitation in surface differential reflectivity (SDR) spectra with p-polarised light was investigated for bare Ag and Ag@MgO NPs. It was shown that the presence of MgO around

• , it was found that Au NPs [5] and Ag NPs [6] deposited on thin film- and wafer-based Si solar cells can enhance their photon absorption due to the occurrence of surface plasmon resonance (SPR), which serves to scatter the incident radiation in the UV–vis region and to increase the light trapping

Properties of plasmonic arrays produced by pulsed-laser nanostructuring of thin Au films

• Katarzyna Grochowska,
• Katarzyna Siuzdak,
• Peter A. Atanasov,
• Carla Bittencourt,
• Anna Dikovska,
• Nikolay N. Nedyalkov and
• Gerard Śliwiński

Beilstein J. Nanotechnol. 2014, 5, 2102–2112, doi:10.3762/bjnano.5.219

• characterized by a short-distance order (length scale ≈140 nm). For the NP shapes produced, an observably broader tuning range (of about 150 nm) of the surface plasmon resonance (SPR) band is obtained by renewal thin film deposition and laser annealing of the NP array. Despite the broadened SPR bands, which

• surface plasmon resonance (SPR) peak around 520 nm resulted in the observable decrease of the film roughness and resistivity [14]. In case of nanostructuring of a thin Au film by a pulsed-laser beam passing through a pinhole (60 μm), the forced arrangement of nanospheres into micro-circular patterns due

Protein-coated pH-responsive gold nanoparticles: Microwave-assisted synthesis and surface charge-dependent anticancer activity

• Dickson Joseph,
• Nisha Tyagi,
• Christian Geckeler and
• Kurt E.Geckeler

Beilstein J. Nanotechnol. 2014, 5, 1452–1462, doi:10.3762/bjnano.5.158

• addition of 1 N HCl or 1 N NaOH. The UV–vis spectroscopic studies revealed that the intrinsic pH of the protein led to the formation of AuNPs with strong surface plasmon resonance (SPR) bands. However, at acidic, neutral and basic pH conditions, either AuNPs with weak SPR bands or no AuNPs were formed

Microstructural and plasmonic modifications in Ag–TiO₂ and Au–TiO₂ nanocomposites through ion beam irradiation

• Venkata Sai Kiran Chakravadhanula,
• Yogendra Kumar Mishra,
• Venkata Girish Kotnur,
• Devesh Kumar Avasthi,
• Thomas Strunskus,
• Vladimir Zaporotchenko,
• Dietmar Fink,
• Lorenz Kienle and
• Franz Faupel

Beilstein J. Nanotechnol. 2014, 5, 1419–1431, doi:10.3762/bjnano.5.154

• dielectric constant of the embedding matrix [5][6]. As the dielectric constant in the expression for extinction coefficient (denominator), hence the refractive index of the matrix plays a very important role in surface plasmon resonance (SPR). Several dielectric matrices, such as SiO2 and polymers have been

Purification of ethanol for highly sensitive self-assembly experiments

• Kathrin Barbe,
• Martin Kind,
• Christian Pfeiffer and
• Andreas Terfort

Beilstein J. Nanotechnol. 2014, 5, 1254–1260, doi:10.3762/bjnano.5.139

• long exposure times, it has been found that for kinetic studies even very minor contaminations can significantly affect the measurements [29]. Of the different time-resolved methods to determine monolayer formation, surface-plasmon resonance (SPR) [30][31] and a resistivity sensor developed by Bohn et

Nanostructure sensitization of transition metal oxides for visible-light photocatalysis

• Hongjun Chen and
• Lianzhou Wang

Beilstein J. Nanotechnol. 2014, 5, 696–710, doi:10.3762/bjnano.5.82

• and facilitates the vectorial electron transfer. Plasmonic metal nanostructures as the photosensitizer Surface plasmon resonance (SPR) is the resonant photon-induced collective oscillation of valence electrons, which happens only if the frequency of photons matches the natural frequency of surface