Intake of silica nanoparticles by giant lipid vesicles: influence of particle size and thermodynamic membrane state

• Florian G. Strobl,
• Florian Seitz,
• Christoph Westerhausen,
• Armin Reller,
• Adriano A. Torrano,
• Christoph Bräuchle,
• Achim Wixforth and
• Matthias F. Schneider

Beilstein J. Nanotechnol. 2014, 5, 2468–2478, doi:10.3762/bjnano.5.256

• saddle splay modulus is often neglected, as it can be shown that during morphological transitions of a membrane without a change in topology this term is constant [17]. However, for the case of a complete uptake involving fission, this contribution has to be considered. Starting from Equation 1, one can

Quasi-1D physics in metal-organic frameworks: MIL-47(V) from first principles

• Danny E. P. Vanpoucke,
• Jan W. Jaeken,
• Stijn De Baerdemacker,
• Kurt Lejaeghere and
• Veronique Van Speybroeck

Beilstein J. Nanotechnol. 2014, 5, 1738–1748, doi:10.3762/bjnano.5.184

• ][10][11][12][13][14][15][16][17][18][19][20][21][22]. In addition to providing large internal surface areas, the framework topology also allows to organize metal sites in a well-defined, ordered fashion, creating zero-, one- and two-dimensional metal(-oxide) structures. Such structures provide

• ) The topology of MIL-47(V) provides access to 1D metal-oxide chains. (2) The V version provides one unpaired electron per metal site, which is of interest for magnetic properties. (3) MIL-47 belongs to the family of so-called breathing MOFs [4][11][43][44][45][46][47][48][49], leading to interesting

• (V) The periodic cell used in this work contains 4 formula units or 72 atoms, and is shown in Figure 1a. This cell contains 2 vanadium oxide chains with 2 vanadium atoms per chain. Each V atom contains one unpaired d-electron, since the V atoms have a formal charge of +IV in the MIL-47(V) topology

Topology assisted self-organization of colloidal nanoparticles: application to 2D large-scale nanomastering

• Hind Kadiri,
• Serguei Kostcheev,
• Daniel Turover,
• Rafael Salas-Montiel,
• Komla Nomenyo,
• Anisha Gokarna and
• Gilles Lerondel

Beilstein J. Nanotechnol. 2014, 5, 1203–1209, doi:10.3762/bjnano.5.132

• , Cedex, France SILSEF SAS, 382 Rue Louis Rustin, Archamps Technopole, 74160 Archamps, France 10.3762/bjnano.5.132 Abstract Our aim was to elaborate a novel method for fully controllable large-scale nanopatterning. We investigated the influence of the surface topology, i.e., a pre-pattern of hydrogen

• silsesquioxane (HSQ) posts, on the self-organization of polystyrene beads (PS) dispersed over a large surface. Depending on the post size and spacing, long-range ordering of self-organized polystyrene beads is observed wherein guide posts were used leading to single crystal structure. Topology assisted self

• contains defects that limit its application. The purpose of using patterned substrates is to control these defects and obtain a single crystal structure on a large scale, however, this technique (grapho-epitaxy) works well only on a small scale. In this study, we concentrated on topology-assisted self

The softening of human bladder cancer cells happens at an early stage of the malignancy process

• Jorge R. Ramos,
• Joanna Pabijan,
• Ricardo Garcia and
• Malgorzata Lekka

Beilstein J. Nanotechnol. 2014, 5, 447–457, doi:10.3762/bjnano.5.52

• provides the information about fluorescently labeled structures while AFM delivers the topology and the mechanical properties of the sample. In our studies, the fluorescent images of actin filaments were compared with the surface topography. The cytoskeleton is important for a normal cell function, however

Modeling and optimization of atomic layer deposition processes on vertically aligned carbon nanotubes

• Nuri Yazdani,
• Vipin Chawla,
• Eve Edwards,
• Vanessa Wood,
• Hyung Gyu Park and
• Ivo Utke

Beilstein J. Nanotechnol. 2014, 5, 234–244, doi:10.3762/bjnano.5.25

• coatings of VACNT arrays. However, the approach can be applied to predict film conformality as a function of depth for any porous topology, including nanopores and nanowire arrays. Keywords: atomic layer deposition; vertically aligned carbon nanotubes; continuum diffusion model; conformal coating

• (VACNT) arrays present a complex surface and topology for ALD that requires new processing strategies. First, the graphitic surface of a pristine CNT is chemically inert, and provides no bonding sites for the nucleation of ceramics, which prevents the conformal coating of the CNT without prior

• penetration depth valid for any porous topology with high aspect ratio provided that the reactive sticking is close to one (Γ ≈ 1). It only requires the determination of (1) an effective diffusion coefficient related to the porosity, constrictivity, and tortuosity of the porous medium and of (2) the surface

Design criteria for stable Pt/C fuel cell catalysts

• Josef C. Meier,
• Carolina Galeano,
• Ioannis Katsounaros,
• Jonathon Witte,
• Hans J. Bongard,
• Angel A. Topalov,
• Claudio Baldizzone,
• Stefano Mezzavilla,
• Ferdi Schüth and
• Karl J. J. Mayrhofer

Beilstein J. Nanotechnol. 2014, 5, 44–67, doi:10.3762/bjnano.5.5

• network with two maxima in the pore size distribution around 4 and 10 nm [71]. When comparing the untreated and the electrochemically treated catalyst locations in Figure 4, the major observation is that no significant changes take place, neither in the morphology nor in the external surface topology of

Spin relaxation in antiferromagnetic Fe–Fe dimers slowed down by anisotropic Dy^III ions

• Valeriu Mereacre,
• Frederik Klöwer,
• Yanhua Lan,
• Rodolphe Clérac,
• Juliusz A. Wolny,
• Volker Schünemann,
• Christopher E. Anson and
• Annie K. Powell

Beilstein J. Nanotechnol. 2013, 4, 807–814, doi:10.3762/bjnano.4.92

• ligands, are arranged in the well-known "butterfly" shape. The two FeIII ions form the “wingtips” and the DyIII ions define the “body” of the butterfly, with the two hydroxo ligands each bridging a FeDy2 triangle. The typical butterfly topology has a planar Fe2Dy2 unit, with the two (µ3-OH) bridges on

Atomic force microscopy recognition of protein A on Staphylococcus aureus cell surfaces by labelling with IgG–Au conjugates

• Elena B. Tatlybaeva,
• Hike N. Nikiyan,
• Alexey S. Vasilchenko and
• Dmitri G. Deryabin

Beilstein J. Nanotechnol. 2013, 4, 743–749, doi:10.3762/bjnano.4.84

• operating conditions [4]. These benefits allow for the development of highly sensitive high-resolution methods for the detection of individual structures or labels on the surface of microorganisms. These, in turn, open wide prospects for the estimation of the exact quantity of bound markers, their topology

Large-scale atomistic and quantum-mechanical simulations of a Nafion membrane: Morphology, proton solvation and charge transport

• Pavel V. Komarov,
• Pavel G. Khalatur and
• Alexei R. Khokhlov

Beilstein J. Nanotechnol. 2013, 4, 567–587, doi:10.3762/bjnano.4.65

• formation of conductive channels and their topology was obtained from analysis of slices through the hydrophilic subphase (for more detail, see [27]). It was found that the hydrophilic subphase is organized like a sponge-like network and the global membrane morphology can be classified as bicontinuous: both

Ferromagnetic behaviour of Fe-doped ZnO nanograined films

• Boris B. Straumal,
• Svetlana G. Protasova,
• Andrei A. Mazilkin,
• Thomas Tietze,
• Eberhard Goering,
• Gisela Schütz,
• Petr B. Straumal and
• Brigitte Baretzky

Beilstein J. Nanotechnol. 2013, 4, 361–369, doi:10.3762/bjnano.4.42

• and Co concentration is different for the Mn- and Co-doped nanograined ZnO manufactured by different methods. It is most probably controlled by the topology of the GB network (ferromagnetic GB foam) in the ZnO polycrystals. Our findings strongly suggest that GBs and related vacancies are the intrinsic

• can tailor the thickness of the amorphous intergranular layer and, thus, increase or decrease the Js value [70]. It is well known that GBs with different character possess different adsorption ability [72][73]. If the GB networks have different topology, the GBs having various adsorption ability will

Revealing thermal effects in the electronic transport through irradiated atomic metal point contacts

• Bastian Kopp,
• Zhiwei Yi,
• Daniel Benner,
• Fang-Qing Xie,
• Christian Obermair,
• Thomas Schimmel,
• Johannes Boneberg,
• Paul Leiderer and
• Elke Scheer

Beilstein J. Nanotechnol. 2012, 3, 703–711, doi:10.3762/bjnano.3.80

• topology of the electrochemically closed contact is taken into account, as sketched in Figure 8a. Actually, one is not dealing with a single, but rather with two point contacts, namely an Au–Ag and an Ag–Au contact in series. These act as a thermocouple in which the sensor and the reference contact are

Parallel- and serial-contact electrochemical metallization of monolayer nanopatterns: A versatile synthetic tool en route to bottom-up assembly of electric nanocircuits

• Jonathan Berson,
• Assaf Zeira,
• Rivka Maoz and
• Jacob Sagiv

Beilstein J. Nanotechnol. 2012, 3, 134–143, doi:10.3762/bjnano.3.14

• nucleate and grow only on monolayer-template surfaces exposing chemically active functions that bind the respective metal ions, the morphology and lateral distribution of the resulting metal features thus depending on the local dimensions and topology of the template features on which the metal grains

Electron-beam patterned self-assembled monolayers as templates for Cu electrodeposition and lift-off

• Zhe She,
• Andrea DiFalco,
• Georg Hähner and
• Manfred Buck

Beilstein J. Nanotechnol. 2012, 3, 101–113, doi:10.3762/bjnano.3.11

• patterned SAM, Z0 becomes a function of the exposed topology. For aromatic SAMs, such as MBP0, which exhibit negative-resist behaviour, the density of nucleation sites Z0 is determined by the extent of cross-linking of the molecules. While the exact relationship between the defect size in the SAM and the

Size-dependent phase diagrams of metallic alloys: A Monte Carlo simulation study on order–disorder transitions in Pt–Rh nanoparticles

• Johan Pohl,
• Christian Stahl and
• Karsten Albe

Beilstein J. Nanotechnol. 2012, 3, 1–11, doi:10.3762/bjnano.3.1

• redeveloped on a more intuitive foundation [7] under the term “nanothermodynamics” [8] by the same author. Recent microcanonical approaches pioneered by Gross et al. [9][10] explore the topology of the entropy surface S(E,Ni) as a function of the energy E and the particle number N. Studying the entropy

When “small” terms matter: Coupled interference features in the transport properties of cross-conjugated molecules

• Gemma C. Solomon,
• Justin P. Bergfield,
• Charles A. Stafford and
• Mark A. Ratner

Beilstein J. Nanotechnol. 2011, 2, 862–871, doi:10.3762/bjnano.2.95

• electronics; quantum interference; thermoelectrics; topology; Introduction Destructive interference effects, such as nodes in the transmission function, are a signature of coherence and offer a possible avenue for tuning the transport properties of single-molecule junctions. While not present in all systems

• investigate the transport through several acyclic cross-conjugated molecules and show that maintaining degenerate interference features in these systems may be challenging. As a basis for comparison, we use Hückel theory transport calculations to understand what can be expected from the topology alone. Using

• calculate the transport with an atomistic model of the system, going beyond simple topology to include the through-space interactions that arise from the three-dimensional nature of chemical structures. Molecular geometries were obtained by optimizing the isolated molecule using Q-Chem 3.0 [26] with density

Deconvolution of the density of states of tip and sample through constant-current tunneling spectroscopy

• Holger Pfeifer,
• Berndt Koslowski and
• Paul Ziemann

Beilstein J. Nanotechnol. 2011, 2, 607–617, doi:10.3762/bjnano.2.64

• developing a reliable deconvolution scheme shifts the focus towards how to access the actual transmission probability function. Keywords: deconvolution; Nb DOS; STM; STS; Introduction Undoubtedly, the power of scanning tunneling microscopy (STM) is based on its capability to map the surface topology of a

Micro to nano: Surface size scale and superhydrophobicity

• Christian Dorrer and
• Jürgen Rühe

Beilstein J. Nanotechnol. 2011, 2, 327–332, doi:10.3762/bjnano.2.38

• following lines: I) We compare the dewetting process for a surface with a large size scale with that for a surface with a smaller size scale, both with the same solid fraction and the same topology. For the surface with the larger roughness features, the receding meniscus has to dewet from fewer, but larger

The description of friction of silicon MEMS with surface roughness: virtues and limitations of a stochastic Prandtl–Tomlinson model and the simulation of vibration-induced friction reduction

• W. Merlijn van Spengen,
• Viviane Turq and
• Joost W. M. Frenken

Beilstein J. Nanotechnol. 2010, 1, 163–171, doi:10.3762/bjnano.1.20

• in the literature as the ‘surface topology model of stick-slip’ [23]. Based on this notion that ξ(x) is proportional to the surface roughness in MEMS, a measurement of the typical topology of the sidewall surface is required. We have made a special MEMS tribometer to do this, in which the counter

On the reticular construction concept of covalent organic frameworks

• Binit Lukose,
• Agnieszka Kuc,
• Johannes Frenzel and
• Thomas Heine

Beilstein J. Nanotechnol. 2010, 1, 60–70, doi:10.3762/bjnano.1.8

• [H] (connector IV), and the linkers between linear [l] (linkers a, b, e) and trigonal [t] (linkers c, d). Topology of the layer is determined by the geometries of the connector and linker molecules, and typically a hexagonal pattern is formed due to the D3h symmetry of the connector moieties. Based

• and the corresponding linkers. This process requires a release of three or six water molecules in case of t or l topology, respectively. Co-condensation of the above molecular units with compounds such as 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP), hexahydroxybenzene (HHB) and dodecahydroxycoronene