Influence of ion beam current on the structural, optical, and mechanical properties of TiO₂ coatings: ion beam-assisted vs conventional electron beam evaporation

• Agata Obstarczyk and
• Urszula Wawrzaszek

Beilstein J. Nanotechnol. 2025, 16, 1097–1112, doi:10.3762/bjnano.16.81

• ; Introduction One of the commonly used methods for the deposition of various materials for thin film optical coatings, is electron beam evaporation (EBE) [1][2][3][4][5]. Today, in many applications, including medicine, telecommunications, optoelectronics, photovoltaics, the requirements for optical coatings

• , S3A, and S4A, respectively. The deposition parameters are shown in Table 1. Like in our previous reports [23][24], additional post-process modification of as-prepared thin films was carried out, that is, annealing at 800 °C (Nabertherm tubular furnace). The post-process annealing was carried out for 2

• ion gun current from 3 to 4 A caused a decrease in crystallite size from 34.7 to 30.8 nm after annealing (Figure 1d). The results of the structure analysis are shown in Table 2. Based on the XRD patterns, there is no evidence for the occurrence of TiO2 with the rutile phase, as its specific peaks were

Fabrication of metal complex phthalocyanine and porphyrin nanoparticle aqueous colloids by pulsed laser fragmentation in liquid and their potential application to a photosensitizer for photodynamic therapy

• Taisei Himeda,
• Risako Kunitomi,
• Ryosuke Nabeya,
• Tamotsu Zako and
• Tsuyoshi Asahi

Beilstein J. Nanotechnol. 2025, 16, 1088–1096, doi:10.3762/bjnano.16.80

• biological optical window (wavelengths from 650 to 1000 nm) and have recently attracted attention for applications in biomedical research such as photoacoustic imaging of tissues and PDT of tumors [2][3]. Porphyrins and Pcs are hydrophobic hydrocarbons that are insoluble in water. Hence, polymer composite

• nanoparticles and nanomicelle encapsulation have been used to disperse them in water [2][3][4][5][6][7]. For example, AlClPc has been loaded into nanoemulsions using castor oil and Cremophor ELP® [5]. ZnPc was dispersed in unilamellar liposomes by a solvent exchange method [7][8], and its photocytotoxicity

• % concentration of F-127 solution is described in detail in Figure 2. This concentration is about one tenth of the critical micelle concentration (CMC = 0.7 wt % at 25 °C) [29]. The AlClPc/F-127 aqueous suspension (0.02 wt %/0.1 wt %) was sonicated for 20 min. Then, 2 mL of the suspension was placed in a plastic

Single-layer graphene oxide film grown on α-Al₂O₃(0001) for use as an adsorbent

• Shiro Entani,
• Mitsunori Honda,
• Masaru Takizawa and
• Makoto Kohda

Beilstein J. Nanotechnol. 2025, 16, 1082–1087, doi:10.3762/bjnano.16.79

• deposition; electronic state analysis; graphene oxide; X-ray absorption fine structure; Introduction Graphene oxide (GO) is oxidized graphene and its surface and periphery are partially modified by epoxy, hydroxy, and carboxy functional groups [1][2]. GO can be thinned to a monolayer of one carbon atom and

• structure are confirmed by Raman spectroscopy measurements. Figure 2 shows two sets of the Raman spectra of SLG and SLGO. In SLG/α-Al2O3(0001), four prominent peaks are identified, which are assigned to the D band (around 1355 cm−1), G band (around 1585 cm−1), 2D band (around 2700 cm−1), and D+G band

• -yield method was employed to obtain the spectra. The amount of Cs adsorption was inspected by XPS. The energy scan for XPS was done with a VSW CLASS 100 hemispherical energy analyzer. An Al Kα (1486.6 eV) X-ray source (PSP TX400/2) was used for the excitation. In the XPS measurement, the CsCl solution

Piezoelectricity of hexagonal boron nitrides improves bone tissue generation as tested on osteoblasts

• Sevin Adiguzel,
• Nilay Cicek,
• Zehra Cobandede,
• Feray B. Misirlioglu,
• Hulya Yilmaz and
• Mustafa Culha

Beilstein J. Nanotechnol. 2025, 16, 1068–1081, doi:10.3762/bjnano.16.78

• undergoes continuous remodeling, where old bone is replaced with new tissue, a process that becomes particularly prominent once bones reach peak mass and continues through adulthood, replacing most of the skeleton approximately every decade [1]. Hydroxyapatite crystals (Ca10(PO4)6(OH)2) form through the

• nucleation of calcium and phosphate ions, imparting stiffness and resistance to bone. Additionally, collagen and noncollagenous matrix proteins contribute to bone formation by offering a scaffold for hydroxyapatite deposition [2][3]. Bone tissue consists of four main cell types: bone lining cells

• structural changes [2]. Bone has an intrinsic regenerative capacity, enabling new bone formation after injury through the piezoelectric properties of its natural collagen structure. The piezoelectricity of bone tissue facilitates regeneration by converting mechanical stimuli into electrical signals. This

Soft materials nanoarchitectonics: liquid crystals, polymers, gels, biomaterials, and others

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2025, 16, 1025–1067, doi:10.3762/bjnano.16.77

• materials, collectively known as “soft materials” [1][2][3][4][5], may be indicative of the significant advancements made in materials science. In the past, materials that were robust, rigid, and durable were esteemed. Nevertheless, the significance of materials endowed with intelligent capabilities that

• control the structure of discotic liquid crystal molecular nanowires by manipulating the subphase temperature and surface pressure in a Langmuir monolayer system (Figure 2) [226]. The LB technique represents a powerful methodology that allows for effective control over the assembly of molecular-sized

Multifunctional properties of bio-poly(butylene succinate) reinforced with multiwalled carbon nanotubes

• Volodymyr Krasinskyi,
• Krzysztof Bajer,
• Ludmila Dulebova,
• Nickolas Polychronopoulos,
• Oksana Krasinska and
• Daniel Kaczor

Beilstein J. Nanotechnol. 2025, 16, 1014–1024, doi:10.3762/bjnano.16.76

• strength, thermal stability, and biodegradability. However, to broaden its range of applications, certain properties require enhancement, including mechanical performance, thermal and electrical conductivity, biodegradation rate, and barrier properties [1][2][3][4][5]. The limited biodegradability of PBS

• , 2, and 3 wt % of MWCNTs functionalized with carboxyl groups with PBS in a batch mixer resulted in a uniform distribution of agglomerated MWCNTs within the polymer matrix, an increase in the storage modulus, and enhanced electrical conductivity of PBS. Moreover, MWCNTs had a significant effect on the

• into nanosizes and uniformly distributed within the polymer matrix. To investigate the effect of CNTs on the rheological properties of PBS, specifically its flowability, the melt mass-flow rate (MFR) of pure PBS and the PBS/CNT_0.5 nanocomposite was studied at different temperatures and loads (Figure 2

A calix[4]arene-based supramolecular nanoassembly targeting cancer cells and triggering the release of nitric oxide with green light

• Cristina Parisi,
• Loredana Ferreri,
• Tassia J. Martins,
• Francesca Laneri,
• Samantha Sollima,
• Antonina Azzolina,
• Antonella Cusimano,
• Nicola D’Antona,
• Grazia M. L. Consoli and
• Salvatore Sortino

Beilstein J. Nanotechnol. 2025, 16, 1003–1013, doi:10.3762/bjnano.16.75

• , characterized by the presence of a cavity with remarkable hosting properties and synthetic versatility [1][2][3][4][5]. Water soluble calixarenes can be obtained by the introduction of appropriate hydrophilic moieties in the calixarene molecular scaffold, leading to a good biocompatibility and low

• purpose, we report the design and synthesis of the cationic calix[4]arene 1 and its supramolecular nanoassembly with the blue-light-activatable nitroso-derivative NOPD 2 (Scheme 1). We show that (i) 1 self-assembles in water medium into nanoaggregates able to internalize into cancer cells selectively and

• that (ii) the nanoaggregates of 1 are able to effectively encapsulate the water-insoluble NOPD 2 and trigger the NO release with much more biocompatible green light through a photosensitization process, leading to an improvement of more than 100 nm in terms of excitation wavelength. Nanoassemblies of 1

Time-resolved probing of laser-induced nanostructuring processes in liquids

• Maximilian Spellauge,
• David Redka,
• Mianzhen Mo,
• Changyong Song,
• Heinz Paul Huber and
• Anton Plech

Beilstein J. Nanotechnol. 2025, 16, 968–1002, doi:10.3762/bjnano.16.74

• many fields, such as heterogeneous catalysis [2][3], (bio)photonics [4], and coating or device fabrication [5]. In a bottom-up approach the products of the laser-based synthesis are not defined by direct spatial control, but by harnessing the energetic and structural relaxation pathways of fundamental

• and continuously evolving [26][60][61][62][63][64]. X-ray or electron diffraction techniques (Figure 2), implemented via pump–probe schemes and combined with femtosecond ultrashort pulses, have enabled the observation of ultrafast atomic-scale motions [65]. During these transitions, transient and

• first 2 ps after laser excitation, with the corresponding ΔPDF result presented in Figure 5D–F. After laser excitation, ΔPDF clearly shows pair density reductions at radial distances corresponding to O···H hydrogen bond and the first three O···O coordination shells of neutral water. For better

Shape, membrane morphology, and morphodynamic response of metabolically active human mitochondria revealed by scanning ion conductance microscopy

• Eric Lieberwirth,
• Anja Schaeper,
• Regina Lange,
• Ingo Barke,
• Simone Baltrusch and
• Sylvia Speller

Beilstein J. Nanotechnol. 2025, 16, 951–967, doi:10.3762/bjnano.16.73

• Mitochondria are essential organelles in eukaryotic cells, primarily responsible for energy supply. They have an endosymbiotic origin, resulting from the incorporation of an ancestral prokaryote into another prokaryotic host approximately 1.8 billion years ago [1][2][3]. This symbiotic relationship gave rise

• subsequently removed, and the imaging dish was rinsed gently with 2 mL Krebs–Ringer medium before being refilled with 3 mL of fresh medium. For comparison, reference measurements were performed on similarly shaped polystyrene microspheres with diameters of 1 and 3 μm. 100 μL of the microsphere ethanol solution

• each pixel, and upon detecting a preset current drop of 2% relative to the standby current, it retracts to a defined height (hopping height) [27][35]. In our measurements, the standby current was approximately 1 nA by applying a voltage of 0.15–0.40 V between the bath electrode and the nanopipette

Tendency in tip polarity changes in non-contact atomic force microscopy imaging on a fluorite surface

• Bob Kyeyune,
• Philipp Rahe and
• Michael Reichling

Beilstein J. Nanotechnol. 2025, 16, 944–950, doi:10.3762/bjnano.16.72

• insulator materials in real space with unprecedented spatial resolution [2][3][4][5][6]. Besides high-resolution imaging of molecular structures [7], NC-AFM has demonstrated its ability to identify sublattices of atomic surfaces [8][9][10]. In these studies, the knowledge of the tip’s atomic structure plays

• NC-AFM images. Results and Discussion In Figure 2, we present RT data showing two examples of abrupt contrast changes where the polarity of the tip is maintained (polarity-preserving tip changes) but a different atomic contrast appears. The occurrences of tip changes are marked by the two chevron

• ⟨11−2⟩ directions, where a0 is the bulk lattice constant of CaF2. Atomic assignment follows the model introduced in [10], with the solid line in panels (b, c, e, f) representing a polynomial fit of degree seven as a guide to the eye. Examples of polarity-changing tip changes on CaF2(111). (a) Δf data

Synthesis of biowaste-derived carbon-dot-mediated silver nanoparticles and the evaluation of electrochemical properties for supercapacitor electrodes

• Navya Kumari Tenkayala,
• Chandan Kumar Maity,
• Md Moniruzzaman and
• Subramani Devaraju

Beilstein J. Nanotechnol. 2025, 16, 933–943, doi:10.3762/bjnano.16.71

• energy demand. Therefore, a notable research focus has been given to advancements in renewable energy storage systems. Secondary batteries and supercapacitors are promising alternatives for energy storage applications [1][2]. Through the electrostatic polarization of electrolyte solutions, supercapacitor

• color changing from brown to dark brownish black confirmed the synthesis of PG-CDs-AgNP within 2 h. After 2 h of reaction, the sample was collected for UV–vis studies. The UV–vis spectra were also implemented at 12 and 24 h, respectively. The growth and the formation of PG-CDs-AgNP were recorded by

• absorption bands of PG-CDs-AgNPs was acquired at various time intervals to study the production and growth of nanoparticles over time. The gradual growth of PG-CDs-AgNPs has been checked and depicted in Figure 1b. The SPR peak was noticed within 2 h of reaction with PG-CDs, with a visible change in color of

Structural and magnetic properties of microwave-synthesized reduced graphene oxide/VO₂/Fe₂O₃ nanocomposite

• Sumanta Sahoo,
• Ankur Sood and
• Sung Soo Han

Beilstein J. Nanotechnol. 2025, 16, 921–932, doi:10.3762/bjnano.16.70

• . Keywords: Fe2O3; magnetism; microwave irradiation; reduced graphene oxide; VO2; Introduction Graphene-based materials have been significantly explored in various fields of materials science due to their unique physical and chemical characteristics [1][2][3][4]. The special arrangement of carbon materials

• be ascribed to significant exfoliation of the graphite oxide to form the rGO. Figure 2 schematically summarizes the effects of MW irradiation on the mixed powder of graphite oxide and metal oxide precursors. The short-life MW irradiation was also successful in converting V2O5 to VO2. This type of

• element (derived from rGO). The data thus obtained was in coherence with the reported results from XRD and EDX analysis. Additionally, the high-resolution XPS spectrum of V 2p designates two major peaks at 516.5 and 523.3 eV, which can be ascribed to the V 2p3/2 and V 2p1/2, respectively (Figure 7b) [40

Focused ion beam-induced platinum deposition with a low-temperature cesium ion source

• Thomas Henning Loeber,
• Bert Laegel,
• Meltem Sezen,
• Feray Bakan Misirlioglu,
• Edgar J. D. Vredenbregt and
• Yang Li

Beilstein J. Nanotechnol. 2025, 16, 910–920, doi:10.3762/bjnano.16.69

• magnetic or superconductive structures can be created [1][2][3][4]. Also, specific mechanical structures on atomic force microscopy (AFM) cantilevers can be made [5][6]. In the literature, four mechanisms are used to explain the complex process of focused ion beam-induced deposition (FIBID) [5][7]; the

• time, and refresh time, precursor material and substrate have an influence on the effective deposition rate. Gallium (Ga+) and helium (He+) are the most often utilized ion species for FIBID [1][2][5]. Besides these standard FIB systems, new kinds of laser-cooled ion sources have been developed in the

• , ion currents from 16 to 285 pA were used, so the current densities were between 0.9 and 14.2 pA·μm−2. The overall deposition time was kept constant at 2:30 min, and the ion dose was changed from 128 to 2138 pC·μm−2. The ions were accelerated with voltages of 2, 5, 8, and 16 kV, while the measured ion

Characterization of ion track-etched conical nanopores in thermal and PECVD SiO₂ using small angle X-ray scattering

• Shankar Dutt,
• Rudradeep Chakraborty,
• Christian Notthoff,
• Pablo Mota-Santiago,
• Christina Trautmann and
• Patrick Kluth

Beilstein J. Nanotechnol. 2025, 16, 899–909, doi:10.3762/bjnano.16.68

• differences between the nanopores in thermal and PECVD SiO2. The track-to-bulk etching rate ratio is significantly different for the two materials, producing nanopores with cone angles that differ by almost a factor of two. Furthermore, thermal SiO2 exhibits an exceptionally narrow size distribution of only 2

• attracted significant attention in the past decade because of their broad applicability in a variety of areas including biosensing, micro/ultrafiltration, desalination, ion and molecular separation, dialysis, battery technologies, blue energy generation, and nanofluidics [1][2][3][4][5][6][7][8][9][10][11

• uncertainties in dimensional measurements and makes it challenging to obtain robust structural information about the nanopores. Figure 2 shows a representative 2D scattering pattern obtained from conical nanopores in thermal SiO2. This image represents the simultaneous measurement of approximately 107 parallel

Heat-induced transformation of nickel-coated polycrystalline diamond film studied in situ by XPS and NEXAFS

• Olga V. Sedelnikova,
• Yuliya V. Fedoseeva,
• Dmitriy V. Gorodetskiy,
• Yuri N. Palyanov,
• Elena V. Shlyakhova,
• Eugene A. Maksimovskiy,
• Anna A. Makarova,
• Lyubov G. Bulusheva and
• Aleksandr V. Okotrub

Beilstein J. Nanotechnol. 2025, 16, 887–898, doi:10.3762/bjnano.16.67

• producing hybrid materials which combine these two forms of carbon [1][2][3]. In particular, such graphene-on-diamond heterostructures have been shown to be attractive for power electronics [4][5], microelectronic devices [6][7], and detectors [7][8]. At room temperature and atmospheric pressure, carbon in

• spectra were measured upon excitation by photons with energies of 830 and 330 eV to probe different surface depths of the samples after annealing (Figure 2). In these cases, the inelastic mean free path for electrons emitted from the C 1s level in diamond is about 1.0 nm (probing depth of 3 nm) for 830 eV

• to sp2-hybridized carbon atoms. The relative area of this sp2-peak is 3% in the spectrum measured at 830 eV, and becomes significantly larger (16%) as the photon excitation energy decreases to 330 eV. The rather small amount of sp2 carbon in the 2 nm thick surface layer indicates that the temperature

Ar⁺ implantation-induced tailoring of RF-sputtered ZnO films: structural, morphological, and optical properties

• Manu Bura,
• Divya Gupta,
• Arun Kumar and
• Sanjeev Aggarwal

Beilstein J. Nanotechnol. 2025, 16, 872–886, doi:10.3762/bjnano.16.66

• Manu Bura Divya Gupta Arun Kumar Sanjeev Aggarwal Department of Physics, Kurukshetra University, Kurukshetra, 136119, India 10.3762/bjnano.16.66 Abstract Radio frequency-sputtered zinc oxide films are implanted with 30 keV Ar+ ions at various fluences ranging from 1 × 1015 to 2 × 1016 ions·cm−2

• promising material for device fabrication in different fields, namely, spintronics, nanoelectronics, and photonics [1][2]. It possesses a wide bandgap of 3.37 eV [3] and has a large exciton binding energy of about 60 meV [4], which assures the stability of ZnO film-based devices such as liquid crystal

• 2.5 × 1015 ions·cm−2. Gupta et al. [14] have investigated the activation of the A1 (LO) mode and the production of a broad band at the lower Raman shift side in ZnO films implanted with 300 keV argon and 1.2 MeV xenon ions with varying fluence from 1 × 1014 to 3 × 1015 ions·cm−2. Gautam et al. [15

Insights into the electronic and atomic structures of cerium oxide-based ultrathin films and nanostructures using high-brilliance light sources

• Paola Luches and
• Federico Boscherini

Beilstein J. Nanotechnol. 2025, 16, 860–871, doi:10.3762/bjnano.16.65

• ; Introduction Transition metal oxides in the form of thin films or nanostructures find extensive use in sustainable energy technologies [1][2]. They serve as active materials or supports for catalysts for various chemical reactions, essential to energy conversion, sensing, and environmental remediation [3][4

• spectrum shows only minor modifications after annealing, while if the Ce3+-related resonant energy is used (125 eV), a marked Ce 4f peak appears around 2 eV binding energy after the annealing. This demonstrates the significantly higher sensitivity to Ce3+ that can be achieved by exploiting resonant

• its sensitivity, the method, when combined with other techniques, has provided quantitative information on the number of electrons transferred per particle to the support (Figure 2), enabling the optimization of the size of the supported active Pt catalyst [27]. This is a crucial factor in minimizing

Synchrotron X-ray photoelectron spectroscopy study of sodium adsorption on vertically arranged MoS₂ layers coated with pyrolytic carbon

• Alexander V. Okotrub,
• Anastasiya D. Fedorenko,
• Anna A. Makarova,
• Veronica S. Sulyaeva,
• Yuliya V. Fedoseeva and
• Lyubov G. Bulusheva

Beilstein J. Nanotechnol. 2025, 16, 847–859, doi:10.3762/bjnano.16.64

• capacity and cycle life of SIBs. Molybdenum disulfide (MoS2) has a layered structure and a high theoretical capacity of 669 mAh·g−1, so it is considered as a promising anode material for SIBs [1][2]. The large sodium ion can diffuse with a low energy barrier between the S−Mo−S layers due to the interlayer

• about 2 and 7 atom % after coating the film with PyC. Figure 4 compares the S/Mo, Na/Mo, and Na/C ratios in the samples determined from the XPS survey spectra measured at excitation photon energies of 470 and 830 eV. The former energy provides a probing depth of about 1 nm and therefore allows for the

• and PyC-MoS2 films is shown in Figure 5. The low-energy peak at 226.1–226.3 eV corresponds to the S 2s line. The Mo 3d spectra of the initial MoS2 and PyC-MoS2 consist of an intense spin–orbit doublet with the binding energy of the Mo 3d5/2 component of 228.9 eV (Figure 5a,b). This energy corresponds

Facile one-step radio frequency magnetron sputtering of Ni/NiO on stainless steel for an efficient electrode for hydrogen evolution reaction

• Ha Huu Do,
• Khac Binh Nguyen,
• Phuong N. Nguyen and
• Hoai Phuong Pham

Beilstein J. Nanotechnol. 2025, 16, 837–846, doi:10.3762/bjnano.16.63

• efficiency. The evaluation of catalytic activities revealed that the optimal sample of Ni/NiO/SS-10 displayed a higher HER performance than bare SS. To produce H2 at a current density of 10 mA·cm−2, this electrode required a low overpotential of 184 mV and demonstrated remarkable durability over 12 h of

• increasing consumption of fossil fuels, causing CO2 emissions and resulting in climate change [1]. Hydropower can be harnessed to provide sustainable energy for future generations because there are no harmful emissions with only water vapor as a byproduct [2][3][4]. Also, hydropower offers better energy

• and O peaks. The chemical state of Ni is further analyzed by the Ni 2p3/2 peaks. As depicted in Figure 5b, the Ni 2p3/2 spectrum can be deconvoluted into four peaks. The peaks at 852.8, 853.7, and 855.8 eV correspond to Ni0, Ni2+, and Ni3+, respectively. Another broad peak at nearly 861 eV is

Synthesis and magnetic transitions of rare-earth-free Fe–Mn–Ni–Si-based compositionally complex alloys at bulk and nanoscale

• Shabbir Tahir,
• Tatiana Smoliarova,
• Carlos Doñate-Buendía,
• Michael Farle,
• Natalia Shkodich and
• Bilal Gökce

Beilstein J. Nanotechnol. 2025, 16, 823–836, doi:10.3762/bjnano.16.62

• field, exhibit an adiabatic temperature change, enabling energy-efficient and environmentally friendly refrigeration [2]. These solid-state cooling systems are being developed as alternatives to conventional gas-based refrigeration and are especially advantageous for applications requiring tailored

• Ni55.2Mn18.6Ga26.2, a giant magnetocaloric response with a ΔS of −20.4 J·kg−1·K−1 at 317 K in a 5 T field can be achieved compared to Ni57.2Mn15.9Ga27.0 where a ΔS of just −2 J·kg−1·K−1 at 310 K was witnessed. Within the myriad of material systems exhibiting magnetic transitions, compositionally complex alloys (CCAs

• transition near 200 K with an isothermal entropy change of −23 J·kg−1·K−1 at 2 T, respectively. Bulk CCAs are explored thanks to the metallurgy approaches that allow for material composition control and alloying. However, it is desirable to achieve controlled methodologies to downsize CCAs to the nanoscale

Supramolecular hydration structure of graphene-based hydrogels: density functional theory, green chemistry and interface application

• Hon Nhien Le,
• Duy Khanh Nguyen,
• Minh Triet Dang,
• Huyen Trinh Nguyen,
• Thi Bang Tam Dao,
• Trung Do Nguyen,
• Chi Nhan Ha Thuc and
• Van Hieu Le

Beilstein J. Nanotechnol. 2025, 16, 806–822, doi:10.3762/bjnano.16.61

• deoxyribonucleic acid (DNA) [1]. Water molecules and their hydrogen bonding network function as lubricants for biomolecular dynamics. Recent scientific works have analyzed the important role of hydration shells on DNA, proteins, and phospholipid membranes [2][3][4]. The first hydration shell (about 3.5 Å) at the

• exothermic heat increased the reactor temperature to above 90 °C). After 2 h of agitation, the reaction was mixed with 150 mL of a 5% H2O2 solution and kept stirring for one day. After washing to neutral pH, the material was dried and ground to produce a GrO powder (moisture ≈20%). Next, the GrO powder was

• synthesis and brush coating experiments. Synthesis of graphene oxide–nanosilica–zinc hydroxide hydrogel The suspension of 0.625 g GrO and 250 mL of water was agitated and then sonicated for 1 h. The suspension was decanted to collect about 250 mL of GO dispersion. An amount of 4.4 g of Zn(CH3COO)2·2H2O was

Morphology and properties of pyrite nanoparticles obtained by pulsed laser ablation in liquid and thin films for photodetection

• Akshana Parameswaran Sreekala,
• Bindu Krishnan,
• Rene Fabian Cienfuegos Pelaes,
• David Avellaneda Avellaneda,
• Josué Amílcar Aguilar-Martínez and
• Sadasivan Shaji

Beilstein J. Nanotechnol. 2025, 16, 785–805, doi:10.3762/bjnano.16.60

• a narrow bandgap (0.95 eV), high light absorption coefficient (≈105 cm−1), excellent properties in photoelectric conversion, and has enormous potential as an efficient photodetector system and in lithium batteries [1][2]. The prevalent forms of FeS2 are cubic-system pyrite and the orthorhombic

• repetition frequency of 100 Hz, and energy of 90 mJ/pulse was used. In each solvent, laser ablation was carried out for 10 minutes with the aid of a focusing lens (focal length of 50 cm) kept at a 25 cm distance from the target. The laser fluence calculated at this point was 0.23 J·cm−2. Images of the pyrite

• parallel to one another and immersed in 12.5 mL FeS2 nanocolloid (FIPA) kept at room temperature during EPD. A potential difference of 400 V (constant voltage, with current of approximately 2 mA) was applied after optimization of EPD conditions. The deposition was carried out for 1 h. The positive

Changes of structural, magnetic and spectroscopic properties of microencapsulated iron sucrose nanoparticles in saline

• Sabina Lewińska,
• Pavlo Aleshkevych,
• Roman Minikayev,
• Anna Bajorek,
• Mateusz Dulski,
• Krystian Prusik,
• Tomasz Wojciechowski and
• Anna Ślawska-Waniewska

Beilstein J. Nanotechnol. 2025, 16, 762–784, doi:10.3762/bjnano.16.59

• that stabilized the entire nanoparticle [2][3][4]. Such a variety of the iron delivery drugs in the pharmaceutical market results from the continuous improvement of their properties, such as absorption of iron in the human body, time of iron release after administration to the patient, and shape and

• separated from each other and not magnetically interacting. There are many others literature examples of studies of chemical and physical properties on iron deficiency drugs and their usage in agents [2][7][8][11][12][13][14][15]. However, in this work the whole attention is focused on the iron deficiency

• core–shell nanoparticle form, where the shell consists of sucrose, while the core is iron(III) oxide mineral. The average diameter of iron sucrose nanoparticles included in Venofer® was estimated as ≈7 nm, whose core diameter is 3 nm [2][7][8][13]. The elemental analysis for a single iron sucrose

Thickness dependent oxidation in CrCl₃: a scanning X-ray photoemission and Kelvin probe microscopies study

• Shafaq Kazim,
• Rahul Parmar,
• Maryam Azizinia,
• Matteo Amati,
• Muhammad Rauf,
• Andrea Di Cicco,
• Seyed Javid Rezvani,
• Dario Mastrippolito,
• Luca Ottaviano,
• Tomasz Klimczuk,
• Luca Gregoratti and
• Roberto Gunnella

Beilstein J. Nanotechnol. 2025, 16, 749–761, doi:10.3762/bjnano.16.58

• of CrCl3 [2], which can be easily exfoliated and exhibits a slower degradation rate compared to CrI3 or CrBr3[3]. To fully exploit the potential of any material, a detailed understanding of its electronic and structural changes arising from intrinsic and extrinsic defects is crucial [4]. Despite this

• [2][11][8][10], focusing on thin layered flakes and the role of the layer thicknesses obtained by spectro- and scanning microscopy with a lateral resolution of a few tens of nanometers. The interaction with the supporting substrate is a crucial factor [3][12] regarding the properties of the flakes

• known that 270 nm SiO2/Si substrates provide the highest optical contrast (O.C.) value for a single layer or few layers of CrCl3 [2][11]. Because of the insulating behavior of 270 nm SiO2 and to avoid surface charging, we utilized Si(001) wafers with a 1 nm layer of SiO2 and ITO films (190 nm) on glass

Serum heat inactivation diminishes ApoE-mediated uptake of D-Lin-MC3-DMA lipid nanoparticles

• Demian van Straten,
• Luuk van de Schepop,
• Rowan Frunt,
• Pieter Vader and
• Raymond M. Schiffelers

Beilstein J. Nanotechnol. 2025, 16, 740–748, doi:10.3762/bjnano.16.57

• proteins, forms on its surface. This so-called protein corona significantly affects the physicochemical properties of the nanoparticle, such as size, charge and stability [2][3][4][5]. In turn, the composition of the protein corona is influenced by the physicochemical properties of the pristine

• MDA-MB-231 (ATCC) were cultured in DMEM medium with 10% FCS (Gibco) and 1% penicillin-streptomycin (PS) (Fisher Scientific). The human dermal microvascular endothelial cell line HMEC-1 (ATCC) was cultured in MCDB-131 medium supplemented with 10% FCS (Gibco), 2 mM l-glutamine (Gibco), 10 ng/mL rhEGF

• molar ratio of 50:38.5:10:1.5 and a final lipid concentration of 10 mM. siRNA was diluted in an acetate buffer (25 mM, pH 4.0) to a final concentration of 3.3 µM for MC3 LNPs and 12.33 µM for C12 LNPs. For fluorescent LNPs, siRNA and siRNA-AF647 were mixed 2:1 v/v. For MC3 LNPs the Nanoassemblr was set