Deoxygenative gem-difluoroolefination of carbonyl compounds with (chlorodifluoromethyl)trimethylsilane and triphenylphosphine

Fei Wang, Lingchun Li, Chuanfa Ni and Jinbo Hu

Beilstein J. Org. Chem. 2014, 10, 344–351. doi:10.3762/bjoc.10.32

Supporting Information

Full experimental details (difluoromethylation of O, S, and N-nucleophiles and gem-difluoroolefination of carbonyl compounds with TMSCF2Cl) and compound characterization data are given.

Supporting Information File 1: Experimental procedures and characterization data.
Format: PDF Size: 609.7 KB Download

References

Article Citation
Download RIS (Reference Manager) Download BIB (BIBTEX)
Cited References
Download RIS (Reference Manager) Download BIB (BIBTEX)
Back To Article

Article is part of the issue

Organo-fluorine chemistry III

David O'Hagan

Latest Articles

Models of necessity

  1. Timothy Clark and
  2. Martin G. Hicks
  • Commentary
  • Published 13 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1649–1661, doi:10.3762/bjoc.16.137

Rearrangement of o-(pivaloylaminomethyl)benzaldehydes: an experimental and computational study

  1. Csilla Hargitai,
  2. Györgyi Koványi-Lax,
  3. Tamás Nagy,
  4. Péter Ábrányi-Balogh,
  5. András Dancsó,
  6. Gábor Tóth,
  7. Judit Halász,
  8. Angéla Pandur,
  9. Gyula Simig and
  10. Balázs Volk
  • Full Research Paper
  • Published 13 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1636–1648, doi:10.3762/bjoc.16.136

Fluorohydration of alkynes via I(I)/I(III) catalysis

  1. Jessica Neufeld,
  2. Constantin G. Daniliuc and
  3. Ryan Gilmour
  • Full Research Paper
  • Published 10 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1627–1635, doi:10.3762/bjoc.16.135

Facile synthesis of 7-alkyl-1,2,3,4-tetrahydro-1,8-naphthyridines as arginine mimetics using a Horner–Wadsworth–Emmons-based approach

  1. Rhys A. Lippa,
  2. John A. Murphy and
  3. Tim N. Barrett
  • Full Research Paper
  • Published 08 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1617–1626, doi:10.3762/bjoc.16.134

Synthesis of new dihydroberberine and tetrahydroberberine analogues and evaluation of their antiproliferative activity on NCI-H1975 cells

  1. Giacomo Mari,
  2. Lucia De Crescentini,
  3. Serena Benedetti,
  4. Francesco Palma,
  5. Stefania Santeusanio and
  6. Fabio Mantellini
  • Full Research Paper
  • Published 06 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1606–1616, doi:10.3762/bjoc.16.133

Antibacterial scalarane from Doriprismatica stellata nudibranchs (Gastropoda, Nudibranchia), egg ribbons, and their dietary sponge Spongia cf. agaricina (Demospongiae, Dictyoceratida)

  1. Cora Hertzer,
  2. Stefan Kehraus,
  3. Nils Böhringer,
  4. Fontje Kaligis,
  5. Robert Bara,
  6. Dirk Erpenbeck,
  7. Gert Wörheide,
  8. Till F. Schäberle,
  9. Heike Wägele and
  10. Gabriele M. König
  • Full Research Paper
  • Published 03 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1596–1605, doi:10.3762/bjoc.16.132

A dynamic combinatorial library for biomimetic recognition of dipeptides in water

  1. Florian Klepel and
  2. Bart Jan Ravoo
  • Full Research Paper
  • Published 02 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1588–1595, doi:10.3762/bjoc.16.131

Azidophosphonium salt-directed chemoselective synthesis of (E)/(Z)-cinnamyl-1H-triazoles and regiospecific access to bromomethylcoumarins from Morita–Baylis–Hillman adducts

  1. Soundararajan Karthikeyan,
  2. Radha Krishnan Shobana,
  3. Kamarajapurathu Raju Subimol,
  4. J. Helen Ratna Monica and
  5. Ayyanoth Karthik Krishna Kumar
  • Full Research Paper
  • Published 01 Jul 2020

Beilstein J. Org. Chem. 2020, 16, 1579–1587, doi:10.3762/bjoc.16.130

NHC-catalyzed enantioselective synthesis of β-trifluoromethyl-β-hydroxyamides

  1. Alyn T. Davies,
  2. Mark D. Greenhalgh,
  3. Alexandra M. Z. Slawin and
  4. Andrew D. Smith
  • Letter
  • Published 30 Jun 2020

Beilstein J. Org. Chem. 2020, 16, 1572–1578, doi:10.3762/bjoc.16.129

Five-component, one-pot synthesis of an electroactive rotaxane comprising a bisferrocene macrocycle

  1. Natalie Lagesse,
  2. Luca Pisciottani,
  3. Maxime Douarre,
  4. Pascale Godard,
  5. Brice Kauffmann,
  6. Vicente Martí-Centelles and
  7. Nathan D. McClenaghan
  • Full Research Paper
  • Published 30 Jun 2020

Beilstein J. Org. Chem. 2020, 16, 1564–1571, doi:10.3762/bjoc.16.128

Latest Articles

Latest Thematic Issues

Advances in photoredox catalysis

Timothy Noël

New Show Issue

C–H functionalization for materials science

Kenichiro Itami

2019 Show Issue

Medicinal chemistry and drug discovery in an opening era

Matthew Todd

2019 Call Show Issue

Copper-catalyzed reactions for organic synthesis

Gwilherm Evano and Olivier Riant

2019 Show Issue

Molecular switches

Wiktor Szymanski and Stefan Hecht

2019 Show Issue

Terpenes

Jeroen S. Dickschat

2019 Show Issue

Dyes in modern organic chemistry

Heiko Ihmels

2019 Show Issue

Reactive intermediates – carbocations

Dean J. Tantillo and Stephanie R. Hare

2018 Show Issue

Novel macrocycles – and old ones doing new tricks

Wei Jiang and Christoph A. Schalley

2018 Show Issue
Browse all Thematic Issues

Keep Informed

RSS Feed

Subscribe to our Latest Articles RSS Feed.

Subscribe

Follow the Beilstein-Institut

LinkedIn

Twitter: @BeilsteinInst