Cross-dehydrogenative coupling for the intermolecular C–O bond formation

Igor B. Krylov, Vera A. Vil’ and Alexander O. Terent’ev
Beilstein J. Org. Chem. 2015, 11, 92–146. https://doi.org/10.3762/bjoc.11.13

Cite the Following Article

Cross-dehydrogenative coupling for the intermolecular C–O bond formation
Igor B. Krylov, Vera A. Vil’ and Alexander O. Terent’ev
Beilstein J. Org. Chem. 2015, 11, 92–146. https://doi.org/10.3762/bjoc.11.13

How to Cite

Krylov, I. B.; Vil’, V. A.; Terent’ev, A. O. Beilstein J. Org. Chem. 2015, 11, 92–146. doi:10.3762/bjoc.11.13

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Maruya, C.; Yagi, K.; Torigoe, T.; Ohmura, T. Iridium-Catalyzed Intramolecular C(sp3)–H/O–H Coupling: A Route to Benzofuran Derivatives Directly from 2-Alkylphenols through Dehydrogenative C–O Bond Formation between Alkyl and Hydroxy Groups. ACS Catalysis 2025, 18255–18260. doi:10.1021/acscatal.5c06870
  • Li, L.-B.; Ou, Z.-X.; Zhang, B.-H.; Yang, M.-X.; Zhang, J.-Q.; Wang, X.-W. Aminoquinoline-Directed Electrochemical Cobalt-Catalyzed C(sp²)-H Alkoxylation. The Journal of organic chemistry 2025, 90, 14118–14131. doi:10.1021/acs.joc.5c01585
  • Krishna T P, A.; Sakthivel, P.; Kota, L.; Kalainilavan, K.; Asokan, K.; Ilangovan, A. Metal-Free C-H Heterofunctionalization of Naphthoquinone via Unprecedented C-N Bond Formation and Cleavage Using Imidazole. The Journal of organic chemistry 2025, 90, 8013–8026. doi:10.1021/acs.joc.4c03162
  • Varala, R.; Achari, K. M. M.; Alam, M. M.; Ramanaiah, S. Di-tert-butyl peroxide-mediated carbon–heteroatom bond formation reactions. Chemistry of Heterocyclic Compounds 2025, 61, 1–39. doi:10.1007/s10593-025-03392-w
  • Zhang, C.-L.; Su, D.; Wang, H.; Muschin, T.; Wu, Y.; Bao, Y.-S.; Zhu, H.-Y. Immobilized Copper Complexes on Coal-Bearing Kaolin for Catalyzing Allylic Ester Synthesis via C(sp3)-H Bond Activation. Molecules (Basel, Switzerland) 2025, 30, 2232. doi:10.3390/molecules30102232
  • Jat, B.; Yadav, D. K.; Badsara, S. S.; Sharma, S. Recent advances in electrochemical utilization of NHPI esters. Organic & biomolecular chemistry 2025, 23, 4846–4854. doi:10.1039/d5ob00467e
  • Adelibieke, Q.; Yusan, B.; Wang, X.; Huang, S.; Wusiman, A. Photocatalytic Oxidative C(sp3)-H/N-H Cross-Dehydrogenative Coupling of Tertiary Anilines with Amides/Imides: Synthesis of N-Mannich Bases. The Journal of organic chemistry 2025, 90, 6123–6133. doi:10.1021/acs.joc.4c03164
  • Kumar, V.; Sudharsan, S.; Mantry, L.; Maayuri, R.; Das, M.; Gandeepan, P. Transition Metal-Catalyzed Direct Functionalization of Carbazoles. Chemical record (New York, N.Y.) 2025, 25, e202500042. doi:10.1002/tcr.202500042
  • Aaron, M. B.; Devi, P. S.; Anilkumar, G. Recent Advances in the Catalytic Synthesis of α-Ketoamides. Chemical record (New York, N.Y.) 2025, 25, e202500008. doi:10.1002/tcr.202500008
  • Bania, K. K.; Biswas, S.; Devi, A.; Bora, T. J. Heterogeneous Catalysts for C–C Bond Formation Reactions. Synlett 2025, 36, 2128–2154. doi:10.1055/s-0043-1775449
  • Li, J.; Zhou, Z.; Zeng, X.; Wei, Y. Modular synthesis of β-oxygen-containing sulfones from alkenes through hexatungstate-catalyzed cascade hydroxysulfenylation/selective oxidation. Organic Chemistry Frontiers 2025, 12, 1444–1451. doi:10.1039/d4qo02151g
  • Londhe, G.; Bokade, V.; Gnanaprakasam, B. Continuous Flow β‐Zeolite Catalysed Regioselective Alkylation of Naphthols Using Alcohols for Synthesis of Peroxynaphthalen‐2(1H)‐one, Azidonaphthalen‐2(1H)‐one and Fluoronaphthalen‐2(1H)‐one Derivatives. Asian Journal of Organic Chemistry 2025, 14. doi:10.1002/ajoc.202400658
  • Singh, S.; Mahala, S.; Bhuvanesh, N.; Joshi, H. Pd(ii) NCSe–pincer complexes for regioselective cross-dehydrogenative coupling of arylthiophenes with hetero(arenes). Catalysis Science & Technology 2025, 15, 523–536. doi:10.1039/d4cy01198h
  • Patel, D. P.; Patel, V. K.; Singh, S. K. Visible light-induced cross-dehydrogenative coupling of N-heterocyclic compounds: green and efficient synthetic strategies. Organic Chemistry Frontiers 2025. doi:10.1039/d5qo01346a
  • Budnikov, A. S.; Shevchenko, M. I.; Krylov, I. B.; Pechen, D. Y.; Alekseenko, A. L.; Ilovaisky, A. I.; Terent'ev, A. O. Cross-dehydrogenative C–O coupling of oximes with hydrazones: synthesis of fungicidal azo-oxime ethers. Organic Chemistry Frontiers 2025. doi:10.1039/d5qo01151e
  • Maayuri, R.; Gandeepan, P. Ruthenium-catalyzed electrochemical C–H activation for organic synthesis. Electrochemistry; Royal Society of Chemistry, 2024; pp 219–244. doi:10.1039/9781837676408-00219
  • Budnikov, A. S.; Krylov, I. B.; Shevchenko, M. I.; Sokova, L. L.; Liu, Y.; Yu, B.; Terent'ev, A. O. Synthesis of ω-functionalized ketones from strained cyclic alcohols by ring-opening and cross-recombination between alkyl and N-oxyl radicals. Organic & biomolecular chemistry 2024, 22, 8755–8763. doi:10.1039/d4ob01490a
  • Xu, C.; Luo, Y.; Niu, S.; Gong, F.; Lan, S.; Luo, B.; Liu, J.; Yang, S.; Fang, X. Transition-metal and base-free ether synthesis via alcohol-participated yne-allylic substitution. Green Synthesis and Catalysis 2024, 5, 303–309. doi:10.1016/j.gresc.2023.10.003
  • Varala, R.; Seema, V.; Hussein, M.; Alam, M. M.; Beda, D. P. tert ‐Butyl Hydroperoxide (TBHP): Recent Progress in C−H Functionalization and Heteroatom‐Heteroatom Bond Formations. ChemistrySelect 2024, 9. doi:10.1002/slct.202401937
  • Bakthadoss, M.; Aina, O. S.; Reddy, T. T.; Izunobi, J. U.; Familoni, O. B. Mono and di ortho-C-H acetoxylation of 2-aryloxyquinoline-3-carbaldehydes. RSC advances 2024, 14, 13306–13310. doi:10.1039/d4ra01289e
Other Beilstein-Institut Open Science Activities