Silica-supported sulfonic acids as recyclable catalyst for esterification of levulinic acid with stoichiometric amounts of alcohols

Raimondo Maggi, N. Raveendran Shiju, Veronica Santacroce, Giovanni Maestri, Franca Bigi and Gadi Rothenberg
Beilstein J. Org. Chem. 2016, 12, 2173–2180.

Supporting Information

Supporting Information File 1: Experimental part and NMR spectra of products.
Format: PDF Size: 637.4 KB Download

Cite the Following Article

Silica-supported sulfonic acids as recyclable catalyst for esterification of levulinic acid with stoichiometric amounts of alcohols
Raimondo Maggi, N. Raveendran Shiju, Veronica Santacroce, Giovanni Maestri, Franca Bigi and Gadi Rothenberg
Beilstein J. Org. Chem. 2016, 12, 2173–2180.

How to Cite

Maggi, R.; Shiju, N. R.; Santacroce, V.; Maestri, G.; Bigi, F.; Rothenberg, G. Beilstein J. Org. Chem. 2016, 12, 2173–2180. doi:10.3762/bjoc.12.207

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Presentation Graphic

Picture with graphical abstract, title and authors for social media postings and presentations.
Format: PNG Size: 147.8 KB Download

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Renuka, M.; Kalla, R. M. N. Phospho Sulfonic Acid as a Solid Acid Catalyst for Esterification of Long-Chain Fatty Acids. Russian Journal of Organic Chemistry 2023, 59, 733–737. doi:10.1134/s1070428023040243
  • Tian, Y.; Zhu, X.; Zhou, S.; Zhao, W.; Xu, Q.; Liu, X. Efficient synthesis of alkyl levulinates fuel additives using sulfonic acid functionalized polystyrene coated coal fly ash catalyst. Journal of Bioresources and Bioproducts 2023, 8, 198–213. doi:10.1016/j.jobab.2023.01.003
  • Martín, C. D. M. G.; García, J. I. H.; Bonardd, S.; Díaz, D. D. Lignin-Based Catalysts for C-C Bond-Forming Reactions. Molecules (Basel, Switzerland) 2023, 28, 3513. doi:10.3390/molecules28083513
  • Lodhi, A.; Maheria, K. C. Solid acid catalysed synthesis of biologically potent quinazolinones: Environmentally benign approaches. Sustainable Chemistry and Pharmacy 2023, 36, 101265. doi:10.1016/j.scp.2023.101265
  • Pancrazzi, F.; Castronuovo, G.; Maestri, G.; Constantin, A. M.; Voronov, A.; Maggi, R.; Mazzeo, P. P.; Motti, E.; Cauzzi, D. A.; Viscardi, R.; Della Ca', N. Perfluorinated Sulfonate Resins as Reusable Heterogeneous Catalysts for the One‐Pot Synthesis of DiPhenolic Esters (DPEs). European Journal of Organic Chemistry 2022, 2022. doi:10.1002/ejoc.202201315
  • da Silva, E. P. S.; Meneghetti, S. M. P. Investigation of solvent-free esterification of levulinic acid in the presence of tin(IV) complexes. Molecular Catalysis 2022, 528, 112499. doi:10.1016/j.mcat.2022.112499
  • Kumar K. Pavithran, V.; Rao, V. S.; Jaganmohan, C.; Mohanty, S.; Kumar, J.; Rao Battula, V.; Kalyani, K.; Kallam, S. R. An Efficient Synthesis of 3,4-dihydro-2(1H)-pyrimidinones from Aldehyde Bisulfite Adducts using Recyclable Wang Resin Supported Sulfonic Acid Catalyst. Letters in Organic Chemistry 2022, 19, 463–470. doi:10.2174/1570178618666210225113723
  • Sajid, M.; Farooq, U.; Bary, G.; Azim, M. M.; Zhao, X. Sustainable production of levulinic acid and its derivatives for fuel additives and chemicals: progress, challenges, and prospects. Green Chemistry 2021, 23, 9198–9238. doi:10.1039/d1gc02919c
  • Jaiswal, K. S.; Rathod, V. K. Green synthesis of amyl levulinate using lipase in the solvent free system: Optimization, Mechanism and Thermodynamics studies. Catalysis Today 2021, 375, 120–131. doi:10.1016/j.cattod.2020.06.059
  • Maheria, K. C.; Lodhi, A.; Lankapati, H. M.; Krishna, R. Solid Acid-Catalyzed Esterification of Levulinic Acid for Production of Value-Added Chemicals. Catalysis for Clean Energy and Environmental Sustainability; Springer International Publishing, 2021; pp 345–382. doi:10.1007/978-3-030-65017-9_12
  • Peixoto, A. F.; Soliman, M. M. A.; Pinto, T. V.; Silva, S. M.; de Carvalho Pinto Costa, P. M.; Alegria, E. C. B. A.; Freire, C. Highly active organosulfonic aryl-silica nanoparticles as efficient catalysts for biomass derived biodiesel and fuel additives. Biomass and Bioenergy 2021, 145, 105936. doi:10.1016/j.biombioe.2020.105936
  • Lai, B.; Ye, M.; Liu, P.; Li, M.; Bai, R.; Gu, Y. A novel and robust heterogeneous Cu catalyst using modified lignosulfonate as support for the synthesis of nitrogen-containing heterocycles. Beilstein journal of organic chemistry 2020, 16, 2888–2902. doi:10.3762/bjoc.16.238
  • Khajone, V. B.; Bhagat, P. R. Brønsted acid functionalized phthalocyanine on perylene diimide framework knotted with ionic liquid: An efficient photo-catalyst for production of biofuel component octyl levulinate at ambient conditions under visible light irradiation. Fuel 2020, 279, 118390. doi:10.1016/j.fuel.2020.118390
  • Xiaofang, L.; Yang, W.; Zhang, Q.; Li, C.; Wu, H. Current Approaches to Alkyl Levulinates via Efficient Valorization of Biomass Derivatives. Frontiers in chemistry 2020, 8, 794. doi:10.3389/fchem.2020.00794
  • Viscardi, R.; Barbarossa, V.; Gattia, D. M.; Maggi, R.; Maestri, G.; Pancrazzi, F. Effect of surface acidity on the catalytic activity and deactivation of supported sulfonic acids during dehydration of methanol to DME. New Journal of Chemistry 2020, 44, 16810–16820. doi:10.1039/d0nj00229a
  • Niknam, K.; Hashemi, H.; Karimzadeh, M.; Saberi, D. Recent advances in preparation and application of sulfonic acid derivatives bonded to inorganic supports. Journal of the Iranian Chemical Society 2020, 17, 3095–3178. doi:10.1007/s13738-020-01997-w
  • Barbarossa, V.; Viscardi, R.; Di Nardo, A.; Santagata, A. Kinetic parameter estimation for methanol dehydration to dimethyl ether over sulfonic and polymeric acid catalysts. Journal of Chemical Technology & Biotechnology 2020, 95, 1739–1747. doi:10.1002/jctb.6372
  • Badgujar, K. C.; Badgujar, V. C.; Bhanage, B. M. A review on catalytic synthesis of energy rich fuel additive levulinate compounds from biomass derived levulinic acid. Fuel Processing Technology 2020, 197, 106213. doi:10.1016/j.fuproc.2019.106213
  • Wang, Y.; You, J.; Liu, B. Preparation of mesoporous silica supported sulfonic acid and evaluation of the catalyst in esterification reactions. Reaction Kinetics, Mechanisms and Catalysis 2019, 128, 493–505. doi:10.1007/s11144-019-01645-2
  • Trombettoni, V.; Campana, F.; Marrocchi, A.; Vaccaro, L. CHAPTER 5:Sustainable Batch or Continuous-flow Preparation of Biomass-derived Fuels Using Sulfonated Organic Polymers. Green Synthetic Processes and Procedures; The Royal Society of Chemistry, 2019; pp 79–114. doi:10.1039/9781788016131-00079
Other Beilstein-Institut Open Science Activities