Rhodium-catalyzed C–H functionalization of heteroarenes using indoleBX hypervalent iodine reagents

Scholarly Works

• Mohanty, S. R.; Prusty, N.; Nanda, T.; Mahulkar, P. S.; Ravikumar, P. C. Directing group-assisted selective C–H activation of six-membered N-heterocycles and benzo-fused N-heterocycles. Organic Chemistry Frontiers 2024, 11, 540–575. doi:10.1039/d3qo01396k
• Zheng, D.; Zheng, J.; Wang, Q.; Gu, Q.; You, S. Rhodium(III)‐Catalyzed Atroposelective C—H Indolylization of 1‐Aryl Isoquinolines with 3‐Indolylphenyliodonium Salts†. Chinese Journal of Chemistry 2023, 41, 2684–2690. doi:10.1002/cjoc.202300289
• Chi, R.; Wu, J.-X.; Li, D.-C.; Dou, J.-M.; Wang, H.-W. RhIII-promoted directed C-H N-heteroarylation of 2-pyridones. Organic & biomolecular chemistry 2023, 21, 5288–5296. doi:10.1039/d3ob00578j
• Pal, P.; Das, G. K. Mechanistic insight highlights the key steps and significance of metal in Ir(III)-catalysed C-H activated chromones generation. Organic & biomolecular chemistry 2022, 20, 9703–9721. doi:10.1039/d2ob01785g
• Sihag, M.; Soni, R.; Rani, N.; Kinger, M.; Kumar Aneja, D. Recent Synthetic Applications of Hypervalent Iodine Reagents. A Review in Three Installments: Installment II. Organic Preparations and Procedures International 2022, 55, 99–159. doi:10.1080/00304948.2022.2114236
• Yamamoto, Y. doi:10.1002/9783527834242.chf0106
• Shan, Y.; Huang, G.; Yu, J.; Pan, C. Rh(III)‐Catalyzed C6‐Selective C−H 3‐Oxoalkylation of 2‐Pyridones with Allylic Alcohols. Asian Journal of Organic Chemistry 2022, 11. doi:10.1002/ajoc.202200097
• Rani, N.; Soni, R.; Sihag, M.; Kinger, M.; Aneja, D. K. Combined Approach of Hypervalent Iodine Reagents and Transition Metals in Organic Reactions. Advanced Synthesis & Catalysis 2022, 364, 1798–1848. doi:10.1002/adsc.202200088
• Raziullah; Kumar, M.; Ahmad, A.; Dutta, H. S.; Rastogi, A.; Gangwar, M. K.; Koley, D. Ru-Catalyzed C-H alkenylation on the arene ring of pirfenidone using pyridone as a directing group. Chemical communications (Cambridge, England) 2022, 58, 3481–3484. doi:10.1039/d2cc00257d
• Pal, P.; Das, G. K. Mechanistic insights into Rh(III)-catalyzed C H activation/annulation of N-Aryloxyacetamides with alkynyloxiranes. Molecular Catalysis 2021, 516, 111971. doi:10.1016/j.mcat.2021.111971
• Pal, P.; Mondal, S.; Chatterjee, A.; Saha, R.; Chakrabarty, K.; Das, G. Mechanistic exploration of Rh(III)-catalyzed C-H allylation of benzamides with allyl bromide. Journal of Organometallic Chemistry 2021, 949, 121888. doi:10.1016/j.jorganchem.2021.121888
• Huang, G.; Shan, Y.; Yu, J.-T.; Pan, C. RhIII-Catalyzed C6-Selective Oxidative C−H/C−H Crosscoupling of 2-Pyridones with Thiophenes. Chemistry (Weinheim an der Bergstrasse, Germany) 2021, 27, 12294–12299. doi:10.1002/chem.202101769
• Le Du, E.; Duhail, T.; Wodrich, M. D.; Scopelliti, R.; Fadaei-Tirani, F.; Anselmi, E.; Magnier, E.; Waser, J. Structure and Reactivity of N-Heterocyclic Alkynyl Hypervalent Iodine Reagents. Chemistry (Weinheim an der Bergstrasse, Germany) 2021, 27, 10979–10986. doi:10.1002/chem.202101475
• Waser, J.; Nandi, R. K.; Pal, P. Umpolung of Electron-Rich Heteroarenes with Hypervalent Iodine Reagents. HETEROCYCLES 2021, 103, 555. doi:10.3987/com-20-s(k)33
• Karmakar, U.; Samanta, R. A directing group free Pd(II)-catalysed desulfitative C6-arylation of 2-pyridone using an arylsulfonyl chloride. Organic & biomolecular chemistry 2020, 18, 8079–8083. doi:10.1039/d0ob01716g
• Biswas, A.; Maity, S.; Pan, S.; Samanta, R. Transition Metal-Catalysed Direct C-H Bond Functionalizations of 2-Pyridone Beyond C3-Selectivity. Chemistry, an Asian journal 2020, 15, 2092–2109. doi:10.1002/asia.202000506
• Chai, J.; Ding, W.; Wu, J.; Yoshikai, N. Fluorobenziodoxole-BF3 Reagent for Iodo(III)etherification of Alkynes in Ethereal Solvent. Chemistry, an Asian journal 2020, 15, 2166–2169. doi:10.1002/asia.202000653
• Ding, W.; Wang, C.; Tan, J. R.; Ho, C. C.; León, F.; García, F.; Yoshikai, N. Site-selective aromatic C-H λ3-iodanation with a cyclic iodine(iii) electrophile in solution and solid phases. Chemical science 2020, 11, 7356–7361. doi:10.1039/d0sc02737e
• Kumar, S. V.; Banerjee, S.; Punniyamurthy, T. Transition metal-catalyzed coupling of heterocyclic alkenes via C–H functionalization: recent trends and applications. Organic Chemistry Frontiers 2020, 7, 1527–1569. doi:10.1039/d0qo00279h
• Cerveri, A.; Bandini, M. Recent advances in the catalytic functionalization of “electrophilic” indoles. Chinese Journal of Chemistry 2020, 38, 287–294. doi:10.1002/cjoc.201900446

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