Preparation and X-ray structure of 2-iodoxybenzenesulfonic acid (IBS) – a powerful hypervalent iodine(V) oxidant

Scholarly Works

• Yang, Z.; Sun, F.; Xu, J.; Li, Y.; Yang, K.; Du, Y. Preparation, Structural Identification and Reactivities of Two Benziodazole‐type I(III) Reagents. Advanced Synthesis & Catalysis 2023, 365, 2730–2736. doi:10.1002/adsc.202300304
• Cheng, Y.; Li, G.; Jiang, L.; Dong, Y.; Zhan, X.; Sun, F.; Du, Y. Construction of C-S and C-Se Bonds Mediated by Hypervalent Iodine Reagents Under Metal-Free Conditions. Current Organic Chemistry 2022, 26, 1935–1953. doi:10.2174/1385272826666220620153347
• Sihag, M.; Soni, R.; Rani, N.; Kinger, M.; Kumar Aneja, D. Recent Synthetic Applications of Hypervalent Iodine Reagents. A Review in Three Installments: Installment I. Organic Preparations and Procedures International 2022, 55, 1–62. doi:10.1080/00304948.2022.2113964
• Ishihara, K. doi:10.1002/9783527829569.ch2
• Ballaschk, F.; Kirsch, S. F. doi:10.1002/9783527829569.ch11
• Folkman, S. J.; Finke, R. G.; Galán-Mascarós, J. R.; Miyake, G. M. Carbon-Electrode-Mediated Electrochemical Synthesis of Hypervalent Iodine Reagents Using Water as the O-Atom Source. ACS Sustainable Chemistry & Engineering 2021, 9, 10453–10467. doi:10.1021/acssuschemeng.1c01315
• Vlasenko, Y. А.; Yusubov, M. S.; Shafir, A.; Postnikov, P. S. Hypervalent iodine in the structure of N-heterocycles: synthesis, structure, and application in organic synthesis. Chemistry of Heterocyclic Compounds 2020, 56, 854–866. doi:10.1007/s10593-020-02742-0
• Soldatova, N. S.; Postnikov, P. S.; Suslonov, V. V.; Kissler, T. Y.; Ivanov, D. M.; Yusubov, M. S.; Galmés, B.; Frontera, A.; Kukushkin, V. Y. Diaryliodonium as a double σ-hole donor: the dichotomy of thiocyanate halogen bonding provides divergent solid state arylation by diaryliodonium cations. Organic Chemistry Frontiers 2020, 7, 2230–2242. doi:10.1039/d0qo00678e
• Li, X.; Liu, T.; Zhang, B.; Zhang, D.; Shi, H.; Yu, Z.; Tao, S.; Du, Y. Formation of Carbon-Carbon Bonds Mediated by Hypervalent Iodine Reagents Under Metal-free Conditions. Current Organic Chemistry 2020, 24, 74–103.
• Li, X.; Liu, T.; Zhang, B.; Zhang, D.; Shi, H.; Yu, Z.; Tao, S.; Du, Y. Formation of Carbon-Carbon Bonds Mediated by Hypervalent Iodine Reagents Under Metal-free Conditions. Current Organic Chemistry 2020, 24, 74–103. doi:10.2174/1385272824666200211093103
• Zhang, G.; Wang, Y.; Xu, J.; Sun, J.; Sun, F.; Zhang, Y.; Zhang, C.; Du, Y. A new hypervalent iodine(III/V) oxidant and its application to the synthesis of 2H-azirines. Chemical science 2019, 11, 947–953. doi:10.1039/c9sc05536c
• Dallaston, M. A.; Bettencourt, C. J.; Chow, S.; Gebhardt, J.; Spangler, J.; Johnston, M. R.; Wall, C.; Brusnahan, J. S.; Williams, C. M. Ranking Oxidant Sensitiveness: A Guide for Synthetic Utility. Chemistry (Weinheim an der Bergstrasse, Germany) 2019, 25, 9614–9618. doi:10.1002/chem.201902036
• Yusubov, M. S.; Soldatova, N. S.; Postnikov, P. S.; Valiev, R. R.; Yoshimura, A.; Wirth, T.; Nemykin, V. N.; Zhdankin, V. V. 2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(V) oxidant. Chemical communications (Cambridge, England) 2019, 55, 7760–7763. doi:10.1039/c9cc04203b

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