Hydroarylations by cobalt-catalyzed C–H activation

Rajagopal Santhoshkumar and Chien-Hong Cheng
Beilstein J. Org. Chem. 2018, 14, 2266–2288. https://doi.org/10.3762/bjoc.14.202

Cite the Following Article

Hydroarylations by cobalt-catalyzed C–H activation
Rajagopal Santhoshkumar and Chien-Hong Cheng
Beilstein J. Org. Chem. 2018, 14, 2266–2288. https://doi.org/10.3762/bjoc.14.202

How to Cite

Santhoshkumar, R.; Cheng, C.-H. Beilstein J. Org. Chem. 2018, 14, 2266–2288. doi:10.3762/bjoc.14.202

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Presentation Graphic

Picture with graphical abstract, title and authors for social media postings and presentations.
Format: PNG Size: 482.1 KB Download

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Kumari, S.; Thakur, M.; Kumari, M. Progress in Cobalt Complexes for Enabling Asymmetric Hydrogenation, H2 Production Catalysis and Alkene/Alkyne Hydro‐functionalization: A Review. ChemistrySelect 2024, 9. doi:10.1002/slct.202303916
  • Deng, S.-M.; Zhao, Y.-X.; Wang, C. When transition-metal-catalyzed C–H activation meets allene chemistry. Tetrahedron Chem 2023, 8, 100049. doi:10.1016/j.tchem.2023.100049
  • Kumar Banjare, S.; Afreen, S.; Shridhar Mahulkar, P.; Saxena, A.; Ravikumar, P. C. Uncovering the Reactivity of Cobalt‐Catalyst Towards Regioselective Hydroarylation of 1,6‐Diyne via Weak‐Chelation Assisted C−H Bond Activation. Advanced Synthesis & Catalysis 2023, 365, 1977–1982. doi:10.1002/adsc.202300515
  • Bora, J.; Dutta, M.; Chetia, B. Cobalt catalyzed alkenylation/annulation reactions of alkynes via C–H activation: A review. Tetrahedron 2023, 132, 133248. doi:10.1016/j.tet.2023.133248
  • Arribas, A.; Lázaro-Milla, C.; Mascareñas, J. L.; López, F. Catalytic Addition of C–H Bonds Across C–C π-Bonds. Reference Module in Chemistry, Molecular Sciences and Chemical Engineering; Elsevier, 2023. doi:10.1016/b978-0-323-96025-0.00019-3
  • Whitehurst, W. G.; Kim, J.; Koenig, S. G.; Chirik, P. J. C-H Activation by Isolable Cationic Bis(phosphine) Cobalt(III) Metallacycles. Journal of the American Chemical Society 2022, 144, 19186–19195. doi:10.1021/jacs.2c08865
  • Wang, Q.; Yan, Z.; Xing, D. Nickel(0)-catalysed linear-selective hydroarylation of 2-aminostyrenes with arylboronic acids by a bifunctional temporary directing group strategy. Organic Chemistry Frontiers 2022, 9, 3840–3846. doi:10.1039/d2qo00546h
  • Patel, M.; Ajay, U.; Padala, K.; Naveen, T. Recent Advances in Cobalt‐catalyzed Functionalization of Unactivated Olefins. Asian Journal of Organic Chemistry 2022, 11. doi:10.1002/ajoc.202200201
  • Qi, S.-L.; Liu, Y.-P.; Li, Y.; Luan, Y.-X.; Ye, M. Ni-catalyzed hydroarylation of alkynes with unactivated β-C(sp2)-H bonds. Nature communications 2022, 13, 2938. doi:10.1038/s41467-022-30367-8
  • Whitehurst, W. G.; Kim, J.; Koenig, S. G.; Chirik, P. J. Three-Component Coupling of Arenes, Ethylene, and Alkynes Catalyzed by a Cationic Bis(phosphine) Cobalt Complex: Intercepting Metallacyclopentenes for C-H Functionalization. Journal of the American Chemical Society 2022, 144, 4530–4540. doi:10.1021/jacs.1c12646
  • Wang, L.; Wu, X.; Tian, Q.; Li, Y. Co/Cu Co‐Catalyzed Carbonylation of Alkyl Iodides and Thioesters. ChemistrySelect 2022, 7. doi:10.1002/slct.202103503
  • Weaver, G. W. Organic Reaction Mechanisms Series; Wiley, 2021; pp 191–226. doi:10.1002/9781119531975.ch5b
  • Gonzalez-Gomez, J. C.; Alonso, F. Organic Reaction Mechanisms Series; Wiley, 2021; pp 513–551. doi:10.1002/9781119531975.ch13
  • doi:10.1002/9783527346028.ch7
  • Gao, Y.; Zhang, M.; Wang, C.; Yang, Z.; Huang, X.-Q.; Feng, R.; Qi, C. Cobalt(II)-catalyzed hydroarylation of 1,3-diynes and internal alkynes with picolinamides promoted by alcohol. Chemical communications (Cambridge, England) 2020, 56, 14231–14234. doi:10.1039/d0cc05616b
  • Carral-Menoyo, A.; Sotomayor, N.; Lete, E. Cp*Co(III)-Catalyzed C-H Hydroarylation of Alkynes and Alkenes and Beyond: A Versatile Synthetic Tool. ACS omega 2020, 5, 24974–24993. doi:10.1021/acsomega.0c03639
  • Yan, Q.; Huang, H.; Zhang, H.; Li, M.-H.; Yang, D.; Song, M.-P.; Niu, J.-L. Synthesis of 7-Amido Indolines by Cp*Co(III)-Catalyzed C-H Bond Amidation. The Journal of organic chemistry 2020, 85, 11190–11199. doi:10.1021/acs.joc.0c01259
  • Corpas, J.; Mauleón, P.; Arrayás, R. G.; Carretero, J. C. anti-Hydroarylation of Activated Internal Alkynes: Merging Pd and Energy Transfer Catalysis. Organic letters 2020, 22, 6473–6478. doi:10.1021/acs.orglett.0c02281
  • Carral-Menoyo, A.; Sotomayor, N.; Lete, E. Amide-Directed Intramolecular Co(III)-Catalyzed C-H Hydroarylation of Alkenes for the Synthesis of Dihydrobenzofurans with a Quaternary Center. The Journal of organic chemistry 2020, 85, 10261–10270. doi:10.1021/acs.joc.0c01413
  • Whyte, A.; Torelli, A.; Mirabi, B.; Prieto, L.; Rodríguez, J. F.; Lautens, M. Cobalt-Catalyzed Enantioselective Hydroarylation of 1,6-Enynes. Journal of the American Chemical Society 2020, 142, 9510–9517. doi:10.1021/jacs.0c03246
Other Beilstein-Institut Open Science Activities