Cobalt catalysis

  1. editorImage
  1. Editor: Prof. Shigeki Matsunaga
    Hokkaido University

Late transition metal catalysts, such as palladium, rhodium, and iridium, have played key roles in organic synthesis over decades, due to their high catalytic activity and selectivity. More recent studies in this field, however, have experienced a significant paradigm shift towards using non-precious, earth abundant, first-row transition metal catalysts, mainly due to their economic and environmental advantages. To realize high catalytic activity and selectivity using first-row transition metal catalysts, unique design on catalysts, ligands, and/or reacting substrates is often required. In this thematic issue, we would like to shed light on “Cobalt Catalysis” in organic synthesis, because cobalt catalysts not only work as alternatives to precious rhodium catalysts, but often show unique catalytic activities. Recent advances in broad range of cobalt catalysis, such as C–H bond functionalization, cross coupling, asymmetric reactions, biomimetic transformation, polymerization, and others, will be featured.

Additional articles on this topic will be published here soon.

  • Full Research Paper
  • Published 28 Mar 2018

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Beilstein J. Org. Chem. 2018, 14, 709–715, doi:10.3762/bjoc.14.60

Three-component coupling of aryl iodides, allenes, and aldehydes catalyzed by a Co/Cr-hybrid catalyst

  1. Kimihiro Komeyama,
  2. Shunsuke Sakiyama,
  3. Kento Iwashita,
  4. Itaru Osaka and
  5. Ken Takaki
  • Full Research Paper
  • Published 11 Jun 2018

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Beilstein J. Org. Chem. 2018, 14, 1413–1420, doi:10.3762/bjoc.14.118

Thiocarbonyl-enabled ferrocene C–H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical

  1. Santhivardhana Reddy Yetra,
  2. Zhigao Shen,
  3. Hui Wang and
  4. Lutz Ackermann
  • Full Research Paper
  • Published 25 Jun 2018

Beilstein J. Org. Chem. 2018, 14, 1546–1553, doi:10.3762/bjoc.14.131

Cationic cobalt-catalyzed [1,3]-rearrangement of N-alkoxycarbonyloxyanilines

  1. Itaru Nakamura,
  2. Mao Owada,
  3. Takeru Jo and
  4. Masahiro Terada
  • Full Research Paper
  • Published 31 Jul 2018

Beilstein J. Org. Chem. 2018, 14, 1972–1979, doi:10.3762/bjoc.14.172

Cobalt-catalyzed nucleophilic addition of the allylic C(sp3)–H bond of simple alkenes to ketones

  1. Tsuyoshi Mita,
  2. Masashi Uchiyama,
  3. Kenichi Michigami and
  4. Yoshihiro Sato
  • Letter
  • Published 02 Aug 2018

Beilstein J. Org. Chem. 2018, 14, 2012–2017, doi:10.3762/bjoc.14.176

Cobalt-catalyzed peri-selective alkoxylation of 1-naphthylamine derivatives

  1. Jiao-Na Han,
  2. Cong Du,
  3. Xinju Zhu,
  4. Zheng-Long Wang,
  5. Yue Zhu,
  6. Zhao-Yang Chu,
  7. Jun-Long Niu and
  8. Mao-Ping Song
  • Letter
  • Published 09 Aug 2018

Beilstein J. Org. Chem. 2018, 14, 2090–2097, doi:10.3762/bjoc.14.183

  • Full Research Paper
  • Published 28 Aug 2018

Beilstein J. Org. Chem. 2018, 14, 2259–2265, doi:10.3762/bjoc.14.201

Hydroarylations by cobalt-catalyzed C–H activation

  1. Rajagopal Santhoshkumar and
  2. Chien-Hong Cheng
  • Review
  • Published 29 Aug 2018

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Beilstein J. Org. Chem. 2018, 14, 2266–2288, doi:10.3762/bjoc.14.202

  • Full Research Paper
  • Published 10 Sep 2018

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Beilstein J. Org. Chem. 2018, 14, 2366–2374, doi:10.3762/bjoc.14.212

  • Review
  • Published 19 Sep 2018

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Beilstein J. Org. Chem. 2018, 14, 2435–2460, doi:10.3762/bjoc.14.221

  • Review
  • Published 02 Oct 2018

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Beilstein J. Org. Chem. 2018, 14, 2553–2567, doi:10.3762/bjoc.14.232

  • Full Research Paper
  • Published 05 Nov 2018

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Beilstein J. Org. Chem. 2018, 14, 2779–2788, doi:10.3762/bjoc.14.255

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