Unprecedented nucleophile-promoted 1,7-S or Se shift reactions under Pummerer reaction conditions of 4-alkenyl-3-sulfinylmethylpyrroles

Takashi Go, Akane Morimatsu, Hiroaki Wasada, Genzoh Tanabe, Osamu Muraoka, Yoshiharu Sawada and Mitsuhiro Yoshimatsu

Beilstein J. Org. Chem. 2018, 14, 2722–2729. doi:10.3762/bjoc.14.250

Supporting Information

For crystallographic data see also CCDC 1824587 and 1824588.

Supporting Information File 1: Schemes S1 and S2 on the syntheses of compounds 1, 2, and 3a–g; the NMR study for the structure determinations, further DFT calculations, the ORTEP drawing of both sulfone of 5a, 11d and the 1H and 13C NMR charts.
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Supporting Information File 2: Crystallographic information of compound 11d.
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Supporting Information File 3: Crystallographic information of the sulfone of compound 5a.
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Presentation Graphic

Picture with graphical abstract, title and authors for social media postings and presentations.

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