Supporting Information
Full experimental details, 1H and 13C NMR spectra of new compounds, and M062X/6-311+G** computational studies are presented as Supporting Information.
| Supporting Information File 1: Experimental details and 1H and 13C NMR spectra of new compounds. | ||
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| Supporting Information File 2: M062X/6-611+G** calculated structures, energies, and Cartesian coordinates for carbocations and transition states. | ||
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Cite the Following Article
The cyclopropylcarbinyl route to γ-silyl carbocations
Xavier Creary
Beilstein J. Org. Chem. 2019, 15, 1769–1780.
https://doi.org/10.3762/bjoc.15.170
How to Cite
Creary, X. Beilstein J. Org. Chem. 2019, 15, 1769–1780. doi:10.3762/bjoc.15.170
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Scholarly Works
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- Larmore, S. P.; Champagne, P. A. Cyclopropylcarbinyl-to-Homoallyl Carbocation Equilibria Influence the Stereospecificity in the Nucleophilic Substitution of Cyclopropylcarbinols. The Journal of organic chemistry 2023, 88, 6947–6954. doi:10.1021/acs.joc.3c00257
- Moreira, V. M. doi:10.1002/9781119608288.ch6
- Kelly, C. B.; Milligan, J. A.; Tilley, L. J.; Sodano, T. M. Bicyclobutanes: from curiosities to versatile reagents and covalent warheads. Chemical science 2022, 13, 11721–11737. doi:10.1039/d2sc03948f
- Fernandes, A. J.; Panossian, A.; Michelet, B.; Martin-Mingot, A.; Leroux, F. R.; Thibaudeau, S. CF 3 -substituted carbocations: underexploited intermediates with great potential in modern synthetic chemistry. Beilstein journal of organic chemistry 2021, 17, 343–378. doi:10.3762/bjoc.17.32
- Demchuk, O. P.; Hryshchuk, O. V.; Vashchenko, B. V.; Trofymchuk, S. A.; Melnykov, K. P.; Skreminskiy, A.; Volochnyuk, D. M.; Grygorenko, O. O. Fluoroalkyl-Containing 1,2-Disubstituted Cyclobutanes: Advanced Building Blocks for Medicinal Chemistry. European Journal of Organic Chemistry 2020, 2021, 87–95. doi:10.1002/ejoc.202001345
- Hari, D. P.; Abell, J. C.; Fasano, V.; Aggarwal, V. K. Ring-Expansion Induced 1,2-Metalate Rearrangements: Highly Diastereoselective Synthesis of Cyclobutyl Boronic Esters. Journal of the American Chemical Society 2020, 142, 5515–5520. doi:10.1021/jacs.0c00813
- Roy, A.; Bonetti, V.; Wang, G.; Wu, Q.; Klare, H. F. T.; Oestreich, M. Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cyclopropanes. Organic letters 2020, 22, 1213–1216. doi:10.1021/acs.orglett.0c00173
