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Synthesis of 1,2-divinylcyclopropanes by metal-catalyzed cyclopropanation of 1,3-dienes with cyclopropenes as vinyl carbene precursors

Jesús González, Alba de la Fuente, María J. González, Laura Díez de Tejada, Luis A. López and Rubén Vicente

Beilstein J. Org. Chem. 2019, 15, 285–290. https://doi.org/10.3762/bjoc.15.25

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Supporting Information File 1: Experimental details as well as ¹H and ¹³C NMR spectra of new compounds.
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Synthesis of 1,2-divinylcyclopropanes by metal-catalyzed cyclopropanation of 1,3-dienes with cyclopropenes as vinyl carbene precursors

Jesús González, Alba de la Fuente, María J. González, Laura Díez de Tejada, Luis A. López and Rubén Vicente

Beilstein J. Org. Chem. 2019, 15, 285–290. https://doi.org/10.3762/bjoc.15.25

How to Cite

González, J.; de la Fuente, A.; González, M. J.; Díez de Tejada, L.; López, L. A.; Vicente, R. Beilstein J. Org. Chem. 2019, 15, 285–290. doi:10.3762/bjoc.15.25

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Scholarly Works

Coto, D.; Suárez‐García, D.; Mata, S.; Fernández, I.; López, L. A.; Vicente, R. From Cyclopropene to Housane Derivatives Via Intramolecular Cyclopropanation. Angewandte Chemie 2024, 136. doi:10.1002/ange.202409226
Coto, D.; Suárez-García, D.; Mata, S.; Fernández, I.; López, L. A.; Vicente, R. From Cyclopropene to Housane Derivatives Via Intramolecular Cyclopropanation. Angewandte Chemie (International ed. in English) 2024, 63, e202409226. doi:10.1002/anie.202409226
Coto, D.; Barbolla, I.; Vicente, R. Catalytic cyclopropanation reactions with α-silyl-, germanyl- and stannyl carbenes generated from cyclopropenes. Chemical communications (Cambridge, England) 2022, 58, 8416–8419. doi:10.1039/d2cc03338k
Baker, R. J.; Ching, J.; Hou, T. R.; Franzoni, I.; Lautens, M. Dearomative Cyclopropanation of Naphthols via Cyclopropene Ring-Opening. Angewandte Chemie (International ed. in English) 2022, 61, e202116171. doi:10.1002/anie.202116171
Baker, R. J.; Ching, J.; Hou, T. R.; Franzoni, I.; Lautens, M. Dearomative Cyclopropanation of Naphthols via Cyclopropene Ring‐Opening. Angewandte Chemie 2022, 134. doi:10.1002/ange.202116171
González-Rodríguez, J.; Soengas, R. G.; Rodriguez‐Solla, H. A cooperative zinc/catalytic indium system for the stereoselective sequential synthesis of (E)-1,3-dienes from carbonyl compounds. Organic Chemistry Frontiers 2021, 8, 591–598. doi:10.1039/d0qo01388a
Armengol‐Relats, H.; Mato, M.; Echavarren, A. M. Assembly of Complex 1,4‐Cycloheptadienes by (4+3) Cycloaddition of Rhodium(II) and Gold(I) Non‐Acceptor Carbenes. Angewandte Chemie 2020, 133, 1944–1950. doi:10.1002/ange.202012092
Armengol-Relats, H.; Mato, M.; Echavarren, A. M. Assembly of Complex 1,4-Cycloheptadienes by (4+3) Cycloaddition of Rhodium(II) and Gold(I) Non-Acceptor Carbenes. Angewandte Chemie (International ed. in English) 2020, 60, 1916–1922. doi:10.1002/anie.202012092
Mato, M.; Franchino, A.; García-Morales, C.; Echavarren, A. M. Gold-Catalyzed Synthesis of Small Rings. Chemical reviews 2020, 121, 8613–8684. doi:10.1021/acs.chemrev.0c00697
Vicente, R. C-C Bond Cleavages of Cyclopropenes: Operating for Selective Ring-Opening Reactions. Chemical reviews 2020, 121, 162–226. doi:10.1021/acs.chemrev.0c00151
Ross, R.; Jeyaseelan, R.; Lautens, M. Rhodium-Catalyzed Intermolecular Cyclopropanation of Benzofurans, Indoles, and Alkenes via Cyclopropene Ring Opening. Organic letters 2020, 22, 4838–4843. doi:10.1021/acs.orglett.0c01655
Li, P.-H.; Zhang, X.-Y.; Shi, M. Recent developments in cyclopropene chemistry. Chemical communications (Cambridge, England) 2020, 56, 5457–5471. doi:10.1039/d0cc01612h
Zheng, G.; Zhou, Z.; Zhu, G.; Zhai, S.; Xu, H.; Duan, X.; Yi, W.; Li, X. Rhodium(III)‐Catalyzed Enantio‐ and Diastereoselective C−H Cyclopropylation of N‐Phenoxylsulfonamides: Combined Experimental and Computational Studies. Angewandte Chemie 2020, 132, 2912–2918. doi:10.1002/ange.201913794
Zheng, G.; Zhou, Z.; Zhu, G.; Zhai, S.; Xu, H.; Duan, X.; Yi, W.; Li, X. Rhodium(III)-Catalyzed Enantio- and Diastereoselective C-H Cyclopropylation of N-Phenoxylsulfonamides: Combined Experimental and Computational Studies. Angewandte Chemie (International ed. in English) 2020, 59, 2890–2896. doi:10.1002/anie.201913794

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aromatic	the word “aromatic”
aromatic aldehyde	the word “aromatic” OR “aldehyde”
+aromatic +aldehyde	both words “aromatic” AND “aldehyde”
+aromatic -aldehyde	the word “aromatic” but NOT “aldehyde”
“aromatic aldehyde”	the exact phrase “aromatic aldehyde”
benz*	words which begin with “benz”, such as “benzene” or “benzyl”
benz*yl	words that begin with “benz” and end with “yl”, such as “benzyl” or “benzoyl”
benzyl~	words that are close to the word “benzyl”, such as “benzoyl” (i.e., fuzzy search)