Strong hyperconjugative interactions limit solvent and substituent influence on conformational equilibrium: the case of cis-2-halocyclohexylamines

Camila B. Francisco, Cleverton S. Fernandes, Ulisses Z. de Melo, Roberto Rittner, Gisele F. Gauze and Ernani A. Basso

Beilstein J. Org. Chem. 2019, 15, 818–829. doi:10.3762/bjoc.15.79

Supporting Information

Supporting Information File 1: 1H and 13C NMR spectra at 25 and −80 °C, supplementary theoretical values, RScript for PCA and the Cartesian coordinates of the structures.
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Supporting Information File 2: NBO data for PCA.
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