Development of fluorinated benzils and bisbenzils as room-temperature phosphorescent molecules

Shigeyuki Yamada, Takuya Higashida, Yizhou Wang, Masato Morita, Takuya Hosokai, Kaveendra Maduwantha, Kaveenga Rasika Koswattage and Tsutomu Konno

Beilstein J. Org. Chem. 2020, 16, 1154–1162. https://doi.org/10.3762/bjoc.16.102

Supporting Information

Experimental procedures for the synthesis and characterization of fluorinated benzils 2a and 2b, fluorinated bisbenzils 3a and 3b, and nonfluorinated bisbenzil 3c. 1H, 13C, and 19F NMR spectra of 2a, 2b, and 3a–c. Cartesian coordinates of the optimized geometries of 1a, 1c, 2a, and 3a obtained from DFT calculations.

Supporting Information File 1: Experimental preocedures, NMR spectra and Cartesian coordinates.
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Organo-fluorine chemistry V

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