Development of fluorinated benzils and bisbenzils as room-temperature phosphorescent molecules

Shigeyuki Yamada, Takuya Higashida, Yizhou Wang, Masato Morita, Takuya Hosokai, Kaveendra Maduwantha, Kaveenga Rasika Koswattage and Tsutomu Konno

Beilstein J. Org. Chem. 2020, 16, 1154–1162. doi:10.3762/bjoc.16.102

Supporting Information

Experimental procedures for the synthesis and characterization of fluorinated benzils 2a and 2b, fluorinated bisbenzils 3a and 3b, and nonfluorinated bisbenzil 3c. 1H, 13C, and 19F NMR spectra of 2a, 2b, and 3a–c. Cartesian coordinates of the optimized geometries of 1a, 1c, 2a, and 3a obtained from DFT calculations.

Supporting Information File 1: Experimental preocedures, NMR spectra and Cartesian coordinates.
Format: PDF Size: 2.3 MB Download

References

Article Citation
Download RIS (Reference Manager) Download BIB (BIBTEX)
Cited References
Download RIS (Reference Manager) Download BIB (BIBTEX)

Presentation Graphic

Picture with graphical abstract, title and authors for social media postings and presentations.

Format: PNG Size: 184.5 KB Download
Back To Article

Article is part of the issue

Organo-fluorine chemistry V

David O'Hagan

Latest Articles

Synthesis, structural characterization, and optical properties of benzo[f]naphtho[2,3-b]phosphoindoles

  1. Mio Matsumura,
  2. Takahiro Teramoto,
  3. Masato Kawakubo,
  4. Masatoshi Kawahata,
  5. Yuki Murata,
  6. Kentaro Yamaguchi,
  7. Masanobu Uchiyama and
  8. Shuji Yasuike
  • Letter
  • Published 05 Mar 2021

Beilstein J. Org. Chem. 2021, 17, 671–677, doi:10.3762/bjoc.17.56

[2 + 1] Cycloaddition reactions of fullerene C60 based on diazo compounds

  1. Yuliya N. Biglova
  • Review
  • Published 05 Mar 2021

Beilstein J. Org. Chem. 2021, 17, 630–670, doi:10.3762/bjoc.17.55

Synthesis and properties of oligonucleotides modified with an N-methylguanidine-bridged nucleic acid (GuNA[Me]) bearing adenine, guanine, or 5-methylcytosine nucleobases

  1. Naohiro Horie,
  2. Takao Yamaguchi,
  3. Shinji Kumagai and
  4. Satoshi Obika
  • Full Research Paper
  • Published 04 Mar 2021

Beilstein J. Org. Chem. 2021, 17, 622–629, doi:10.3762/bjoc.17.54

Valorisation of plastic waste via metal-catalysed depolymerisation

  1. Francesca Liguori,
  2. Carmen Moreno-Marrodán and
  3. Pierluigi Barbaro
  • Review
  • Published 02 Mar 2021

Beilstein J. Org. Chem. 2021, 17, 589–621, doi:10.3762/bjoc.17.53

Designed whole-cell-catalysis-assisted synthesis of 9,11-secosterols

  1. Marek Kõllo,
  2. Marje Kasari,
  3. Villu Kasari,
  4. Tõnis Pehk,
  5. Ivar Järving,
  6. Margus Lopp,
  7. Arvi Jõers and
  8. Tõnis Kanger
  • Full Research Paper
  • Published 01 Mar 2021

Beilstein J. Org. Chem. 2021, 17, 581–588, doi:10.3762/bjoc.17.52

Breakdown of 3-(allylsulfonio)propanoates in bacteria from the Roseobacter group yields garlic oil constituents

  1. Anuj Kumar Chhalodia and
  2. Jeroen S. Dickschat
  • Full Research Paper
  • Published 26 Feb 2021

Beilstein J. Org. Chem. 2021, 17, 569–580, doi:10.3762/bjoc.17.51

Amino- and polyaminophthalazin-1(2H)-ones: synthesis, coordination properties, and biological activity

  1. Zbigniew Malinowski,
  2. Emilia Fornal,
  3. Agata Sumara,
  4. Renata Kontek,
  5. Karol Bukowski,
  6. Beata Pasternak,
  7. Dariusz Sroczyński,
  8. Joachim Kusz,
  9. Magdalena Małecka and
  10. Monika Nowak
  • Full Research Paper
  • Published 25 Feb 2021

Beilstein J. Org. Chem. 2021, 17, 558–568, doi:10.3762/bjoc.17.50

Metal-free visible-light-enabled vicinal trifluoromethyl dithiolation of unactivated alkenes

  1. Xiaojuan Li,
  2. Qiang Zhang,
  3. Weigang Zhang,
  4. Jinzhu Ma,
  5. Yi Wang and
  6. Yi Pan
  • Full Research Paper
  • Published 24 Feb 2021

Beilstein J. Org. Chem. 2021, 17, 551–557, doi:10.3762/bjoc.17.49

Menthyl esterification allows chiral resolution for the synthesis of artificial glutamate analogs

  1. Kenji Morokuma,
  2. Shuntaro Tsukamoto,
  3. Kyosuke Mori,
  4. Kei Miyako,
  5. Ryuichi Sakai,
  6. Raku Irie and
  7. Masato Oikawa
  • Full Research Paper
  • Published 24 Feb 2021

Beilstein J. Org. Chem. 2021, 17, 540–550, doi:10.3762/bjoc.17.48

Synthesis of (Z)-3-[amino(phenyl)methylidene]-1,3-dihydro-2H-indol-2-ones using an Eschenmoser coupling reaction

  1. Lukáš Marek,
  2. Lukáš Kolman,
  3. Jiří Váňa,
  4. Jan Svoboda and
  5. Jiří Hanusek
  • Full Research Paper
  • Published 23 Feb 2021

Beilstein J. Org. Chem. 2021, 17, 527–539, doi:10.3762/bjoc.17.47

Latest Articles

Latest Thematic Issues

GlycoBioinformatics

Kiyoko F. Aoki-Kinoshita, Frédérique Lisacek, Niclas Karlsson, Daniel Kolarich, and Nicolle Packer

2020 Show Issue

Molecular recognition

Jochen Niemeyer, Thomas Schrader and Ivo Piantanida

2020 Show Issue

Organo-fluorine chemistry V

David O'Hagan

New Show Issue

Advances in photoredox catalysis

Timothy Noël

2019 Show Issue

C–H functionalization for materials science

Kenichiro Itami

2019 Show Issue

Medicinal chemistry and drug discovery in an opening era

Matthew Todd

2019 Show Issue

Copper-catalyzed reactions for organic synthesis

Gwilherm Evano and Olivier Riant

2019 Show Issue

Molecular switches

Wiktor Szymanski and Stefan Hecht

2019 Show Issue

Terpenes

Jeroen S. Dickschat

2019 Show Issue
Browse all Thematic Issues

Other Beilstein-Institut Open Science Activities

Logo
Logo
Logo
Logo

Keep Informed

RSS Feed

Subscribe to our Latest Articles RSS Feed.

Subscribe

Follow the Beilstein-Institut

LinkedIn

Twitter: @BeilsteinInst