Cite the Following Article
Development of N-F fluorinating agents and their fluorinations: Historical perspective
Teruo Umemoto, Yuhao Yang and Gerald B. Hammond
Beilstein J. Org. Chem. 2021, 17, 1752–1813.
https://doi.org/10.3762/bjoc.17.123
How to Cite
Umemoto, T.; Yang, Y.; Hammond, G. B. Beilstein J. Org. Chem. 2021, 17, 1752–1813. doi:10.3762/bjoc.17.123
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- Mulka, R.; Su, D.; Huang, W.-S.; Zhang, L.; Huang, H.; Lai, X.; Li, Y.; Xue, X.-S. FluoBase: a fluorinated agents database. Journal of cheminformatics 2025, 17, 19. doi:10.1186/s13321-025-00949-x
- Das, S.; Das, R.; Ghosh, T.; Kumar Nandi, R. Recent Advancement on Selectfluor Mediated Synthesis of Heterocyclic Molecules. Chemical record (New York, N.Y.) 2025, 25, e202400216. doi:10.1002/tcr.202400216
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- Cheng, Q.; Shen, X. 29.1.5 F/Hal Acetals (Update 2025). Knowledge Updates 2025/2; Georg Thieme Verlag KG, 2025. doi:10.1055/sos-sd-129-00221
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- Wang, C.-Q.; Feng, C. Applications of Nucleophilic Fluorine Sources in the Selective Fluorofunctionalization of Unsaturated Carbon-Carbon Bonds. Acta Chimica Sinica 2024, 82, 160. doi:10.6023/a23080373
- Wen, L.; Zou, Z.; Zhou, N.; Sun, C.; Xie, P.; Feng, P. Electrochemical Fluorination Functionalization of gem-Difluoroalkenes with CsF as a Fluorine Source: Access to Fluoroalkyl Building Blocks. Organic letters 2023, 26, 241–246. doi:10.1021/acs.orglett.3c03901
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- BARHAM JOSHUA; DAUTH BASTIAN; STOCKERL WILLIBALD; GSCHWIND RUTH; YAKUBOV SHAHBOZ. ADDITIVES FOR IMPROVED C-H FLUORINATION REACTIONS. WO 2025088056 A1, May 1, 2025.
- The designation of the inventor has not yet been filed. ADDITIVES FOR IMPROVED C-H FLUORINATION REACTIONS. EP 4545532 A1, April 30, 2025.