Synthetic reactions driven by electron-donor–acceptor (EDA) complexes

Scholarly Works

• Shandu, M. P.; Ngwenya, A. R.; Lamola, J. L.; Moshapo, P. T. Organocatalytic Synthesis of Amides Using Thioacids and Anilines via Electron Donor-Acceptor Photoactivation. The Journal of organic chemistry 2026, 91, 5085–5090. doi:10.1021/acs.joc.6c00035
• Xu, T.; Hong, R.; Lu, T.; Zhu, D.; Yu, J.; Wang, M.; Li, P. Photoinduced intramolecular S-α-C(sp3)-H functionalization enabled by an electron donor-acceptor complex-Mediated radical relay. Chemical science 2026. doi:10.1039/d6sc01281g
• Cai, B.-G.; Wang, Q.; Xuan, J.; Xiao, W.-J. Beyond single pathways: synergistic SET-EnT pathways in visible-light photochemistry. Chemical Society reviews 2026. doi:10.1039/d6cs00112b
• Wu, L.; Li, X.; Yan, D.; Cao, K.; Li, J. Synthesis of symmetric aryl sulfides mediated by xanthates: Based on the EDA complex strategy. Tetrahedron 2026, 191, 135105. doi:10.1016/j.tet.2025.135105
• Natarajan, P.; Partigya; Pooja; Priya; Meena. Visible-light-induced metal- and photocatalyst-free oxidative intramolecular cyclization of N-methyl-N-substituted-[1,1′-biaryl]-2-amines: facile access to phenanthridinones. Journal of Photochemistry and Photobiology A: Chemistry 2026, 472, 116812. doi:10.1016/j.jphotochem.2025.116812
• Bishir, C.; Milton, S.; Hubbard, A.; Indalsingh, M.; Abufouz, Z.; Mei, L. Visible-Light-Induced Radical Cascade [4 + 2]/[4 + 2] Cycloaddition of Underexplored N-Acryloyl Indoles To Access Dihydropyrido[1,2-a]-indolones. Organic letters 2026, 28, 2852–2858. doi:10.1021/acs.orglett.5c05421
• Belli, L. P. A.; Pagliarini, F. R.; Braga, A. L.; de Assis, F. F. Visible light photoalkylation of 2-arylimidazo[1,2-a]pyridines on C3 position via EDA complex formation with Katritzky salts. Tetrahedron 2026, 195, 135207. doi:10.1016/j.tet.2026.135207
• Ji, Y.; Pleixats, R.; Fernández, I.; Gimbert-Suriñach, C.; Vallribera, A.; Granados, A. EDA-complex photoactivation of thianthrene-based radical precursors enables divergent access to functionalized saturated heterocycles. Organic Chemistry Frontiers 2026, 13, 1116–1124. doi:10.1039/d5qo01397f
• Matsukuma, K.; Tayu, M.; Nakai, K.; Yamano, M.; Ohrui, S.; Yamaguchi, T.; Saito, N. De Novo Synthesis of Multisubstituted Pyrrolidines Based on a Programmed Radical [2 + 2 + 1] Annulation Strategy Using Sulfide-Based Electron Donor-Acceptor Catalysis. The Journal of organic chemistry 2026, 91, 4917–4926. doi:10.1021/acs.joc.5c02978
• Lai, D.; Ghosh, S.; Sinha, S.; Hajra, A. Electron Donor–Acceptor (EDA) Complexation With Hypervalent Iodines: An Update. ChemPhotoChem 2026, 10. doi:10.1002/cptc.202500258
• Tagami, K.; Yajima, T. Perfluoroalkylation reactions via halogen-bonded electron donor-acceptor (EDA) complexes of amines and perfluoroalkyl halides under visible light. Tetrahedron 2026, 193, 135156. doi:10.1016/j.tet.2026.135156
• Quan, Z.; Liu, Y.; Zhong, Q.; Wang, B. Metal-free radical borylations: mechanisms, catalytic strategies, and synthetic applications. Chemical science 2026, 17, 1534–1568. doi:10.1039/d5sc08322b
• Zhang, M.-Z.; Yang, J.; Dai, K.-Y.; Wen, J. Photoactive H-Bonding EDA Complex in Radical Chemistry. Chemistry (Weinheim an der Bergstrasse, Germany) 2026, 32, e70708. doi:10.1002/chem.70708
• Wang, F.; Miao, Z. Direct Functionalization of White Phosphorus (P4) with Diaryl Disulfides and Aryl Thianthrenium Salts via Photoactivation of an Electron Donor-Acceptor Complex. The Journal of organic chemistry 2026, 91, 1544–1554. doi:10.1021/acs.joc.5c02185
• Liu, W.; Næsborg, L. Electron Donor–Acceptor Complexes Without Preinstalled Sacrificial Leaving Groups: Applications in Synthesis. Helvetica Chimica Acta 2026, 109. doi:10.1002/hlca.202500168
• Riina, F.; Chiarello, G.; Poletti, L.; Ragno, D.; De Risi, C.; Natali, M.; Droghetti, F.; Massi, A.; Di Carmine, G. Synthesis of α- C -glycoside conjugates via a Giese-like reaction triggered by photoactivated electron donor–acceptor (EDA) complexes and in situ photocatalytic species. Organic Chemistry Frontiers 2026. doi:10.1039/d6qo00174b
• Cai, B.-G.; Zhang, L.-H.; Xie, Y.; Zhang, Q.; Xuan, J. Tunable ring-opening of 2 H -azirines via visible-light-driven novel selective C–C/C–N or CN bond cleavage. Organic Chemistry Frontiers 2026. doi:10.1039/d6qo00168h
• Uchikura, T.; Ohashi, K.; Akutsu, F.; Akiyama, T. Fluoride‐Coupled Electron Transfer and Hydrogen‐Atom‐Transfer‐Mediated Synthesis of Difluoromethylarenes. European Journal of Organic Chemistry 2025, 29. doi:10.1002/ejoc.202501034
• Li, J.; Ji, Z.; Wang, H.; Hu, X.; Lu, X.; Cheng, T.; Liu, G.; Liu, R. Ph3N as an Organocatalytic Donor for Photoactivation of Pyridinium-Masked Enols in the Formal [4 + 2] Cycloaddition with Unactivated Olefins. Organic letters 2025, 28, 553–559. doi:10.1021/acs.orglett.5c05038
• Way, R. Y.; Guo, X.; Tang, Y.; Shirah, J. B.; Zhu, Q. Hydrogen Isotope Exchange of Aromatic C(sp2)-H Bonds via Electron Donor-Acceptor Organic Photocatalysis. Journal of the American Chemical Society 2025, 147, 47179–47186. doi:10.1021/jacs.5c14203

Explore citations to this article at