Benzothiazolium salts as reagents for the deoxygenative perfluoroalkylthiolation of alcohols

Armin Ariamajd, Nils J. Gerwien, Benjamin Schwabe, Stefan Dix and Matthew N. Hopkinson
Beilstein J. Org. Chem. 2021, 17, 83–88. https://doi.org/10.3762/bjoc.17.8

Supporting Information

The Supporting Information contains experimental procedures, characterization data of all BT-SRF reagents and isolated products as well as copies of NMR spectra.

Supporting Information File 1: Experimental section.
Format: PDF Size: 3.5 MB Download

Cite the Following Article

Benzothiazolium salts as reagents for the deoxygenative perfluoroalkylthiolation of alcohols
Armin Ariamajd, Nils J. Gerwien, Benjamin Schwabe, Stefan Dix and Matthew N. Hopkinson
Beilstein J. Org. Chem. 2021, 17, 83–88. https://doi.org/10.3762/bjoc.17.8

How to Cite

Ariamajd, A.; Gerwien, N. J.; Schwabe, B.; Dix, S.; Hopkinson, M. N. Beilstein J. Org. Chem. 2021, 17, 83–88. doi:10.3762/bjoc.17.8

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Presentation Graphic

Picture with graphical abstract, title and authors for social media postings and presentations.
Format: PNG Size: 7.4 MB Download

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Haswell, A.; Tironi, M.; Wang, H.; Hopkinson, M. N. Deoxygenative perfluoroalkylthiolation of carboxylic acids with benzothiazolium reagents. Journal of Fluorine Chemistry 2024, 273, 110231. doi:10.1016/j.jfluchem.2023.110231
  • Mestre, J.; Bernús, M.; Castillón, S.; Boutureira, O. Electrophilic Reagents for the Direct Incorporation of Uncommon SCF2CF2H and SCF2CF3 Motifs. The Journal of organic chemistry 2022, 87, 10791–10806. doi:10.1021/acs.joc.2c01038
  • Tironi, M.; Hopkinson, M. N. Silver‐Catalyzed Nucleophilic Deoxydifluoromethylthiolation of Activated Aliphatic Alcohols with BT−SCF2H. European Journal of Organic Chemistry 2022, 2022. doi:10.1002/ejoc.202101557
  • Cao, Y.; Ahmadi, R.; Poor Heravi, M. R.; Issakhov, A.; Ebadi, A. G.; Vessally, E. Recent trends in dehydroxylative trifluoro-methylation, -methoxylation, -methylthiolation, and -methylselenylation of alcohols. RSC advances 2021, 11, 39593–39606. doi:10.1039/d1ra05018d
  • Maas, L. M.; Schmid, J. R.; Fasting, C.; Voßnacker, P.; Mavroskoufis, A.; Hopkinson, M. N. Activation of tetrahydrofuran with 2-((Fluoroalkyl)thio)Benzothiazolium reagents. Tetrahedron 2021, 101, 132512. doi:10.1016/j.tet.2021.132512
  • Tironi, M.; Dix, S.; Hopkinson, M. N. Deoxygenative nucleophilic difluoromethylselenylation of carboxylic acids and alcohols with BT-SeCF2H. Organic Chemistry Frontiers 2021, 8, 6026–6031. doi:10.1039/d1qo01104a
Other Beilstein-Institut Open Science Activities