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Organocatalytic asymmetric nitroso aldol reaction of α-substituted malonamates

Ekta Gupta, Narendra Kumar Vaishanv, Sandeep Kumar, Raja Krishnan Purshottam, Ruchir Kant and Kishor Mohanan

Beilstein J. Org. Chem. 2022, 18, 217–224. https://doi.org/10.3762/bjoc.18.25

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Organocatalytic asymmetric nitroso aldol reaction of α-substituted malonamates

Ekta Gupta, Narendra Kumar Vaishanv, Sandeep Kumar, Raja Krishnan Purshottam, Ruchir Kant and Kishor Mohanan

Beilstein J. Org. Chem. 2022, 18, 217–224. https://doi.org/10.3762/bjoc.18.25

How to Cite

Gupta, E.; Vaishanv, N. K.; Kumar, S.; Purshottam, R. K.; Kant, R.; Mohanan, K. Beilstein J. Org. Chem. 2022, 18, 217–224. doi:10.3762/bjoc.18.25

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TY  - JOUR
A1  - Gupta, Ekta
A1  - Vaishanv, Narendra Kumar
A1  - Kumar, Sandeep
A1  - Purshottam, Raja Krishnan
A1  - Kant, Ruchir
A1  - Mohanan, Kishor
T1  - Organocatalytic asymmetric nitroso aldol reaction of α-substituted malonamates
JF  - Beilstein Journal of Organic Chemistry
PY  - 2022///
VL  - 18
SP  - 217
EP  - 224
SN  - 1860-5397
DO  - 10.3762/bjoc.18.25
PB  - Beilstein-Institut
JA  - Beilstein J. Org. Chem.
UR  - https://doi.org/10.3762/bjoc.18.25
KW  - enantioselective
KW  - malonamate
KW  - nitroso aldol reaction
KW  - N-selectivity
KW  - Takemoto catalyst
N2  - A practical enantioselective N-selective nitroso aldol reaction of α-methylmalonamates with a nitrosoarene is reported. The reaction employs the Takemoto thiourea catalyst for the induction of enantioselectivity, and the corresponding optically active oxyaminated malonamates were obtained in reasonably good yields.
ER  -

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Zhang, Y.; Vanderghinste, J.; Wang, J.; Das, S. Challenges and recent advancements in the synthesis of α,α-disubstituted α-amino acids. Nature communications 2024, 15, 1474. doi:10.1038/s41467-024-45790-2

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