Recent developments and trends in the iron- and cobalt-catalyzed Sonogashira reactions

Scholarly Works

• Sahoo, A. K.; Dash, R.; Valappil, L. C.; Jhaa, G.; Agarwalla, S. K.; Purohit, C. S.; Chakkingal Parambil, P.; Doddi, A. Pd(II)-Mediated Si-H Activation of Ortho-Silyl Arylphosphines: Complexes with Pd-Si Bonds and their Utility in Carbon-Carbon Coupling Reactions. Inorganic chemistry 2025, 64, 20467–20480. doi:10.1021/acs.inorgchem.5c03868
• Cao, N.; Tong, Y.; Xie, J.; Gong, S. A heterogeneous MOF-253-based Pd/Cu bimetal for Sonogashira coupling reactions. Tetrahedron 2025, 179, 134628. doi:10.1016/j.tet.2025.134628
• Sarkar, G.; Paramanik, K.; Bandopadhyay, N.; Chatterjee, S.; Saha, S.; Panda, S. J.; Purohit, C. S.; Biswas, B.; Das, H. S. Copper(ii) phenalenyl complexes: structures, redox properties and catalytic activity towards Sonogashira coupling reactions. New Journal of Chemistry 2025, 49, 8232–8238. doi:10.1039/d5nj00906e
• Payamifar, S.; Abdouss, M.; Poursattar Marjani, A. A review of using β-cyclodextrin-based catalysts for Sonogashira reactions. Journal of Organometallic Chemistry 2025, 1031, 123592. doi:10.1016/j.jorganchem.2025.123592
• Miyamoto, K.; Kikuzawa, J.; Togo, A.; Fujiki, Y.; Kawashita, N.; Matsumoto, K. Straightforward synthesis of diarylacetylenes from tetrachloroethylene using Kumada coupling reaction by Pd catalyst. Application to tri- and tetraarylethylenes. Bulletin of the Chemical Society of Japan 2025, 98. doi:10.1093/bulcsj/uoaf025
• Binandeh, M. One pot of Sonogashira coupling and oxidation of alcohol reactions by magnetic nanocatalyst in an ideal environment. Journal of Materials Science: Materials in Engineering 2025, 20. doi:10.1186/s40712-025-00212-z
• Yan, F.; Zhang, X.; Li, D.; Zhu, N.; Bao, H. Recent Applications of the Sonogashira Reaction in the Synthesis of Drugs and Their Derivatives: A Review. Applied Organometallic Chemistry 2024, 39. doi:10.1002/aoc.7932
• Jo, Y.-J.; Park, S.-W.; Shin, U. S.; Kim, S.-H. Copper Catalysts Anchored on Cysteine-Functionalized Polydopamine-Coated Magnetite Particles: A Versatile Platform for Enhanced Coupling Reactions. Molecules (Basel, Switzerland) 2024, 29, 5121. doi:10.3390/molecules29215121
• Ghahramani, F.; Mansoori, Y.; Esquivel, D.; Navarro, M. A. A copper- and amine-free sonogashira reaction catalyzed by a supported bis(oxime palladacycle) on magnetized SBA-15. Journal of Solid State Chemistry 2024, 336, 124736. doi:10.1016/j.jssc.2024.124736
• Sim, Y.; Lee, S.-J.; Kim, S.-H. Scope and limitations of the combination of cobalt catalyst and choline hydroxide as green media for Sonogashira coupling and hydration of nitriles. Journal of Chemical Sciences 2024, 136. doi:10.1007/s12039-024-02288-0
• Sil, S.; Krishnapriya, A. U.; Mandal, P.; Kuniyil, R.; Mandal, S. K. Cross-Coupling Between Aryl Halides and Aryl Alkynes Catalyzed by an Odd Alternant Hydrocarbon. Chemistry (Weinheim an der Bergstrasse, Germany) 2024, 30, e202400895. doi:10.1002/chem.202400895
• Zhurkin, F.; Parisot, W.; Lefèvre, G. A Solely Fe‐Catalyzed Sonogashira‐Type Coupling of non‐Activated Secondary Alkyl Iodides with Terminal Alkynes. Advanced Synthesis & Catalysis 2024, 366, 1782–1787. doi:10.1002/adsc.202301340
• Yin, Z. doi:10.1002/9783527841943.ch9
• Braconi, E.; Godineau, E.; Smejkal, T.; Jäckh, S. Nickel‐Catalyzed Sonogashira Couplings: Extending the Reaction Scope to Aryl Bromides and Chlorides. Advanced Synthesis & Catalysis 2024, 366, 1551–1558. doi:10.1002/adsc.202301423
• Kobatake, M.; Miyoshi, N.; Ueno, M. One-Pot Tandem Coupling Method for the Short-Step Formal Synthesis of Riccardin C. Chemistry (Weinheim an der Bergstrasse, Germany) 2023, 29, e202203805. doi:10.1002/chem.202203805
• Rajmane, A.; Kumbhar, A. Polydentate P, N-based ligands for palladium-catalyzed cross-coupling reactions. Molecular Catalysis 2022, 532, 112699. doi:10.1016/j.mcat.2022.112699
• Kotovshchikov, Y. N.; Binyakovsky, A. A.; Latyshev, G. V.; Lukashev, N. V.; Beletskaya, I. P. Copper-catalyzed deacetonative Sonogashira coupling. Organic & biomolecular chemistry 2022, 20, 7650–7657. doi:10.1039/d2ob01267g

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