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N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction

Grigory Kantin, Pavel Golubev, Alexander Sapegin, Alexander Bunev and Dmitry Dar’in

Beilstein J. Org. Chem. 2023, 19, 1841–1848. https://doi.org/10.3762/bjoc.19.136

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Chemical structure C<sub>14</sub>H<sub>21</sub>N<sub>5</sub>O<sub>5</sub>

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Extracted from

Scheme 3

Chemical Information

Calculated using the Chemistry Development Kit 2.12

Property Name	Property Value
Molecular Formula	C₁₄H₂₁N₅O₅
Molecular Weight	339.35 g/mol
Exact Mass	339.1543 Da
InChI	InChI=1S/C14H21N5O5/c1-14(2,3)24-13(22)18-11(20)6-5-9(12(18)21)19-16-10(15-17-19)7-8-23-4/h9H,5-8H2,1-4H3
InChIKey	CGJYWLAUQFKGOU-UHFFFAOYSA-N
SMILES	CC(C)(C)OC(=O)N1C(=O)CCC(C1=O)N2N=C(CCOC)N=N2
Number of Atoms	45
Number of H-Bond Acceptors	10
Number of H-Bond Donors	0
Atoms in the Largest π-System	8
XLogP	0.7

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