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N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction

Grigory Kantin, Pavel Golubev, Alexander Sapegin, Alexander Bunev and Dmitry Dar’in

Beilstein J. Org. Chem. 2023, 19, 1841–1848. https://doi.org/10.3762/bjoc.19.136

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Chemical structure C<sub>18</sub>H<sub>21</sub>N<sub>3</sub>O<sub>6</sub>

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Extracted from

Scheme 3

Chemical Information

Calculated using the Chemistry Development Kit 2.12

Property Name	Property Value
Molecular Formula	C₁₈H₂₁N₃O₆
Molecular Weight	375.38 g/mol
Exact Mass	375.1430 Da
InChI	InChI=1S/C18H21N3O6/c1-18(2,3)27-17(24)20-15(22)7-6-13(16(20)23)19-9-8-11-4-5-12(21(25)26)10-14(11)19/h4-5,10,13H,6-9H2,1-3H3
InChIKey	DAAVRRMXTACXTH-UHFFFAOYSA-N
SMILES	CC(C)(C)OC(=O)N1C(=O)CCC(C1=O)N2CCC3=CC=C(C=C32)[N+](=O)[O-]
Number of Atoms	48
Number of H-Bond Acceptors	6
Number of H-Bond Donors	0
Atoms in the Largest π-System	10
XLogP	2.1

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